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Environmental Organic Chemistry Instructor: Jaeweon Cho

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it is selective for compounds containing double bonds with electron-donating ... 3. DOM mediated photolysis. Week 12. Week 12. Week 12. Week 12. Week 12. Week 12 ... – PowerPoint PPT presentation

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Title: Environmental Organic Chemistry Instructor: Jaeweon Cho


1
Environmental Organic ChemistryInstructor
Jaeweon Cho
12th Week Class
2
Week 12
3
Week 12
4
Week 12
DOM
II
I DOM, NO3-, Fe complexes
III
5
Week 12
6
Week 12
7
Week 12
1. Hydroxyl Radical (HO) - Unselective than
Ozone and singlet Oxygen - Indirect
Measurement - Especially in agricultural
environments (i.e., nitrate and nitrite)
8
Week 12
9
2. Singlet Oxygen (1O2) - mostly quenched by
water - it is also oxidant but with very low
concentration - it is known DOM mediates - it
is selective for compounds containing double
bonds with electron-donating groups (phenols,
sulfide, amines, etc.)
10
Week 12
Diels-Alder-reaction
11
Week 12
12
Week 12
3. DOM mediated photolysis
13
Week 12
14
Week 12
15
Week 12
16
Week 12
17
Week 12
18
Week 12
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