Title: Hazardous Waste Classification in California
1Hazardous Waste Classification in California
- Corey Yep
- Waste Identification and Recycling Section
- State Regulatory Programs Division
- Hazardous Waste Management Program
- Department of Toxic Substances Control
2Purpose of Course
- To introduce the basic concepts of hazardous
waste classification criteria in California
3Objectives
- Understand the term waste
- Understand exclusions and exemptions that may
apply - Understand what the hazardous waste listings and
characteristics are
4Waste Classification Requirements
- Two sets of standards in CA
- Federal requirements
- State requirements
5Federal Requirements
- Statute Chapter 42, United States Code
(Resource Conservation and Recovery Act or RCRA) - (on line at http//uscode.house.gov/usc.htm)
- Regulations Title 40, Code of Federal
Regulations (40 CFR) - (on line at http//www.epa.gov/epahome/cfr40toc.ht
m)
6State Requirements
- Statute California Health and Safety Code,
Division 20, Chapter 6.5, Hazardous Waste Control
Law - (on line at http//www.leginfo.ca.gov/calaw.html)
- Regulations California Code of Regulations,
Division 4.5, Title 22 - (on line at http//www.calregs.com/)
7State Requirements
- Important Note Unlike the federal requirements,
in California both statutes and regulations
contain specific requirements
8California is a federally authorized state
- Generally, Californias requirements contain all
hazardous waste requirements that apply in
California - Most newly adopted federal regulations do not
apply in California until California adopts them
9Definition of Hazardous Waste 25117 HSC
- Hazardous Waste
- waste that meets criteria adopted by DTSC
pursuant to 25141 HSC - includes RCRA hazardous wastes
10Hazardous Waste Criteria25141 HSC
- Criteria shall identify wastes because of its
quantity, concentration, or physical, chemical or
infectious characteristics - causes or significantly contributes to an
increase in mortality, serious irreversible or
incapacitating reversible illness - pose substantial present or potential hazard to
human health or the environment, due to
carcinogenicity, acute or chronic toxicity,
bioaccumulative properties, or persistence in the
environment, when improperly treated, stored,
transported, or disposed of, or otherwise managed
11Chapter 11 - Identification and Listing of
Hazardous Wastes
- Article 1
- General Provisions
- Definition of Waste
- Definition of Hazardous Waste
- Article 2
- Criteria for Identifying the Characteristics of
Hazardous Waste
12Chapter 11 - Identification and Listing of
Hazardous Wastes
- Article 3
- Characteristics of Hazardous Waste
- Article 4
- Lists of RCRA Hazardous Wastes
- Article 5
- Categories of Hazardous Waste
13Waste Classification Process
14Overview of the waste classification process
- Is the material a waste?
- Is the material excluded or exempted?
- Is the waste excluded or exempted?
- Is the waste listed in Article 4?
- Is the waste listed in Appendix X?
- Does the waste exhibit a characteristic of
hazardous waste?
15Waste Laypersons definition
- A material that has been used or has otherwise
served its intended purpose and, for whatever
reason (contaminated, spent, or intent) can or
will no longer be used for its intended purpose
16Definition of Waste25124 HSC 66261.2 22 CCR
- A waste is any discarded material (in any
physical form, such as solid, liquid, semi-solid,
contained gas) that is not excluded by
66261.4(a), 66261.4(e), or 25143.2(b) or
25143.2(d)
17Discarded22 CCR 66261.2(b)
- A material is discarded if it is
- Relinquished
- Recycled
- Inherently waste-like
18Relinquished22 CCR 66261.2(c)
- A material is relinquished if it is
- disposed of
- burned or incinerated
- accumulated, stored or treated (but not recycled)
before, or in lieu of, being relinquished
19Recycled22 CCR 66261.2(d)
- A material is a waste if it is recycled (or
accumulated, stored or treated prior to
recycling) if it is - used in a manner constituting disposal (placed
on land) - burned for energy recovery
- reclaimed
- accumulated speculatively
20Inherently Waste-like22 CCR 66261.2(e)
- A material is a waste if it is inherently
waste-like when it is recycled - RCRA waste codes F020, F021, F022, F023, F026 and
F028 (contain dioxins) - secondary materials fed to a halogen acid furnace
21Packaging/Labeling 22 CCR 66261.2(f)
- Materials are also wastes if they are
- mislabeled or inadequately labeled, unless
labeled correctly within 10 days - in a deteriorated or damaged container, unless
repackaged within 96 hours - Must pose a threat to human health or the
environment
22Waste Exclusions 25124 HSC
- Materials that are not discarded
- Intermediate manufacturing process streams
- Coolants, lubricants or cutting fluids that are
filtered to extend their useful life
23Waste Exclusions 25143.2 HSC
- Certain recyclable materials
- ingredients in industrial processes
- substitutes for commercial products
- returned to original process w/out reclamation
- recycled/reused onsite
24Waste Exclusions 22 CCR 66261.4(a)
- Materials that are not wastes
- Point source discharges subject to CWA (NPDES
permits) - Nuclear wastes
- Spent sulfuric acid used to produce virgin
sulfuric acid - reclaimed pulping liquors
- reclaimed secondary materials returned to
original process
25Overview of hazardous waste classification
- Is the material a waste?
