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glutathione

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The probability of the helical structure is decreased by: ... papaverine. isoquinoline ring. methylene group. benzyl group. methoxy group. Q. 42. quinine ... – PowerPoint PPT presentation

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Title: glutathione


1
Q. 26.
N-terminal
g-glutamyl-cysteinyl-glycine

C-terminal
glutathione

2
26. tétel
penicillin
3
Q. 26.
carnosin
4
Q. 27.
a-helix
H-bond
The probability of the helical structure is
decreased by proline, glycine, tyrosine,
asparagine
5
Q. 27.
b-sheet
H-bond
paralel
H-bond
antiparalel
6
Q. 27.
hem
myoglobin
7
Q. 30.
6
1
5
2
4
1
5
6
2
3
3
4
fructose
glucose
saccharose (sucrose)
a-D-glucopyranosyl-b-D-fructofuranoside
8
Q. 30.
6
5
1
4
2
3
glucose
glucose
Maltose
4-a-D-glucopyranosyl-b-D-glucopyranose
9
Q. 30.
2
3
1
4
5
6
6
glucose
galactose
5
4
1
lactose
2
3
4-b-D-galactopyranosyl-b-D-glucopyranose
10
Q. 30.
glycosidic bond b(1?4)
glucose
glucose
6
cellobiose
5
4
1
2
3
4-b-D-glucopyranosyl-b-D-glucopyranose
reducing
11
Q. 31.
glycosidic bond b(1?4)
H-bond
H-bond
Cellulose
12
31. tétel
amylose
13
Q. 31.
H
glycosydic bond a(1?4)
a-D-glucose
amylopectine
14
Q. 31.
b-D-glucuronic acid
N-acetyl-b-D-glucoseamine
hyaluronic acid (glycosaminoglycal)
15
Q. 31.
b-D-glucuronic acid
N-acetyl-b-D-glucoseamine-6-sulphate
chondroitin-6-szulphate
16
Q. 31.
b-D-glucuronic acid-2-sulphate
N-sulpho-b-D-glucoseamin-6-sulphate
heparin
17
Q. 31.
1
9
Z
oleic acid
18
Q. 31.
1
9
Z
12
Z
linoleic acid
19
Q. 31.
1
1
12
9
6
15
9
12
ALA
GLA
ALA
GLA
linolenic acid all-cis
15
20
Q. 33.
1
3
5
6
9
8
2
4
7
10
11
12
14
cis
arachidonic acid eicoza-5,8,11,14-tetraenic acid
21
Q. 33.
carbonyl group
Z
E
secondary, alcoholic OH
prostaglandin E2 (PGE2)
22
Q. 33.
carbonyl group
Z
E
secondary alcoholic OH
prostaglandin A2 (PGA2)
23
Q. 33.
glycerophospholipides
24
Q. 33.
stearic acid
linoleic acid
ethanolamine
L-a-cephalin phosphatidyl-ethanol-amine
25
Q. 33.
stearic acid
linoleic acid
choline
lecithin phosphatidyl-choline
26
Q. 33.
serine
phosphatidyl-serine
27
Q. 33.
inositol
phosphatidyl-inositol
28
Q. 34.
C
D
A
B
secondary, alcoholic OH b-directed
ergosterol
29
Q. 34.
Z
methylene group
secondary, alcoholic OH b-directed
vitamin D2
30
Q. 34.
methylene group
secondary, alcoholic OH b-directed
vitamin D3
31
Q. 36.
ring junction
18
19
11
13
12
17
10
9
15
1
8
16
14
6
7
5
2
4
3
steric structure of cholic acid 3a,7a,12a-trihydro
xy-cholanic acid
32
Q. 37.
secondary, alcoholic OH b-directed
ring junction B/C , C/D trans
18
12
17
11
13
19
16
14
1
9
15
2
8
10
3
7
5
4
6
carbonyl group
testosterone 17b-hydroxy-4-androstene-3-on
33
Q. 37.
base skeleton estrane
ring junction B/C , C/D trans
carbonyl group
C
D
aromatic ring
A
B
phenolic OH
estrone
34
Q. 37.
base skeleton estrane
ring junction B/C , C/D trans
secondary alcoholic OH
C
D
aromatic ring
A
B
phenolic OH
estradiol 1,3,5(10)-estratriene-3,17b-diol
stilbene
35
Q. 37.
base skeleton pregnene
acetyl group
carbonyl group
progesterone 4-pregnene-3,20-dione
36
Q. 37.
carbonyl group
formyl group
hemiacetal formation
secondary alcoholic OH
17
11
13
hydroxymethyl group
1
3
5
4
carbonyl group
aldosterone
37
Q. 37.
hemiacetale
aldosterone
38
Q. 37.
tertiary alcoholic OH a-directed
17
carbonyl group
hydrocortisone or cortisol 11b,17a,21-trihydroxy-4
-pregnene-3,20-dione
39
Q. 38.
anellation of rings A/B, C/D cis B/C trans
a-unsatureted lactone ring
g
a
b
17
13
C
D
14
10
tertiary alcoholic OH b-directed
A
B
5
3
secondary alcoholic OH b-directed
digitoxigenin
40
Q. 38.
anellation of rings A/B, C/D cis B/C trans
a-unsaturated lactone ring
g
a
b
17
13
14
10
tertiary alcoholic OH b-directed
5
3
secondary alcoholic OH b-directed
strophantidin
41
Q. 39.
IPP isopentenyl pyrophosphate
42
Q. 39.
h
t
limonene
43
Q. 39.
1
3
primary alcoholic OH
4
2
5
6
7
8
geraniol
44
Q. 39.
8
9
9
8

