Green Energy and Hydrogen from Coal The draft of Integrated Project Proposals in Support for the HYPOGEN EU Initiative of Sustainable Energy Development Jerzy Bednarczyk, Jan Kozubowski, Jan Rogut Institute of Opencast Mining

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Green Energy and Hydrogen from Coal The draft
of Integrated Project Proposals in Support for
the HYPOGEN EU Initiative of Sustainable Energy
DevelopmentJerzy Bednarczyk, Jan Kozubowski,
Jan RogutInstitute of Opencast Mining
Poltegor, Wroclaw, poltegor_at_igo.wroc.plWarsaw
Technical University, Warsaw, jankozu_at_inmat.pw.edu
.plCentral Mining Institute, Katowice,
rogutjan_at_yahoo.com

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Main Targets and Points of Interests of Hydrogen
Related Research in Poland

• Fossil fuel based power plants as future energy
  and hydrogen producers the sustainable way - the
  Green Energy from Coal concept
• Trans-border Czech - Slovak- Polish HyCom in
  Cieszyn/Tesin as an important tool for
  regional development - non fossil
• Establishment of the International RD Centre of
  Separation Technologies for Hydrogen Economy
  Needs - EU Marie Curie Transfer of Knowledge
  (TOK) Fund - Coke oven gas as separation model
  fluid - low cost nanostructured metals for
  hydrogen separation, cleaning up, and storage
• Hydrogen as friendly (!), safe (!) and profitable
  (!) material and energy carrier

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Sources of Natural Gas for Europe in Short Term
Perspective
Long-term Security of Gas Supply in a
Liberalized Market Jean-Paul PINON Director Gas
Market, CREG Co-chairman of the Gas Working
Group, CEER UNEC Round Table Genève 20/01/2004
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Hydrogen Production, Investment Costs
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• Coal is of great interest because
  it is
• Plentiful. Resource 500 years
• (vs. gas/oil 100 years).
• Inexpensive. 1-1.5 /GJ HHV
• (vs. gas at 2.5 /GJ).
• Ubiquitous. Wide geographic distribution
  
• (vs. middle east).
• Clean?! Gasification, esp. with
  sequestration,
• produces little gaseous emissions and
• a chemically stable, vitreous ash.

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European Green Electricity and Hydrogen from
Coal Technology Development Area
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3
2
1
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Locations and Specialisations

• Upper Silesia - bituminuous coal based
  demonstration plant for HE production and CO2
  sequestration
• Black Triangle - lignite based demonstration
  plant plant for HE production and CO2
  sequestration
• Belchatow lignite mine - large scale facility
  for basic sequestration research
• gfz Potsdam - facility for applied
  sequestration research
• Newcastle University - mineral sequestration,
  process water issues
• University of Stuttgart, SIU Carbondale, ISSEP
  Liege - coal processing
• JRC (Petten, Ispra, Sevilla ) - foresight,
  regulations and policy aspects

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Green Electricity and Hydrogen from Coal
Clean Coal Technologies CO2 Sequestration
Green Hydrogen and Energy from Coal
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Vision of Technologically Viable and
Economically Feasible Increase of Total Energy
Efficiency of Electricity Production of Coal
Based Power Plants from 30-35 now to 60-70
in 10-15 Year Long Perspective
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HYPOGEN FutureGen
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USTDEV-1.2.7 - Capture and sequestration of CO2
associated with cleaner fossil fuel plants

• Global and EU energy supply will, for the
  foreseeable future (2015 - 2020), be dominated by
  fossil energy sources. However, their CO2
  emissions are a major drawback in the context of
  global climate change.
• The challenge is therefore to be able to use
  these fossil fuels whilst eliminating CO2
  through cost-effective capture and sequestration
  and at the same time maintaining EU industrial
  competitiveness in global markets.
• Targets reduce the cost of CO2 capture from
  50-60 to 20-30 per tonne of CO2
  captured, whilst aiming at achieving
  capture rates above 90, and assess the
  reliability and long term stability of
  sequestration.

