Alkoxymercuration PowerPoint PPT Presentations
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The alkoxide is a good nucleophile and will react with methyl or primary alkyl ... Central cavity is electronegative and attracts cations. K ...
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Epoxide groups are Common in Biologically Active Molecules. A New Class of Anti-tumor Agents ... Base Catalyzed Ring-Opening of Epoxides. Base Opens Ring from ...
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Protonation of double bond yields the most stable carbocation. ... Borane prefers least-substituted carbon due to steric hindrance as well as charge distribution. ...
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1. reduction of alkene (addition of hydrogen) 2. reduction of an alkyl halide ... 3. dehalogenation of a vicinal dihalide. 4. reduction of an alkyne. reactions ...
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Both alcohols and ethers can hydrogen bond to water and have similar solubilities in water ... with phosphorus tribromide, thionyl chloride or hydrogen halides ...
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Addition of hydrogen (reduction). Addition of halogens. Addition of hydrogen halides. ... 2. reduction of an alkyl halide. a) hydrolysis of a Grignard reagent ...
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Reduction of Carboxylic Acids and Esters. Lithium Aluminum Hydride Reduction ... Ester formation. Ether synthesis. Periodic acid cleavage of glycols ...
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... atmospheric oxygen, ethers slowly oxidize to hydroperoxides and dialkyl peroxides. ... Sulfides are easily oxidized to sulfoxides and sulfones. ...
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Enolate Chemistry and Malonic Ester Synthesis ... Synthetic Polymers (less reactive esters and amides) Predicting Products Problems ...
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Dallas County Community College District. 2003, Prentice Hall. Organic ... Spectroscopy of Ethers. IR: Stretches Present: Stretches Absent: MS: Chapter 14. 13 ...
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Examples: IUPAC Names Alkoxy alkane: use the more complex alkyl group as the root. Cyclic Ethers Heterocyclic: noncarbon in the ring: oxygen is in ring.
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Borane, BH3, adds a hydrogen to the most substituted carbon in ... the alkyl borane with basic hydrogen peroxide produces the alcohol. ... hydrogen peroxide ...
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Remember the alkoxy name is only a higher priority than the halides. ... American cockroach. Chapter 14. 6. 5. forming complexes. a. 6 electron reagents - storage ...
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Electrons in pi bond are loosely held. Electrophiles are attracted ... Milder oxidation than permanganate. Products formed are ketones or aldehydes. Chapter 8 ...
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... A cyclic ether containing two carbons is called ethylene oxide ... beverage is merely twice the ... Physical Properties of Aldehydes and Ketones Carbon-oxygen ...
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18: Ethers and Epoxides; Thiols and Sulfides. Based on McMurry's Organic Chemistry, 6th edition ... An ether has two organic groups (alkyl, aryl, or vinyl) ...
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Many C-metal bonds observed in catalytic processes, not isolated, often transient ... Works for both aromatic and aliphatic halides (except F) ...
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