10
7

10
4
7

1
1

5
6
6
2

2
3
4
5

3
camphor
45
Q. 39.
head
head
head
1
5
9
13
3
7
11
15
10
12
14
16
4
6
8
tail
tail
tail
2
unsaturated primary alcohol
phytol
46
Q. 39.
primary alcohol
h
h
t
b-ionone ring
vitamin A all-trans
47
Q. 39.
t
t
t
h
h
h
t
t
h
t
squalene
48
Q. 40.
4
18
19
20
5
16
17
3
7
9
10
12
11
13
15
8
14
2
6
1
2
6
1
13
8
10
12
14
7
9
11
15
3
16
17
19
20
5
18
4
b-ionone ring
b-carotene all-trans
49
Q. 40.
a-ionone ring
b-ionone ring
a-carotene all-trans
50
Q. 40.
17
18
19
20
2
12
4
6
8
10
14
17
1
3
7
13
15
5
9
11
16
9
1
3
5
7
11
13
2
4
6
8
10
12
14
15
16
18
19
lycopene all-trans
51
Q. 40.


alcoholic secondary OH
zeaxanthin all-trans
52
Q. 40.
primary alcohol
f
f
l
b-ionon ring
Vitamin A all-trans
53
Q. 42.
indoxyle
54
Q. 42.
serotonin
55
Q. 42.
papaverine
56
Q. 42.




