Household Formulations

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Household Formulations

• Jackie Pytel
• Stepan Company
• April 30, 2006

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Glass Cleaners
Hard Surface Cleaners
Heavy Duty Liquids
Bathroom Cleaners
Household Liquids
Light Duty Liquids
Fabric Softeners
All Purpose Cleaners
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What Are Your Targets?
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Surfactants for HSC
Nonionics
Detergency

• Fatty Alcohol Ethoxylates (AE)
• Alkyl Phenol Ethoxylates (APE)
• Fatty Alkanolamides (FAA)
• Amine Oxides (AO)

Wetting
Foaming
Anionics

• Linear Alkyl Benzene Sulfonate (LAS)
• Alcohol Ether Sulfate (AES)
• Alcohol Sulfate (AS)
• Alpha Sulfo Methyl Ester (SME)
• Alpha Olefin Sulfonate (AOS)
• Soap

Emulsification
Dispersion
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Raw Materials for HSC
Alcohols Glycols Glycol Ethers Hydrocarbons
Coupling Clarity Viscosity
Solvents
Coupling Clarity Viscosity
Sodium Xylene Sulfonate (SXS) Sodium Octane
Sulfonate (PAS)
Hydrotropes
Deflocculation Neutralization Buffering Alkalinity
Sequestration
Silicates Phosphates Carbonates Citrates
Builders
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Raw Materials for HSC
Chelation
EDTA NTA
Chlorine Releasing Agents Quaternary
Compounds Phenolic Compounds Pine Oil
Disinfectants
Dye Fragrance Opacifier
Aesthetics
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All Purpose Cleaners
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All Purpose Cleaner (APC) Concentrate
Component
Wt
Alcohol Ethoxylate (C11 9 EO) Linear
Alkylbenzene Sulfonate (60) Sodium
Citrate Sodium Carbonate Sodium Xylene Sulfonate
(40) EDTA (37) Water, Fragrance, Dye
7.0 5.6 6.5 4.0 8.0 3.0 to 100.0
Appearance pH Solids Use
Clear Liquid 10.5 32 2-4 oz./gal.
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Ready-to-Use Spray Wipe Cleaner
Component
Wt
Alcohol Ether Sulfate (60) Alcohol
Ethoxylate Sodium Metasilicate (Anhydrous) Glycol
Ether EDTA Water, Dye, Fragrance
1.6 2.0 1.0 3.0 0.6 to 100.0
Appearance pH Solids Use
Clear Liquid 12 4.5 As Is, With Trigger Spray
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Glass Cleaners
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Glass Cleaner
Wt
Component
Isopropyl Alcohol Glycol Ether Sodium Lauryl
Sulfate (30) Water, Dye, Fragrance
4.0 3.2 0.3 to 100.0
Appearance pH Solids Use
Clear Liquid 8.5 1 As Is, With Trigger Spray
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Bathroom Cleaners
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Bathroom Cleaner/Disinfectant
Component
Wt
Germicidal Quaternary Compound (50) Na4EDTA Nonyl
phenol Ethoxylate (10 EO) Sodium Metasilicate
Pentahydrate Glycol Ether Water, Dye, Fragrance
0.42 1.60 0.50 0.25 4.00 to 100.00
Appearance pH (As Is) Solids Use
Clear Liquid 12.5 2.6 As Is, With Trigger Spray
EPA Registration Required
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Bathroom Cleaner with Bleach
Component
Wt
Sodium Hydroxide (50) Sodium Metasilicate
Pentahydrate Lauramine Oxide (30) Sodium
Hypochlorite (15) Water, Fragrance
1.0 0.5 5.0 14.0 to 100.0
Appearance pH (As Is) Solids Use
Clear Liquid 13 3 As Is, With Trigger Spray
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Heavy Duty Acid Bathroom Cleaner
Wt
Component
Glycolic Acid Sulfamic Acid Lauramine Oxide
(30) Water, Dye, Fragrance
5.0 5.0 10.0 to 100.0
Appearance pH (As Is) Solids Use
Clear Liquid 1.0 13 As Is or Diluted as Needed
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Liquid Scouring Cleansers
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Liquid Scouring Cleanser
Component
Wt
Lauramine Oxide (30) Linear Alkylbenzene
Sulfonate (60) Sodium Citrate Calcium Carbonate
(100 Mesh) Water, Dye, Fragrance
7.0 5.0 2.0 50.0 to 100.0
Appearance pH (As Is) Solids Viscosity _at_ 25oC Use
Creamy, Viscous Liquid 9.6 57 3000 cps As Is,
Rub Gently and Rinse or Wipe
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Viscous Toilet Bowl Cleaners
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Viscous Toilet Bowl Cleaner
Component
Wt
Hydrochloric Acid (36) Alkoxylated Tallow Amine
(2EO) Water, Dye, Perfume
25.0 4.0 to 100.0
Appearance pH Solids Viscosity _at_ 25oC Use
Clear Viscous Liquid 1 12 5000 cps As Is From
Squirt Bottle
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Light Duty Liquids
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Surfactants for LDLs
Primary

