Enolate Chemistry - PowerPoint PPT Presentation

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Enolate Chemistry

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Halogenation and Enolate Formation. Halogenation of ... Enamines behave like Enolates. Enamines stop at one addition. Single Addition makes Enamines useful ... – PowerPoint PPT presentation

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Title: Enolate Chemistry


1
Enolate Chemistry
  • 18-3 to 18-7

2
Halogenation of Ketones
3
Halogenation of Ketones
4
Halogenation and Enolate Formation
5
Halogenation of Enolate Anion
6
Alkylation of Ketones and Aldehydes
7
Alkylation of a Ketone
8
Avoiding Polyalkylation
9
Enamines behave like Enolates
10
Enamines stop at one addition
11
Single Addition makes Enamines useful
12
Aldol Condensation Self-Condensation
13
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14
Dehydration gives Alkene
15
Temperature determines condensation product
16
(No Transcript)
17
Heating results in dehydration
18
Crossed Aldol Condensation
19
Crossed Aldol Condensation
20
Controlling Crossed Condensations
21
Intramolecular Aldol Condensation
22
Intramolecular Aldol Condensation
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