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Substitution reactions of octahedral complexes

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http://www.staff.ncl.ac.uk/mechanisms/ The solvolysis reaction. 3. Inert and labile complexes. 4. Influence of the leaving group. 5 ... – PowerPoint PPT presentation

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Title: Substitution reactions of octahedral complexes


1
Substitution reactions of octahedral complexes
2
General mechanism
http//www.staff.ncl.ac.uk/mechanisms/
3
The solvolysis reaction
4
Inert and labile complexes
5
Influence of the leaving group
6
Influence of the spectator ligands
7
Stereochemistry of the substitution
8
Substitution by direct replacement
9
The shift mechanism
10
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11
Other coordination numbers
12
Substitution at 17e and 19e complexes
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