• Linear Alkylbenzene Sulfonate
• Alcohol Ether Sulfate
• Alcohol Sulfate
• Alpha Olefin Sulfonate
• Alpha Sulfo Methyl Ester

Secondary

• Fatty Alkanolamide
• Amine Oxide
• Betaine
• Alcohol Ethoxylate
• Alkyl Polyglucoside
• Amphoacetates

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Raw Materials for LDLs
Sodium Xylene Sulfonate Ethyl Alcohol
(denatured) Urea
Hydrotropes
Inorganic Salt Polymers Opacifier Dye Fragrance
Miscellaneous
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Premium Light Duty Liquid
Component
Wt
Linear Alkylbenzene Sulfonic Acid Ammonium Lauryl
Ethoxysulfate (60) Coco Sulfo Methyl Ester
(38) Coco Diethanolamide Sodium Hydroxide
(50) Ethanol Mg Sulfate Water, Dye, Fragrance
18.3 18.0 15.0 4.5 5.1 2.5 0.5 to 100.0
Appearance pH Solids Viscosity _at_ 25oC Use
Clear Yellow Liquid 6.5 40 500 cps As needed
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Value Brand Liquid Dishwash
Component
Wt
Linear Alkylbenzene Sulfonate (40) Sodium Alkyl
Ether Sulfate (60) Coco Diethanolamide Sodium
Chloride Water, Dye, Fragrance
30.0 10.0 3.0 Q.S. to 100.0
Appearance Solids Viscosity _at_ 25oC Use
Clear Liquid 21 175 cps As Is
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Heavy Duty Liquid Laundry Detergents
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Surfactants for HDLs
Anionics

• Linear Alkyl Benzene Sulfonate (LAS)
• Alcohol Ether Sulfate (AES)
• Alpha Sulfo Methyl Ester (SME)
• Alcohol Sulfate (AS)
• Soap

Nonionics

• Fatty Alcohol Ethoxylates (AE)
• Alkyl Phenol Ethoxylates (APE)

