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INITIAL RESPONSE TO SMALL LABORATORY SPILLS

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Wear Personal Protective Equipment EVERYTIME you handle Chemicals ... Seton www.seton.ca. Tenaquip www.tenaquip.com. Who You Going To Call? ... – PowerPoint PPT presentation

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Title: INITIAL RESPONSE TO SMALL LABORATORY SPILLS


1
INITIAL RESPONSE TO SMALL LABORATORY SPILLS
  • Safe and quick response to small laboratory
    spills
  • May 13, 2008
  • Rob Provost Co-ordinator HWM

2
A Little Preparation Goes A Long Way..
  • Know the Hazards of the Chemicals you work with
    everyday
  • Wear Personal Protective Equipment EVERYTIME you
    handle Chemicals
  • Understand and Know the location of the MSDS of
    the Chemicals you handle
  • Keep handy SOME Spill Cleanup Supplies

3
What is a SMALL SPILL??
The size and cleanup difficulty of the spill can
be determined by several different factors
  • Physical state of spill material (ie. Solid,
    Liquid or Gas)
  • Quantity of material
  • Hazards of the material (Flammable, Corrosive
    or Toxicity)
  • Hazardous Conditions Caused by the spill
  • Has someone been Contaminated by the spill

4
Physical State of Material
  • Solid Spills are easier to control and cleanup
    than liquids
  • Identified Liquid spills lt 1L can be controlled
    and absorbed with appropriate supplies
  • NEVER attempt to stop a stuck or broken gas
    cylinder Evacuate the AREA and Call UofT Police
    287-7333 !

5
Spill Quantity
  • Any size spill can be cleaned up IF you have the
    right equipment available!
  • If possible do enough to prevent progress of
    spill
  • Solids spills can be scooped back into a jar or
    beaker
  • Liquids can be absorbed with paper towels, bench
    coat or cloth to control it

6
Hazards of the Material
  • Vapours produced from spills cause the MOST
    hazards, either Toxic or Flammable
  • Corrosive Solids and Liquids can react with the
    response materials
  • HIGH vapour pressure usually is an indication of
    a volatile liquid
  • NEVER response to unknown spill alone

7
Conditions Caused by Spill
  • Solids or Viscous Liquids can make moving around
    slippery and dangerous
  • Location of Spill can make exiting hazardous
  • Try not to contaminate clean areas with the spill
    material
  • Extinguish any sources of ignition if spill
    contains flammable materials
  • Make sure Fume Hoods are running!

8
Contamination of Personnel
  • First Priority should be given to any people who
    are contaminated
  • Removing contaminated clothing to prevent further
    contact
  • Flush contaminated area with water for NO less
    than fifteen minutes
  • Seek Immediate Medical Attention

9
Cleanup Procedures
  • STOP - THINK! Do not rush. Carefully plan
    cleanup.
  • Attend to any persons who may have been
    contaminated
  • Post signs to identify the hazard and control
    access
  • Review MSDS for Hazards and Cleanup suggestions
    or consult a Chemical Dictionary hazards
  • Determine whether it can be handled safely
  • Contact Environmental Protection Services (EPS)
    for Assistance 978-7000
  • Eliminate all ignition sources if flammable
    material is involved.
  • Turn on fumehoods to capture or direct flow of
    vapours

10
Cleanup Procedures contd
  • Don personal protective equipment, as appropriate
    to the hazards.
  • Try to confine the spill to a small area. Do not
    allow the material to spread.
  • Carefully remove other materials, containers,
    equipment from path of the spill.
  • Absorb any liquids with absorbent or available
    supplies
  • Sweep solids of low toxicity into a dust pan and
    place into container for disposal
  • (NOTE Do NOT use BIO or RAD Bags for disposal of
    Chemical Waste)

11
Cleanup Procedures contd
  • Dispose of all cleanup materials as hazardous
    waste.
  • Waste must be properly packaged in a leakproof
    container, sealed and labelled with a hazardous
    waste label.
  • Handle the waste the same way you would any other
    chemical waste produced from your lab.
  • Then report the incident to supervisor and
    Environmental Health and Safety and to the local
    joint health and safety committee. Use the
    "Accident/Incident/Occupational Disease Report"
    form.

