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Electrophilic aromatic substitution PowerPoint PPT Presentation

Electrophilic aromatic substitution - Title: Substitution aromatique lectrophile Author: Ed Blackburn Last modified by: eblackbu Created Date: 3/30/1996 4:18:52 PM Document presentation format

Title: Substitution aromatique lectrophile Author: Ed Blackburn Last modified by: eblackbu Created Date: 3/30/1996 4:18:52 PM Document presentation format

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Electrophilic Aromatic Substitution - Electrophilic Aromatic Substitution Electrophilic Aromatic Substitution involves the attack on the electrophile by the electrons of the aromatic ring and ...

Electrophilic Aromatic Substitution Electrophilic Aromatic Substitution involves the attack on the electrophile by the electrons of the aromatic ring and ...

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Electrophilic Aromatic Substitution - Electrophilic Aromatic Substitution Electrophilic Aromatic Substitution involves the attack on the electrophile by the electrons of the aromatic ring and ...

Electrophilic Aromatic Substitution Electrophilic Aromatic Substitution involves the attack on the electrophile by the electrons of the aromatic ring and ...

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Electrophilic Aromatic Substitution - Title: PowerPoint Presentation Last modified by: Created Date: 1/18/2005 6:12:23 PM Document presentation format: (4:3)

Title: PowerPoint Presentation Last modified by: Created Date: 1/18/2005 6:12:23 PM Document presentation format: (4:3)

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Electrophilic Reaction on Nitrogen PowerPoint PPT Presentation

Electrophilic Reaction on Nitrogen - 6-membered rings - electron deficient - reactive in Nu-fil. Ar subst. 2 / 4 Pos. ... Metal - Halogen Exchange. R-Li: Alkyllithium, NOT LDA etc. ...

6-membered rings - electron deficient - reactive in Nu-fil. Ar subst. 2 / 4 Pos. ... Metal - Halogen Exchange. R-Li: Alkyllithium, NOT LDA etc. ...

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Electrophilic Aromatic Substitution - Electrophilic Aromatic Substitution. The most important reaction of benzene. Rate determining step is addition by the electrophile ...

Electrophilic Aromatic Substitution. The most important reaction of benzene. Rate determining step is addition by the electrophile ...

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Alkenes and Electrophilic Addition PowerPoint PPT Presentation

Alkenes and Electrophilic Addition - New Way Chemistry for Hong Kong A-Level Book 3A. New Way Chemistry for Hong Kong ... Trigonal planar geometry. Bond angle = 120o. The C=C double bond in ethene ...

New Way Chemistry for Hong Kong A-Level Book 3A. New Way Chemistry for Hong Kong ... Trigonal planar geometry. Bond angle = 120o. The C=C double bond in ethene ...

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Benzene and Electrophilic Substitution PowerPoint PPT Presentation

Benzene and Electrophilic Substitution - 29.2 Nomenclature of the Derivatives of Benzene. 29.3 Structure of Benzene and ... Benzo(a)pyrene (C20H12) New Way Chemistry for Hong Kong A-Level Book 3A. 45 ...

29.2 Nomenclature of the Derivatives of Benzene. 29.3 Structure of Benzene and ... Benzo(a)pyrene (C20H12) New Way Chemistry for Hong Kong A-Level Book 3A. 45 ...

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Electrophilic Aromatic Substitution - In an electrophilic aromatic substitution reaction, a hydrogen atom is replaced ... The nitronium ion (NO2 ) is the reactive electrophile in this reaction ...

In an electrophilic aromatic substitution reaction, a hydrogen atom is replaced ... The nitronium ion (NO2 ) is the reactive electrophile in this reaction ...

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16. Chemistry of Benzene: Electrophilic Aromatic Substitution PowerPoint PPT Presentation

16. Chemistry of Benzene: Electrophilic Aromatic Substitution - 16. Chemistry of Benzene: Electrophilic Aromatic Substitution Substitution Reactions of Benzene and Its Derivatives Benzene is aromatic: a cyclic conjugated compound ...

16. Chemistry of Benzene: Electrophilic Aromatic Substitution Substitution Reactions of Benzene and Its Derivatives Benzene is aromatic: a cyclic conjugated compound ...