- Is the material excluded or exempted?
- Is the waste excluded or exempted?
- Is the waste listed in Article 4?
- Is the waste listed in Appendix X?
- Does the waste exhibit a characteristic of
hazardous waste?
26Hazardous Waste Exclusions 22 CCR 66261.4(b)
- Wastes that are not hazardous wastes
- Infectious wastes (animal carcasses)
- Wastes excluded under 40 CFR 261.4
- Used oil re-refining still bottoms used in
asphalt products - Used CFCs that are reclaimed
- Mining wastes
27Hazardous Waste Exclusions 22 CCR
66261.4(b)Wastes excluded under 261.4(b),
unless the waste also exhibits an Article 3
characteristic
- Household wastes
- Agricultural wastes used as fertilizers
- Mining overburden
- Fossil fuel combustion wastes
- Trivalent chromium wastes (leather tanning)
- Mining wastes
- Cement kiln dust
- Arsenic treated wood
- And more...
28Hazardous Waste Exemptions22 CCR 66261.4(c-g)
- materials in product or raw material storage
tanks are exempt until removed (within 90 days of
ceasing operation) - samples - subject to regulation as a waste after
use as a sample ceases - treatability study samples for generator and labs
- controlled substances
29Statutory Exclusions/Exemptions
25141.5(b)(2)(B) HSC
- These wastes are not hazardous wastes if only
hazardous by oral LD50 criteria -
acetic acid calcium fluoride aluminum
chloride calcium formate ammonium bromide calcium
propionate ammonium sulfate cesium
chloride anisole magnesium chloride boric
acid potassium chloride
30Statutory Exclusions/Exemptions
25141.5(b)(2)(B) HSC
- These wastes are not hazardous wastes if only
hazardous by oral LD50 criteria -
sodium bicarbonate food flavoring oils sodium
borate allspice oil decahydrate ceylon
cinnamon oil sodium carbonate clarified
slurry oil sodium chloride dill oils sodium
iodide lauryl leaf oils sodium tetraborate
31Statutory Exclusions/Exemptions 25141.5(b)(3)(A)
HSC
- Effective January 1, 1996
- Excluded from hazardous waste classification for
disposal purposes only - Hazardous only because of Total Threshold Limit
Concentration
32Statutory Exclusions/Exemptions
25141.5(b)(3)(A) HSC
- Must follow predisposal hazardous waste
management requirements in regulations adopted by
DTSC - Does not apply to
- liquids, sludges, sludge-likes, soils, finely
divided or tarry materials - organic constituents
33Statutory Exclusions/Exemptions 25143.1 HSC
- Geothermal drilling wastes
- Mining wastes
- still subject to TPCA
- still subject to Ch. 6.8, HSC
34Statutory Exclusions/Exemptions 25143.1.5 HSC
- Treated wood wastes
- Effective January 1, 1996
- treated wood wastes exclusively from electric,
gas or telephone service - must be disposed in a landfill that is authorized
to accept treated wood wastes
35Statutory Exclusions/Exemptions 25143.8 HSC
- Cementitious materials
- effective January 1, 1996
- cement, cement kiln dust, clinker, clinker dust
- not required to be tested for solid corrosivity
- if hazardous solely due to corrosivity for
solids, excluded from classification as
hazardous waste
36Statutory Exclusions/Exemptions 25143.12 HSC
- Petroleum contaminated debris if
- wood, paper, textiles, concrete rubble, metallic
objects, solid manufactured objects - not Federally regulated
- does not contain free liquids
- disposed in Class I or II landfill
37Statutory Exclusions/Exemptions
- Asbestos wastes
- 25143.7 HSC
- may be disposed in a landfill that is not Class I
- Biohazardous waste
- 25117.5 and 117635 HSC
- formaldehyde fixed human surgery specimens or
tissues - Wastes contaminated with chemotherapeutic agents
- pharmaceuticals
38Hazardous Waste Exemptions 22 CCR 66261.7
- Contaminated containers
- Exempted if empty
- RCRA empty