12
Response Chart
Spill State Gas / Liquid / Solid
  • Hazard
  • Contact
  • Hazard
  • Contact
  • Inhalation
  • Hazard
  • Contact
  • Inhalation
  • Protection
  • Dust Mask
  • Gloves
  • Protection
  • SCBA
  • Encapsulating Suit
  • Protection
  • Vapour Resp.
  • Gloves, Boots, Coveralls
  • Containment
  • Sweep
  • Containment
  • Vent remove
  • Containment
  • Neutralize Absorb

13
Cleanup Techniques
  • Protect floor drains or other means for
    environmental release. Spill socks and absorbents
    may be placed around drains, as needed.
  • Contain and clean-up the spill with the
    appropriate material.
  • Loose spill control materials should be
    distributed over the entire spill area, working
    from the outside, circling to the inside. This
    reduces the chance of splash or spread of the
    spilled chemical.
  • When spilled materials have been absorbed, use
    brush and scoop to place materials in an
    appropriate container. Polyethylene bags may be
    used for small spills. Five gallon pails may be
    appropriate for larger quantities.

14
Spill Cleanup Supplies
Solids
Liquids
  • Warning Sign
  • Broom and Dustpan
  • Disposal Container, any leakproof container
  • Hazardous Waste Label
  • Warning Sign
  • Absorbent material
  • Broom and Dustpan
  • Disposal Container, any leakproof container
  • Hazardous Waste Label

15
Personal Protective Equipment
  • Already in Lab
  • Safety Glasses or Goggles
  • Nitrile Gloves
  • Lab coat or Apron

Extra Supplies
  • Neoprene Gloves
  • Shoe Covers
  • Respirator

16
Mercury Spills
  • One of the most common spills at U of T is a
    Mercury Spill. Either from a Thermometer or a
    leak of elemental Mercury.
  • Initial Hazard is from contact, wear gloves while
    cleaning
  • Use damp cloth or tissue to wipe mercury into
    disposal container or syringe (without sharp) to
    vacuum up droplets
  • Be CAREFUL of broken glass if thermometer was
    involved
  • Also dispose of any equipment contaminated that
    cannot be properly cleaned
  • Should the Mercury persist contact EPS for the
    area to be vacuumed clean

17
Leaking Cylinders
  • The most dangerous spill situation is a leaking
    or broken gas cylinder, for two reasons. The gas
    contained in the cylinder can be either toxic,
    flammable, corrosive, an asphyxiant or a
    combination of these.
  • Initially evacuate the area, have someone contact
    UofT Police 287-7333 while finding someone who
    knows what the cylinder contains
  • Try to isolate the area affected by gas through
    ventilation controls, fume hoods and securing
    doors
  • Signage of the hazard is important to control
    exposure

18
Post Spill Duties
  • After the spill is cleaned up and the material
    collected has been labelled and stored for proper
    hazardous disposal, what then?.
  • May need to limit access to the area until the
    air has be refreshed
  • Reports of the incident should be made to
    Environmental Health and Safety and to the local
    joint health and safety committee
  • Notify Caretaking for further cleaning and
    restoring the area affected
  • Remove any warning signs from the area
  • Restock the supply used from the Spill Cart

19
UTSC Spill Cart Inventory
  • Face Shield
  • Gloves Triple Polymer Cleanroom (non-latex)
  • Broom (rubber edged)
  • Neutrasorb Acid Neutralizer
  • Solusorb Solvent Neutralizer
  • Hand Broom
  • pH Paper
  • Rubber Boots
  • Safety Goggles
  • Fire Extinguisher
  • Spill Bucket
  • Spill Cleanup Kits (containing plastic bags,
    plastic tray and sponge)

Personal Respirator
Mercury Spill Kit
Warning Signs
Disposal Labels
20
Spill Response Suppliers
  • Avenue Industrial Supply www.avenuesupply.com
  • Levitt-Safety www.levitt-safety.com
  • Seton www.seton.ca
  • Tenaquip www.tenaquip.com

21
Who You Going To Call?
If you cant safely handle the spill CALL
  • Environmental Protection Services 978-7000
  • Weekdays (8AM to 4PM)
  • or
  • U of T Police 287-7333
  • for After Hours Response
  • Please state type of spill, quantity, location,
    contact person and phone number.
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