quinine
57
Q. 42.
methylene blue
58
Q. 42.
7
9
8
1
6
trilactime
2
4
5
3
lactame
dilactime
uric acid 2,6,8-trihydroxy-purine
59
Q. 43.
HEME protoporphyrine IX-Fe-complex
60
Q. 43.
bilirubin
61
Q. 43.
biliverdin
62
Q. 43.
chlorophyll
63
Q. 44.
amphoteric
phenolic OH
6
7
5
1
8
2
4
9
3
laktame
lactime
hypoxanthine 6-hydroxy-purine
64
Q. 44.
no tautomerisation
7
6
5
1
8
2
4
3
9
caffeine 1,3,7-trimethyl-xanthine
65
Q. 44.
no tautomerisation
7
6
5
1
8
2
4
3
9
theophylline 1,3-dimethy-xanthine
66
Q. 44.
amphoteric
7
6
5
1
8
2
4
3
9
theobromine 3,7-dimethyl-xanthine
67
Q. 44.
9
7
1
8
6
2
4
5
3
adenine
68
Q. 44.
9
1
7
8
6
4
5
2
3
guanine
69
Q. 45.
4
3
5
2
1
6
5
1
4
3
2
uridine b-D-ribofuranosyl-uracil (RNA)
thymidine b-D-ribofuranosyl-thymine (DNA)
cytidine b-D-ribofuranosyl-citosin
pyrimidine bases
70
Q. 45.
6
guanine G
adenine A
1
7
5
8
4
2
3
9
ribose
guanosine b-D-ribofuranosyl-guanine
adenosine b-D-ribofuranosyl-adenine
purine bases
71
Q. 45.
a
b
AMP (adenosine-5-monophosphate)
ADP (adenosine-5-diphosphate)
72
Q. 45.
lacton
5
a
b
g
3
ATP (adenosine-5-triphosphate)
cAMP (adenosine-3,5-phosphate)
73
Q. 45.
azido group
AZT (3-azido-2,3-dideoxy-thymidine)
74
Q. 46.
RNA (ribonucleic acid)
75
Q. 46.
A
G
T
C
3
P
P
P
P
OH
5
dAdGdTdC
DNA (deoxyribonucleic acid)
76
Q. 47.
NAD (nicotinic amide-adenine-dinucleotide)
77
Q. 47.
NAD
2e-/H
NADH
78
Q. 47.
dimethyl-isoalloxantine
ribitol
ribose
pyrphosphate
FAD (flavine-adenine-dinucleotide)
79
Q. 47.
2H/2e-
H2C-COO-

H2C-COO-
succinate
FAD

fumarate
FADH2
80
Q. 47.
thioethanol amin
pantotheic acid
adenine
ribose
pyrophosphate
Co-A (coenzim-A)
phosphate
81
Q. 48.
creatinine
82
Q. 48.
creatine phosphate
83
Q. 48.
barbituric acid
84
Q. 49.
1
2
4
5
3
7
6

atropine
85
Q. 49.
ecgonine
cocaine
86
Q. 49.
morphine
87
Q. 49.
LSD (lysergic acid diethylamide)
88
Q. 49.
quinine
89
Q. 49.
3
4
4
5
2
5
1
3
2
6
1
nicotine 2-(3)-pyridyl-N-methyl-pyrrolidine
90
Q. 49.
4
3
5
2
6
1
coniine (2-propyl-pyperidine)
91
Q. 49.
mescaline
92
Q. 49.
ephedrine
93
Q. 51.
a-tokoferol (vitamin E)
94
Q. 51.
n
vitamins K
n 4 vitamin K1 (phylloquinone) n 6
vitamin K2 (menaquinone)
95
Q. 51.
ubiquinone Coenzyme-Q
96
Q. 51.
vitamin B1 tiamine
97
Q. 51.
Riboflavin vitamin B2
98
Q. 51.
Pyridoxal vitamin B6
99
Q. 51.
Panthotheic acid (a,g-dihydroxy-b,b-dimethyl-butyr
ic acid)
100
Q. 51.
p-amino-benzoic acid PABA
glutamic acid a-amino-glutaric acid
2-amino-4-hydroxy- 6-hydroxymethyl-pteridine
Folic acid (pteroyl-glutamic acid)
101
Q. 51.
2
3
1


4
5
6
vitamin C (L-ascorbic acid)
102
Q. 52.
Aspirin
103
Q. 52.
phenacetin
104
Q. 52.
sulfanilamide
105
Q. 52.
cephalosporines
106
Q. 52.
3
4
2
5
6
1
barbiturates
107
Q. 52.
6
1
5
2
3
4
5-fluorouracil
108
Q. 52.
6
7
1
5
8
2
9
4
3
6-mercaptopurine
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