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Chapter 12 Reactions of Arenes: Electrophilic Aromatic Substitution PowerPoint PPT Presentation

Chapter 12 Reactions of Arenes: Electrophilic Aromatic Substitution - EAS in Naphthalene When attack is at C-1, carbocation is stabilized by allylic resonance and benzenoid character of other ring is maintained.

EAS in Naphthalene When attack is at C-1, carbocation is stabilized by allylic resonance and benzenoid character of other ring is maintained.

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Electrophilic Aromatic Substitution - ... Directing effects of substituents already on the ring. Products of Nitration ... Substituents that make the ring react faster (than benzene) with electrophiles ...

... Directing effects of substituents already on the ring. Products of Nitration ... Substituents that make the ring react faster (than benzene) with electrophiles ...

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Chap 15 Electrophilic aromatic substitution (???????) PowerPoint PPT Presentation

Chap 15 Electrophilic aromatic substitution (???????) - These reactions are of the general type shown below; E -Electrophilic reagent ???? ... Fluorine (F2) reacts so rapidly with benzene that aromatic fluorination requires ...

These reactions are of the general type shown below; E -Electrophilic reagent ???? ... Fluorine (F2) reacts so rapidly with benzene that aromatic fluorination requires ...

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Electrophilic Aromatic Substitution - ... G may stabilize the carbocation intermediate and therefore speed the reaction, or it may raise the energy of the carbocation and slow the reaction.

... G may stabilize the carbocation intermediate and therefore speed the reaction, or it may raise the energy of the carbocation and slow the reaction.

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Chapter 12 Reactions of Arenes: Electrophilic Aromatic Substitution - Title: Organic Chemistry Fifth Edition Subject: Sections 12.1-12.8 Author: Frank Carey Last modified by: smpibm Created Date: 8/14/2000 8:05:35 PM Document ...

Title: Organic Chemistry Fifth Edition Subject: Sections 12.1-12.8 Author: Frank Carey Last modified by: smpibm Created Date: 8/14/2000 8:05:35 PM Document ...

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16. Chemistry of Benzene: Electrophilic Aromatic Substitution - 16. Chemistry of Benzene: Electrophilic Aromatic Substitution Based on McMurry s Organic Chemistry, 7th edition * 16.9 Oxidation of Aromatic Compounds Alkyl side ...

16. Chemistry of Benzene: Electrophilic Aromatic Substitution Based on McMurry s Organic Chemistry, 7th edition * 16.9 Oxidation of Aromatic Compounds Alkyl side ...

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16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 1 PowerPoint PPT Presentation

16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 1 - 16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 1 Based on McMurry s Organic Chemistry, 6th edition, Chapter 16 Substitution Rxns of Benzene ...

16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 1 Based on McMurry s Organic Chemistry, 6th edition, Chapter 16 Substitution Rxns of Benzene ...

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Chapter 12 (Part a) Reactions of Arenes: Electrophilic Aromatic Substitution PowerPoint PPT Presentation

Chapter 12 (Part a) Reactions of Arenes: Electrophilic Aromatic Substitution - Title: Carey Chapter 12 Aromatic Sub. Author: Monte Wolf Last modified by: mwolf Created Date: 8/14/2000 8:05:35 PM Document presentation format: On-screen Show (4:3)

Title: Carey Chapter 12 Aromatic Sub. Author: Monte Wolf Last modified by: mwolf Created Date: 8/14/2000 8:05:35 PM Document presentation format: On-screen Show (4:3)

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6.4 Electrophilic Addition of Hydrogen Halides to Alkenes PowerPoint PPT Presentation

6.4 Electrophilic Addition of Hydrogen Halides to Alkenes - Electrophilic Addition of Hydrogen Halides to Alkenes Electrophilic addition of hydrogen halides to alkenes proceeds by rate-determining formation of a carbocation ...

Electrophilic Addition of Hydrogen Halides to Alkenes Electrophilic addition of hydrogen halides to alkenes proceeds by rate-determining formation of a carbocation ...