- Empty containers are not hazardous wastes
- Residues remaining in empty containers are not
hazardous wastes - Still a CA hazardous waste unless CA empty too
- California empty
39California empty
- Containers empty when
- Pourable wastes no longer pour when container
inverted - Nonpourable wastes are scraped or otherwise
removed - 5 gallons or smaller - destroyed and disposed
- Larger than 5 gallons - reclaimed for scrap
value, reconditioned, remanufactured, or refilled - Aerosols if completely discharged of contents and
propellant
40Waste Classification Process
- Hazardous Waste Identification
- Listings
41Overview of hazardous waste classification
- Is the material a waste?
- Is the material excluded or exempted?
- Is the waste excluded or exempted?
- Is the waste listed in Article 4?
- Is the waste listed in Appendix X?
- Does the waste exhibit a characteristic of
hazardous waste?
42Listed Hazardous Wastes 22 CCR Article 4
- A waste is compared to the wastes described in
the list - The source of the waste (i.e., the process that
generated the waste) is more important than the
wastes characteristics or constituents - must meet all conditions of the listing
43Three categories of lists
- 1. Non-specific sources (F)
- 2. Specific sources (K)
- 3. Discarded commercial chemical products,
off-specification species, and spill residues (P,
U)
44Overview of hazardous waste classification
- Is the material a waste?
- Is the material excluded or exempted?
- Is the waste excluded or exempted?
- Is the waste listed in Article 4?
- Is the waste listed in Appendix X?
- Does the waste exhibit a characteristic of
hazardous waste?
45Appendix X
- List of 791 chemicals
- List of 66 common names or types of hazardous
wastes - List creates a presumption
- Wastes listed or containing a listed chemical are
presumed hazardous - Can be classified as nonhazardous using testing
or knowledge, as with other wastes
46Waste Classification Process
- Hazardous Waste Identification
- Characteristics
47Overview of hazardous waste classification
- Is the material a waste?
- Is the material excluded or exempted?
- Is the waste excluded or exempted?
- Is the waste listed in Article 4?
- Is the waste listed in Appendix X?
- Does the waste exhibit a characteristic of
hazardous waste?
48Characteristics of Hazardous Wastes22 CCR
Article 3
- Ignitability
- Corrosivity
- Reactivity
- Toxicity
49Ignitability 22 CCR 66261.21
- Liquid with a flashpoint lt 140F (60C)
- Not a liquid and is capable, under STP, of
causing fire through friction, absorption of
moisture or spontaneous chemical changes and,
when ignited, burns so vigorously and
persistently that it creates a hazard - Ignitable compressed gas
- Oxidizer
50Corrosivity 22 CCR 66261.22
- pH
- Aqueous solution with a pH ? 2 or gt 12.5
- Not aqueous and, when mixed with an equal weight
of water, has pH ? 2 or gt 12.5 (CA only)
51Corrosivity 22 CCR 66261.22
- Steel corrosion rate
- Liquid that corrodes steel at a rate greater than
6.35mm per year - Not liquid, and, when mixed with an equal weight
of water, corrodes steel at a rate greater than
6.35mm per year (CA only)
52Reactivity 22 CCR 66261.23
- explode or react violently when exposed to water
or under normal handling conditions - create toxic fumes or gases when exposed to water
or under common handling conditions - meets the criteria for classification as an
explosive under Department of Transportation
rules.
53Toxicity 22 CCR 66261.24
- Extractable Constituents
- Toxicity Characteristic Leaching Procedure (TCLP)
- Persistent and Bioaccumulative Toxic Substances
- Waste Extraction Test (WET)
- Total Concentration
- The TCLP is not interchangeable with the WET or
the total analysis.