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Major Research Partners

• Poland - GIG, Poltegor, PW, IChPW, IE, AGH,
  IGSMiE, EMAG
• Czech Republic TU Ostrava, ICHP Praque,
• Germany TU Stuttgart, gfz Potsdam, GGS Hannover,
  
• UK University of Newcastle, BGS
• Belgium ISSEP
• JRC ( Petten, Ispra, Sevilla)
• US SIU Carbondale, US EPA NRMRL Cincinnati,
  Washington University
• Greece NTUA
• Russia Yukos RD Centre, Boreskov Institute of
  Catalysis
• Denmark DTU Lyngby

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Low emission coal gasification to
hydrogencombined with sequestration ready CO2
production
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ISCC - Innovative In Situ CO2 Capture Technology
for Solid Fuel Gasification
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Energy and Hydrogen Production
post-combustion capture
Energy Conversion
Capture of CO2
Energy / Power
ASU
Oxy-fuel combustion
Energy Conversion
Fossil Fuel
Capture of CO2
Storage/Use of CO2
pre-combustion decarbonisation
Partial oxidation or Reforming
CO Shift
Fuel gas extraction
Energy / Power or Hydrogen
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Low emission coal gasification combined with
CO2 sequestration in unmineable coal bedsand
CBM recovery
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Underground coal gasificationcombinedwithgeothe
rmicsandCO2 sequestration
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O2 H2O
CO2 H2 CO
CO2 H2 CO
CO2
X
X
A
C
ToC
B
A
C
H2O COLD
H2O COLD
H2O HOT
H2O HOT
300
60
B
0 25 50 75 years
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Distribution of Magnesium Silicate Mineral
Deposits Worldwide
xMgO.ySiO2.zH2O (s) gt x MgO (s) y SiO2 (s) z
H2O (R1) MgO (s) CO2 gt MgCO3 (s) (R2)
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Mine Water
The Existing Problem
To be Solved
And we do not need the more in future
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Final Targets

• Development of background for construction of
  distributed system of energy and hydrogen
  production from coal, combined with
• European distributed system of carbon dioxide
  sequestration
• using synergy with other methods of hydrogen
  production

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Partners from non EU Countries have been invited
for participationUSRFChinaJapan
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TOK
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RD Centre of Separation Technologies for
Hydrogen Economy Needs

• Sources of the funds
• Marie Curie Transfer of Knowledge Coordinated
  Action
• US DOE and US EPA open solicitations
• European Capital Venture
• Private/Public Partnership

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Production of Hydrogen and Electricity from
CoalDivision of Component Costs
Conventional Gasification Technology
Hydrogen Separation Membrane Reactor
Data for diagrams taken from Production of
Hydrogen and Electricity from Coal with CO2
Capture by T.G. Kreutz et al. .http//www.princet
on.edu/cmi/research/Kyoto02/Kreutz20Kyoto2002.p
df
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Coke - oven gas as a model gas mixture for
development of advanced, low cost separation -
cleaning technologies
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Hydrogen as FRIENDLY SAFE and PROFITABLE
material and energy carrier
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Innovative Concepts

• Hydrogen as a reagent for hazardous waste
  treatment - dioxin free alternative to
  incinerators ( EcoSteel )
• Bio-mimetic Process of Hydrogen Generation from
  Biomass
• Hydrogen as energy source for biological methods
  of value recovery ( metal and clean water) from
  mine water drainage

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EcoSteel RESEARCH PROGRAMME OF THE RESEARCH
FUND FOR COAL AND STEEL (CALL 2004)
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Bio-mimetic Process of Hydrogen Generation from
Biomass
A. Brune, TIBITECH January 1998 (VOL 16)
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Welcome to CooperationRogut JanCentral Mining
InstitutePlac Gwarkow 140-166
KatowicePoland(48) 506 184 865(48) 32 259
2455sixjr_at_gig.katowice.plrogutjan_at_yahoo.comTha
nks for Attention