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Electrophilic Addition to Alkenes PowerPoint PPT Presentation

Electrophilic Addition to Alkenes - Electrophilic Addition to Alkenes. Electrophile - chemical species that is electron deficient ' ... is one of the best electrophiles - just a proton. This is ...

Electrophilic Addition to Alkenes. Electrophile - chemical species that is electron deficient ' ... is one of the best electrophiles - just a proton. This is ...

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Electrophilic Aromatic Substitution Part 1 PowerPoint PPT Presentation

Electrophilic Aromatic Substitution Part 1 - How to solve this problem? Make Br2 more electrophilic. Aromatic. Not aromatic. FeBr3 ... Other Electrophiles: Friedel-Crafts Acylation. Write out the complete ...

How to solve this problem? Make Br2 more electrophilic. Aromatic. Not aromatic. FeBr3 ... Other Electrophiles: Friedel-Crafts Acylation. Write out the complete ...

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Steric hindrance at the electrophilic carbon slows the SN2 reaction. PowerPoint PPT Presentation

Steric hindrance at the electrophilic carbon slows the SN2 reaction. - PowerPoint Presentation

PowerPoint Presentation

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Electrophilic substitution in pyrrole, furan and thiophene PowerPoint PPT Presentation

Electrophilic substitution in pyrrole, furan and thiophene - Electrophilic substitution in pyrrole, furan and thiophene X = O, NH, or S Examples: Furan is able to act as a diene in the reactions of cycloaddition The Fisher ...

Electrophilic substitution in pyrrole, furan and thiophene X = O, NH, or S Examples: Furan is able to act as a diene in the reactions of cycloaddition The Fisher ...

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Substitution Reactions of Benzene and Its Derivatives: Electrophilic Addition/Elimination Reactions. PowerPoint PPT Presentation

Substitution Reactions of Benzene and Its Derivatives: Electrophilic Addition/Elimination Reactions. - Substitution Reactions of Benzene and Its Derivatives: Electrophilic Addition/Elimination Reactions. Benzene is aromatic: a cyclic conjugated compound with 6 electrons

Substitution Reactions of Benzene and Its Derivatives: Electrophilic Addition/Elimination Reactions. Benzene is aromatic: a cyclic conjugated compound with 6 electrons

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Chemistry of Benzene. Aromatic Electrophilic Substitution PowerPoint PPT Presentation

Chemistry of Benzene. Aromatic Electrophilic Substitution - 1. Nomenclature and physical ... Conjugation between p-orbitals is depicted by resonance structures ... Conjugation, involving s-orbitals, is depicted by ...

1. Nomenclature and physical ... Conjugation between p-orbitals is depicted by resonance structures ... Conjugation, involving s-orbitals, is depicted by ...

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Chapter 7 Electrophilic and Nucleophilic Addition and Abstraction PowerPoint PPT Presentation

Chapter 7 Electrophilic and Nucleophilic Addition and Abstraction - The electrophile can either add first to the metal center, or directly to the ligand. ... Depending on the electrophile, addition to a Cp ring of ferrocene can either ...

The electrophile can either add first to the metal center, or directly to the ligand. ... Depending on the electrophile, addition to a Cp ring of ferrocene can either ...

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Chapter 12 Reactions of Arenes: Electrophilic Aromatic Substitution - Y. H. Y. d d. 12.1. Representative Electrophilic Aromatic Substitution ... Rearrangements in Friedel-Crafts Alkylation. Carbocations are intermediates. ...

Y. H. Y. d d. 12.1. Representative Electrophilic Aromatic Substitution ... Rearrangements in Friedel-Crafts Alkylation. Carbocations are intermediates. ...

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Alkenes:Electrophilic addition and carbocation rearrangement McM 6'12 PowerPoint PPT Presentation

Alkenes:Electrophilic addition and carbocation rearrangement McM 6'12 - Alkenes: Electrophilic addition and carbocation rearrangement (McM 6.12) ... Polymerization of alkenes (McM 7.10) Radical polymerization. Cationic polymerization ...

Alkenes: Electrophilic addition and carbocation rearrangement (McM 6.12) ... Polymerization of alkenes (McM 7.10) Radical polymerization. Cationic polymerization ...