54 TCLP WET
TCLP vs. WET
- Simulated landfill leachate
- Acetic acid extractant
- 18 hour extraction
- 8 inorganic constituents
- 23 organic constituents
- less aggressive for inorganic constituents
- zero headspace extractor for volatile organic
compounds
- Simulated landfill leachate
- Citric acid extractant
- 48 hour extraction
- 19 inorganic constituents
- 18 organic constituents
- more aggressive for inorganic constituents
- not necessary for organic compounds
55Federal Toxicity Characteristic 22 CCR
66261.24(a)(1)
- D004 Arsenic
- D005 BariumÂ
- D018 BenzeneÂ
- D006 CadmiumÂ
- D019 Carbon tetrachlorideÂ
- D020 ChlordaneÂ
- D021 ChlorobenzeneÂ
- D022 Chloroform
- D007 ChromiumÂ
- D023 o-Cresol
- D024 m-CresolÂ
- D025 p-CresolÂ
- D026 Cresol
- D016 2,4-DÂ
- D027 1,4-Dichloro- benzene
- D028 1,2-Dichloro- ethane
56Federal Toxicity Characteristic 22 CCR
66261.24(a)(1)
- D029 1,1 DichloroethyleneÂ
- D030 2,4 DinitrotolueneÂ
- D012 Endrin Â
- D031 Heptachlor (and its epoxide)Â
- D032 HexachlorobenzeneÂ
- D033 Hexachlorobu- tadieneÂ
- D034 HexachloroethaneÂ
- D008 LeadÂ
- D013 LindaneÂ
- D009 MercuryÂ
- D014 MethoxychlorÂ
- D035 Methyl ethyl ketone
- D036 NitrobenzeneÂ
- D037 Pentachlorophenol
57Federal Toxicity Characteristic 22 CCR
66261.24(a)(1)
- D041 2,4,5 Trichloro- phenol
- D042 2,4,6 Trichloro- phenolÂ
- D017 2,4,5-TP (Silvex)Â
- D043 Vinyl chloride
- D038 PyridineÂ
- D010 Selenium
- Â D011 Silver Â
- D039 Tetrachloro- ethylene
- D015 ToxapheneÂ
- D040 Trichloro- ethyleneÂ
58Federal Toxicity Characteristic 22 CCR
66261.24(a)(1)
- Each constituent has a Regulatory Threshold (RT)
- If the measured concentration in the TCLP extract
equals or exceeds the RT, the waste is toxic and
hazardous - Wastes hazardous for a particular constituent are
identified by that waste code
59Persistent and Bioaccumulative Toxic Substances
22 CCR 66261.24(a)(2)
- Inorganic constituents
- Both WET soluble and total concentrations
- Organic constituents
- Both WET soluble and total concentrations
60Inorganic Constituents 22 CCR 66261.24(a)(2)(A)
- Antimony
- Arsenic
- Asbestos
- Barium
- Beryllium
- Cadmium
- Chromium
- Chromium VI
- Silver
- Thallium
- Vanadium
- Zinc
- Cobalt
- Copper
- Fluoride Salts
- Lead
- Mercury
- Molybdenum
- Nickel
- Selenium
61Organic constituents 22 CCR 66261.24(a)(2)(B)
- PCBs
- Toxaphene
- Trichloro-
- ethylene
- 2,4,5-Tri-
- chloro phenoxy-propionic acid
- (Silvex)
- Aldrin
- Chlordane
- DDT,DDE, DDD
- 2,4-Dichlorophen
- oxyacetic acid
- Dieldren
- Dioxin
- (2,3,7,8-TCDD)
- Endrin
- Heptachlor
- Kepone
- Organic Lead Compounds
- Lindane
- Methoxychlor
- Mirex
- Pentachloro phenol
62Persistent and Bioaccumulative Toxic Substances
22 CCR 66261.24(a)(2)
- Toxic and hazardous if
- gt Soluble Threshold Limit Concentration (STLC) by
the WET (mg/L) - gt Total Threshold Limit Concentration (TTLC) by
analysis for total concentration in waste (mg/kg)
63WET versus TCLP
- Relationship between total concentrations and WET
and TCLP methods - WET method involves a 10-fold dilution of waste
to extractant fluid of solid portion of waste - TCLP method involves a 20-fold dilution of waste
to extractant fluid of solid portion of waste
64WET versus TCLP
- If the chemical in a solid waste is 100 soluble
in the waste, then the maximum extractable
concentration result would be - WET 1/10 the total concentration
- TCLP 1/20 the total concentration
65Example
- 530 mg/kg total lead concentration, the maximum
soluble results would be - WET 53 mg/l
- TCLP 26.5 mg/l
- Both federal and state soluble thresholds for
lead are 5 mg/l
66Acute Toxicity
- Oral Toxicity
- Dermal Toxicity
- Inhalation Toxicity
- Acute Aquatic Toxicity
67Acute Oral Toxicity 22 CCR 66261.24(a)(3)