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Raw Materials for HDLs
Coupling Clarity Enzyme Stability
Ethyl Alcohol Propylene Glycol
Solvents
Coupling Clarity Viscosity
Sodium Xylene Sulfonate Ethyl Alcohol
Hydrotropes
Polyphosphates NTA/EDTA Carbonates Sodium
Citrate Triethanolamine (TEA) Soap
Deflocculation Chelation Buffering Alkalinity Sequ
estration
Builders
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Additional Ingredients for HDLs
Stilbene Derivatives Pyrazoline
Derivatives Naphthotriazol Derivatives
Optical Brightener
Carboxy Methyl Cellulose Polyacrylates
Anti-Redeposition Agents
Protease Amylase Cellulase Lipase
Proteins Starches Cotton Fats/Oils
Enzymes
Dye Fragrance Opacifier
Aesthetics
Customer Appeal
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Premium Liquid Laundry Detergent
Wt
Component
Linear Alkylbenzene Sulfonic Acid Lauryl Ethoxy
(3) Sulfate (60) C1214 Alcohol Ethoxylate
(7EO) Sodium Hydroxide (50) Soap Citric
acid Fluorescent Whitening Agent Propylene
Glycol CaCl2 - 2H20 Protease Amylase Water, Dye,
Fragrance
5.36 23.30 10.00 1.38 4.00 2.50
0.15 7.00 0.02 1.00 0.50 to
100.00
8.5 110 cps 36 29.5 ¼ to ½ Cup
pH (As Is) Viscosity _at_ 25oC Solids Surfactant
actives Use
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Value Brand HDL
Component
Wt
Linear Alkylbenzene Sulfonate (40) Alcohol
Ethoxylate (C25 7EO) Soap Sodium
Carbonate Fluorescent Whitening Agent Water, Dye,
Fragrance
15.0 3.0 1.5 2.8 0.1 to 100.0
pH (As Is) Viscosity _at_ 25oC Solids Surfactant
Actives Use
10.5 120 cps 13.4 9.0 ½ to 1 Cup
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Heavy Duty Powdered Laundry Detergents
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Surfactants for HDPs
Anionics

• Linear Alkyl Benzene Sulfonate (LAS)
• Alcohol Ether Sulfate (AES)
• Methyl Ester Sulfonates (MES)
• Alcohol Sulfate (AS)
• Soap

Nonionics

• Fatty Alcohol Ethoxylates (AE)
• Alkyl Phenol Ethoxylates (APE)

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Raw Materials for HDPs
Soda Ash NTA/EDTA Sodium Citrate Silicates Soap
Alkalinity Chelation Buffering Decrease Clumping
Builders
Sodium Chloride Sodium Sulfate
Fillers
Cost Savings Good Solubility
Perborate Percarbonate Activator
Non-Chlorine Color Safe Improved Cleaning
Bleach Systems
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Powdered Laundry Detergent

• Surfactants
• Premium (20-30 actives)
• LAS (C12) 20-25
• AES (C1214-1.8EO) 2-5
• AE (C1215-7EO) 2-5
• SXS 1-3
• Economy (10-15 actives)
• LAS (C12) 10-15
• AE (C1215-7EO) 0-5
• Builders/Fillers
• Optical Brightener, Anti-redep Agents, Enzymes,
  Powdered Bleach Systems
• Aesthetics Dye and Fragrance

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Fabric Softeners
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Raw Materials for Fabric Softeners
Cationic Surfactants

• Dialkyl Diamidoamine Methyl Sulfate
• TEA Diester Ammonium Methyl Sulfate
• Dialkyl Dimethyl Ammonium Chloride
• Imidazolinium Quaternaries

Stabilizers

• Calcium Chloride
• Ethoxylated Amines
• Alcohol Ethoxylates

Aesthetics
Customer Appeal

• Dye
• Fragrance
• Fluorescent Whitening Agents

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Premium Ultra Fabric Softener
Component
Wt
Diester Quat (90) Calcium Chloride
(Granular) Water, Dye, Fragrance, FWA
24.4 1.0 to 100.0
Appearance Viscosity _at_ 25oC Solids Use
Opaque Liquid 60 cps 22 1 oz. / load In Rinse
Cycle
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Economy Fabric Softener
Component
Wt
Ditallow Diamidoamine Quat (90) Water, Dye,
Fragrance, FWA
4.5 to 100.0
Appearance Viscosity _at_ 25oC Solids Use
Opaque Liquid 40 cps 4 3 oz. / load In Rinse
Cycle
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Ready to Get Started???

• Product Benchmarks
• Starting Formulation
• Formulate
• Performance Testing
• Pleasant Fragrance
• COST