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16' Chemistry of Benzene: Electrophilic Aromatic Substitution - Reactions of benzene lead to the retention of the aromatic core ... Benzene with acetyl chloride yields acetophenone. Mechanism of Friedel-Crafts Acylation ...

Reactions of benzene lead to the retention of the aromatic core ... Benzene with acetyl chloride yields acetophenone. Mechanism of Friedel-Crafts Acylation ...

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Electrophilic attack on conjugated dienes PowerPoint PPT Presentation

Electrophilic attack on conjugated dienes - More stable since the double bond. bears more substituents. Less ... Diene dienophile adduct. 7. Diene dienophile adduct. Either diene or dienophile must have ...

More stable since the double bond. bears more substituents. Less ... Diene dienophile adduct. 7. Diene dienophile adduct. Either diene or dienophile must have ...

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Electron flow during the electrophilic addition mechanism PowerPoint PPT Presentation

Electron flow during the electrophilic addition mechanism - Presentation illustrating electron flow during electrophilic addition. First a sequence of s animates the process and can be controlled manually, then an ...

Presentation illustrating electron flow during electrophilic addition. First a sequence of s animates the process and can be controlled manually, then an ...

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12.9 Rate and Regioselectivity in Electrophilic Aromatic Substitution PowerPoint PPT Presentation

12.9 Rate and Regioselectivity in Electrophilic Aromatic Substitution - Electrophilic Aromatic Substitution. A substituent already ... electrophile to positions ortho and/or. para to themselves. Meta directors direct an incoming ...

Electrophilic Aromatic Substitution. A substituent already ... electrophile to positions ortho and/or. para to themselves. Meta directors direct an incoming ...

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Substituent Effects: Electrophilic Aromatic Substitution PowerPoint PPT Presentation

Substituent Effects: Electrophilic Aromatic Substitution - Substituents that withdraw electrons from the benzene ring will destabilize the ... a pale yellow solid, melts at 83 C, and explodes at 240 C. Supplying TNT with ...

Substituents that withdraw electrons from the benzene ring will destabilize the ... a pale yellow solid, melts at 83 C, and explodes at 240 C. Supplying TNT with ...

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12.12 Substituent Effects in Electrophilic Aromatic Substitution: Activating Substituents PowerPoint PPT Presentation

12.12 Substituent Effects in Electrophilic Aromatic Substitution: Activating Substituents - Title: Organic Chemistry Fifth Edition Subject: Sections 12.12-12.14 Author: Frank Carey Last modified by: smpibm Created Date: 8/15/2000 4:05:16 PM

Title: Organic Chemistry Fifth Edition Subject: Sections 12.12-12.14 Author: Frank Carey Last modified by: smpibm Created Date: 8/15/2000 4:05:16 PM

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16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 2 PowerPoint PPT Presentation

16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 2 - 16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 2 Based on McMurry s Organic Chemistry, 6th edition, Chapter 16 * Reaction of Disubstituted ...

16. Chemistry of Benzene: Electrophilic Aromatic Substitution Part 2 Based on McMurry s Organic Chemistry, 6th edition, Chapter 16 * Reaction of Disubstituted ...

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Chapter 3. Reactions of Alkenes 3.1. Electrophilic Addition PowerPoint PPT Presentation

Chapter 3. Reactions of Alkenes 3.1. Electrophilic Addition - Chapter 3. Reactions of Alkenes 3.1. Electrophilic Addition reactions on carbon-carbon double bonds General reaction pattern: Incorporation of an electrophile by the C=C.

Chapter 3. Reactions of Alkenes 3.1. Electrophilic Addition reactions on carbon-carbon double bonds General reaction pattern: Incorporation of an electrophile by the C=C.

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Chapter 12 Electrophilic Aromatic Substitution rxns sections 12'312'7 PowerPoint PPT Presentation

Chapter 12 Electrophilic Aromatic Substitution rxns sections 12'312'7 - Problems with the Friedel-Crafts Alkylation Reaction ( ref. Sections 12.6 & 12.8) H ... RCCl. O. Zn(Hg), HCl. CH2R. Acylate the ring , then reduce the carbonyl ...