- Effective January 1, 1997
- Waste is hazardous if oral LD50? 2500 mg/kg (
25141.5 HSC) - Regulations state oral LD50?
- 5000 mg/kg
68Acute Toxicity 22 CCR 66261.24(a)(4), (5) (6)
- Waste is hazardous if dermal LD50 ?4300 mg/kg
- Waste is hazardous if inhalation LC50 ? 10,000
ppm - Waste is Hazardous if acute aquatic toxicity
96-hour LC50 ? 500 mg/liter
69Carcinogenicity 22 CCR 66261.24(a)(7)
Hazardous if present in a waste in single or
combined concentration exceeding 0.001 (10 ppm)
- 2-acetylaminofluorene
- acrylonitrile
- 4-aminodiphenyl
- benzidine
- bis(chloromethyl)ether
- Methyl chloromethyl ether
- 1,2-dibromo-3-chloropropane
- 3,3-dichlorobenzidine
- Dimethylaminoazoben-zene
- ethyleneimine
- alpha-naphthylamine
- beta-naphthylamine
- 4-nitrobiphenyl
- N-nitrosodimethylamine
- beta-propiolactone
- vinyl chloride
70 Experience or Testing 22 CCR 66261.24(a)(8)
- Wastes shown through experience or testing to
pose a hazard - The criteria were not expected to capture all
possible wastes that could be hazardous - DTSC is required to modify Chapter 11 if a waste
is identified as hazardous using this section and
has statewide application ( 25141.5 HSC)
71Waste Classification Process
- Mixtures
- Characteristic
- RCRA Listed
- Derived From
- Contained In
72Mixture Rule
- Characteristic HW - nonRCRA and RCRA
- Evaluate the mixture for hazardous waste
characteristics - Intentional mixture to avoid regulation is
treatment, and requires authorization - Listed HW Mixtures
- RCRA listed hazardous wastes mixtures are
hazardous wastes - concentrations are irrelevant
- Exemptions
- delisted or listed only for characteristic (ex.
F003)
73Derived From Rule
- Wastes derived from the treatment, storage or
disposal - Characteristic Wastes
- Evaluate the mixture for HW characteristics
- RCRA or nonRCRA characteristic
- RCRA Listed Wastes
- hazardous waste, even if treatment destroyed
chemicals of concern - Exemption - delisted or listed only for
characteristic (ex. F003)
74Contained-in Policy
- Applies to contaminated media and debris
- Environmental media (water or soil) that contain
listed wastes are hazardous wastes - unless it is demonstrated that the listed waste
is present in insignificant concentrations
(risk-based evaluation)
75Hazardous Waste Categories
76Categories of Hazardous Wastes22 CCR Article 5
- RCRA Hazardous Wastes
- NonRCRA Hazardous Wastes
- Extremely Hazardous Wastes
- Special Wastes
- Other - Universal Wastes
- 22 CCR 66273
77Category Dictates
- Land disposal restrictions/treatment standards
- Fees
- Generator
- Disposal
- DTSC discretionary authority
- variances
- tiered permitting
78RCRA Hazardous Wastes22 CCR 66261.100
- Not excluded
- Listed (F,K,P,U lists)
- Ignitable
- Corrosive liquid
- Reactive
- Toxic (using TCLP)
- Wastes are presumed RCRA unless determined
otherwise
79NonRCRA Hazardous Wastes22 CCR 66261.101
- Not listed (F,K,P,U lists)
- Corrosive solid
- Toxic for anything except for federal toxicity
22 CCR 66261.24(a)(1) - Excluded under 40 CFR 261.4 and exhibits any of
the Article 3 criteria - Containers that are RCRA-empty but not
California-empty
80Extremely Hazardous Waste Criteria 22 CCR
66261.110
- Acute Oral Toxicity
- Extremely hazardous if LD50 ? 50 mg/kg
- Acute Dermal Toxicity
- Extremely hazardous if LD50 ? 43 mg/kg
- Acute Inhalation Toxicity
- Extremely hazardous if LC50 ? 100 ppm
- Carcinogenicity
- single or combined concentration gt 0.1 (1000
ppm)
81Extremely Hazardous Waste Criteria 22 CCR
66261.110 66261.113
- Experience or Testing
