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Theme 1: Production, Characterization, Application

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... processes Cationic surfactants for bitumen applications Bitumen stability and surface properties Noticeable results Clear distinction between the role of ... – PowerPoint PPT presentation

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Title: Theme 1: Production, Characterization, Application


1
Theme 1 Production, Characterization, Application
2
Workshop 1.1 Emulsification processes and
equipment
  • Statistics
  • 27 communications (19 from academia 8 from
    industry)
  •  Main work-streams 
  • Microfluidic and membrane devices improving
  • Rotor-stator (RS) and High pressure (HP)
    homogenizers - main interest to industry
  • Process optimization and intensification
  • Understanding the basic mechanisms. 
  • Applying emulsion techniques to produce
    particles
  •  Other methods are also tested ultrasound, thin
    film spinning, CO2 responsive emulsions

3
  • Noticeable results
  • Intensification by emulsification at high
    internal phase (50-90 vol ).
  • Simplified geometries of homogenizer heads with
    preserved high performance
  • Significant step in increasing the microfluidic
    production (EDGE device, asymmetric plates).

4
Workshop 1.2 Micro- and milli-fluidics applied to
emulsions
  • Statistics
  • 13 communications coming from academia
  • Main work-streams
  • Droplets formation and manipulation
  • Understanding mechanisms
  • Droplet formation well understood
  • Coalescence mechanisms at the scale of some
    droplets ongoing activity
  • Production of specific emulsions / particles
  • Microflidics as a tool for characterization
    (interfacial rheology, viscosity)

5
  • Noticeable results
  • New mechanism of drop formation in membrane
    emulsification hint for optimized pore geometry
  • Tailored processes to achieve drop morphology
  • Nano-channel emulsification (submicron droplets)
  • In some cases - specific and high grade particles
    or droplet assemblies.
  •  
  • Main problem
  • Still does not comply with industrial demands
  •  

6
Workshop 1.3 Physical stability, Rheology
  • Statistics 
  •  17 from academia and 13 from industry
  • Remarks 
  • Several companies offer instruments for stability
    and microrheology characterization (LUM,
    Formulaction, Malvern, .)
  • Opaque systems can be characterized.
  • Attempts to understand macroscopic stability by
    analysis of several structural levels (e.g.
    influence of surfactant structure on ripening and
    coalescence).

7
  • Perspectives
  • Different versions of light scattering and
    optical microscopy analysis seem to be most
    versatile and found wide application.
  • Commercial instruments for microrheology are
    already on the market

8
Workshop 1.4 Interfaces and dynamic behaviours
  • Statistics
  • 20 communications from academia and 6 from
    industry
  •  
  • Main work-streams
  • Characterization of complex mixtures - synergy
    (surfactant polymer, particles,
    cosurfactant)
  • Improvement of instruments and data analysis for
    surface characterization
  • High frequency (fast) processes
  • Cationic surfactants for bitumen applications
  • Bitumen stability and surface properties

9
  • Noticeable results
  •  Clear distinction between the role of particles
    (as good stabilizers) and surfactants (as fast
    adsorbing emulsifiers)
  • Progress in understanding the relation bitumen
    emulsion surface properties.

10
Workshop 1.5 End use properties and innovative
industrial applications
  • Statistics
  • 10 contributions from academia and 9 from
    industry
  • Remarks
  • Interest in developing correlations between
    physical properties of emulsions and use
    properties
  • Explore how to improve quality and end use
    properties with the help of systematic studies
  • New insight into psycho-rheology (relation
    between physic-chemical properties and human
    perception) 

11
Workshop 1.6 Bitumen emulsion and road material
properties
  • Statistics
  • 5 communications from academia and 16 from
    industry
  • Main work-streams
  •  Cold mixes
  • Behavior of grave emulsion on jobsites
    evolution of mechanical properties and emulsifier
    binder
  • Methodology to improve formulation and mix design
  • Environment
  • Warm mixed asphalt
  • Microsurface
  • Market studies
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