Problems with the Friedel-Crafts Alkylation Reaction ( ref. Sections 12.6 & 12.8) H ... RCCl. O. Zn(Hg), HCl. CH2R. Acylate the ring , then reduce the carbonyl ...

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12.13 Substituent Effects in Electrophilic Aromatic Substitution: Strongly Deactivating Substituents PowerPoint PPT Presentation

12.13 Substituent Effects in Electrophilic Aromatic Substitution: Strongly Deactivating Substituents - ... are meta directing and strongly deactivating. Many EWGs Have a Carbonyl Group ... the net effect is that halogens are deactivating but ortho-para directing ...

... are meta directing and strongly deactivating. Many EWGs Have a Carbonyl Group ... the net effect is that halogens are deactivating but ortho-para directing ...

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Functionalized Diaziridines as Potential Electrophilic Aziridinating Agents PowerPoint PPT Presentation

Functionalized Diaziridines as Potential Electrophilic Aziridinating Agents - ... Aziridinating Agents. Katherine L. Hervert, Department of Chemistry, Ohio Wesleyan University. The facile alkene oxidation to an epoxide is an excellent ...

... Aziridinating Agents. Katherine L. Hervert, Department of Chemistry, Ohio Wesleyan University. The facile alkene oxidation to an epoxide is an excellent ...

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Organic reaction mechanisms PowerPoint PPT Presentation

Organic reaction mechanisms - Click a box below to go to the mechanism Click here for advice Homolytic Free Radical Substitution Free Radical Addition Heterolytic Electrophilic Addition

Click a box below to go to the mechanism Click here for advice Homolytic Free Radical Substitution Free Radical Addition Heterolytic Electrophilic Addition

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H - Aromatic ring is ACTIVATED and undergoes electrophilic ... Ring Nomenclature: G. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ? ...

Aromatic ring is ACTIVATED and undergoes electrophilic ... Ring Nomenclature: G. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ?. H. G. ? ...

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21_Lecture.ppt PowerPoint PPT Presentation

21_Lecture.ppt - The nitrogen withdraws electrons by resonance, resulting in an electron-deficient ring system. * Pyridine undergoes electrophilic aromatic substitution at C-3: ...

The nitrogen withdraws electrons by resonance, resulting in an electron-deficient ring system. * Pyridine undergoes electrophilic aromatic substitution at C-3: ...

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Functional Group PowerPoint PPT Presentation

Functional Group - Electrophilic Addition Reactions ... Electrophile a reactant attracted to the region of high electron density ... Predominant reaction electrophilic substitution ...

Electrophilic Addition Reactions ... Electrophile a reactant attracted to the region of high electron density ... Predominant reaction electrophilic substitution ...

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CONTENTS - ARENES CONTENTS Prior knowledge Structure of benzene Thermodynamic stability Delocalisation Electrophilic substitution Nitration Chlorination Friedel-Crafts reactions

ARENES CONTENTS Prior knowledge Structure of benzene Thermodynamic stability Delocalisation Electrophilic substitution Nitration Chlorination Friedel-Crafts reactions

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Organic Chemistry PowerPoint PPT Presentation

Organic Chemistry - Prob 21.21 Which ring in each compound undergoes electrophilic aromatic substitution more readily? Draw the product of nitration of each compound.

Prob 21.21 Which ring in each compound undergoes electrophilic aromatic substitution more readily? Draw the product of nitration of each compound.

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Criteria for Aromaticity PowerPoint PPT Presentation

Criteria for Aromaticity - Basis for Electrophilic Aromatic Substitution. Electrophile attack on electron-rich aromatic ring ... Electrophilic Aromatic Substitution. Nitration ...

Basis for Electrophilic Aromatic Substitution. Electrophile attack on electron-rich aromatic ring ... Electrophilic Aromatic Substitution. Nitration ...

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AQA organic reaction mechanisms PowerPoint PPT Presentation

AQA organic reaction mechanisms - Electrophilic Substitution. Nucleophilic Addition. Nucleophilic ... 1. Formation of the electrophile (an acylium ion) AlCl3. Cl AlCl3. With ethanoyl chloride ...