- Water Reactive
- Calculated Acute Toxicity
- Persistent and Bioaccumulative Toxic Substances
- Total concentrations only
- List and TTLCs differ from hazardous waste TTLCs
82Special Waste22 CCR 66261.120
- Subset of nonRCRA hazardous wastes
- Typically in larger waste volumes but pose lesser
hazards - NOT self implementing - a generator must apply to
DTSC to receive special waste classification - Eligible to be managed according to less
stringent standards (not automatic)
83Special Waste Criteria 22 CCR 66261.122
- Can be hazardous for only inorganic constituents
- Constituent concentrations may exceed their
respective STLCs or TTLCs - WET-soluble concentration (when expressed in
mg/kg) cannot exceed its TTLC value
84Special Waste Management 22 CCR 66261.126
- Waste can go into Class III landfill
- Landfill must have WDRs for special waste
- Landfill operator must have a variance from DTSC
85Universal Waste Rule 22 CCR 66273
- Fluorescent tubes, batteries, thermostats, CRTs
- Relaxed standards to encourage proper management,
recycling, and disposal - Emergency regulations - CRTs
86Universal Waste Rule 22 CCR 66273
- Final rule for fluorescent tubes, thermostats,
batteries - effective February 8, 2002
- household exemption sunset in 4 years
- small generators exemption - after 2 year a
reduction and then sunsets in 4 years
87Universal Waste Rule
- SB 633
- effective January 1, 2002
- mercury light switches removed from vehicles as
universal waste - 25214.6 HSC
- regulations are needed to clarify
88Universal Waste Rule
- AB 1158
- aerosol cans are universal waste
- 25201.16 HSC
- statutes are sufficiently clear for universal
waste management
89Waste Classification Process
- Generator Options Miscellaneous Information
90Waste Classification Options
- Self-classify, and manage accordingly
66260.200(c) - Generator responsibility
- DTSC concurrence 66260.200(d)
- DTSC reclassification 66260.200(f)
- public notice if granted (25141.6 HSC)
- adopt regulations if broad application (25141.5
HSC) - DTSC special waste (66261.124)
- All DTSC determinations are subject to fee for
service
91Generator Options - Variance22 CCR 66260.210
25143 HSC
- Allows generator to manage hazardous waste
differently hazardous waste management
requirements in regulations or statute - must obtain DTSC approval
- must meet criteria outlined in statute and
regulations
92Generator Options - Variance22 CCR 66260.210
25143 HSC
- Variance criteria
- requirements, waste, waste quantity, management
activity or management unit is insignificant or
unimportant as a hazard to human health or
environment when managed according to variance
conditions - requirements imposed, waste handling, processing,
disposal or waste management activity is
adequately managed by another governmental agency
93Miscellaneous Hazardous Waste Classification
Information
- 25157.8 HSC
- AB 2784 (1998) and AB 414 (2001)
- Effective January 1, 1999
- Wastes with lead ? 350ppm must be disposed in
Class I landfill - Exception waste disposed before August 21, 1998
94Miscellaneous Hazardous Waste Classification
Information
- Wastes with lead ? 350ppm are not hazardous
wastes unless they also exhibit a hazardous waste
characteristic (no other hazardous waste
requirements required other than disposal to
Class I landfill) - sunsets July 1, 2006 (extended from July 1, 2003)
95Hazardous Waste Classification
- Department of Toxic Substances Control
- Waste Identification and Recycling Section
- Evaluating goals and customer needs
- Helpline 916-322-7676