Electrophilic Substitution. Nucleophilic Addition. Nucleophilic ... 1. Formation of the electrophile (an acylium ion) AlCl3. Cl AlCl3. With ethanoyl chloride ...

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Aromatic Substitution PowerPoint PPT Presentation

Aromatic Substitution - Substituent Effects on Electrophilic Aromatic Substitution meta-Directing Substituents ortho-para-Directing Groups ... that the nitro substituent is a meta director.

Substituent Effects on Electrophilic Aromatic Substitution meta-Directing Substituents ortho-para-Directing Groups ... that the nitro substituent is a meta director.

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Reactions of Aromatic Compounds PowerPoint PPT Presentation

Reactions of Aromatic Compounds - Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Electrophile substitutes for a hydrogen on the benzene ring. Mechanism Bromination of Benzene ...

Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Electrophile substitutes for a hydrogen on the benzene ring. Mechanism Bromination of Benzene ...

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Benzene - Benzene Part 1 ELECTROPHILIC SUBSTITUTION Theory The high electron density of the ring makes it open to attack by electrophiles Addition to the ring would upset ...

Benzene Part 1 ELECTROPHILIC SUBSTITUTION Theory The high electron density of the ring makes it open to attack by electrophiles Addition to the ring would upset ...

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CH 16: Chemistry of Benzene PowerPoint PPT Presentation

CH 16: Chemistry of Benzene - CH 16: Chemistry of Benzene Renee Y. Becker CHM 2211 Valencia Community College * Nucleophilic Aromatic Substitution * No Mechanism Electrophilic and Nucleophilic ...

CH 16: Chemistry of Benzene Renee Y. Becker CHM 2211 Valencia Community College * Nucleophilic Aromatic Substitution * No Mechanism Electrophilic and Nucleophilic ...

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Chapter 17: Aldehydes and Ketones: Nucleophilic Addition PowerPoint PPT Presentation

Chapter 17: Aldehydes and Ketones: Nucleophilic Addition - Carbonyl carbons are electrophilic sites and can be attacked ... Friedel-Craft Acylation (12.7) - aryl ketones. 5. Hydroformylation of alkenes (please read) ...

Carbonyl carbons are electrophilic sites and can be attacked ... Friedel-Craft Acylation (12.7) - aryl ketones. 5. Hydroformylation of alkenes (please read) ...

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Mass Spectral Data of the Products from Unknowns A-D PowerPoint PPT Presentation

Mass Spectral Data of the Products from Unknowns A-D - Chemistry 283g- Experiment 5 Electrophilic Aromatic Substitution: A Friedel-Craft Acylation Reaction IR Spectral Data of the Unknowns A-D Mass Spectral Data of the ...

Chemistry 283g- Experiment 5 Electrophilic Aromatic Substitution: A Friedel-Craft Acylation Reaction IR Spectral Data of the Unknowns A-D Mass Spectral Data of the ...

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AQA organic reaction mechanisms - Click a box below to go to the mechanism Click here for advice AS Free Radical Substitution Electrophilic Addition Nucleophilic Substitution (nitrile hydrolysis reaction)

Click a box below to go to the mechanism Click here for advice AS Free Radical Substitution Electrophilic Addition Nucleophilic Substitution (nitrile hydrolysis reaction)

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Nitration of Methyl Benzoate PowerPoint PPT Presentation

Nitration of Methyl Benzoate - Nitration of Methyl Benzoate. Purpose. In this experiment a cold solution of an aromatic ... The nitration is a typical electrophilic substitution reaction. ...

Nitration of Methyl Benzoate. Purpose. In this experiment a cold solution of an aromatic ... The nitration is a typical electrophilic substitution reaction. ...

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Organic Chemistry Fifth Edition PowerPoint PPT Presentation

Organic Chemistry Fifth Edition - Aldol Condensation of Butanal. dehydration of -hydroxy aldehyde can be ... Electrophilic Alkenes. Termite Self-Defense! 18.12. Conjugate Addition to ...

Aldol Condensation of Butanal. dehydration of -hydroxy aldehyde can be ... Electrophilic Alkenes. Termite Self-Defense! 18.12. Conjugate Addition to ...

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Electrophilic PowerPoint PPT Presentations