Title: Hydrogen bonded supramolecular tubules
1Hydrogen bonded supramolecular tubules
2Molecular design of H-bonded rosette macrocycles
Unstable in water
Stable in water
3(No Transcript)
4TEM image of Rosette Nanotubes
50 nm
50 nm
5Rosette Nanotubes with Crown Ether Binding Sites
Fenniri et al. JACS 2002, 124, 11064
6Induction of supramolecular chirality in rosette
nanotubes
7Dendron rodcoil functional triblock
self-assembler
HO
OH
O
O
O
O
O
O
O
O
O
O
O
O
OH
-
m
n
HO
nm9
- Dendron
- hydrogen bonding
- ?-? stacking
- bulky
- Coil
- structurally diverse
- hydrophobic
- flexibile
8Synthesis of dendron rodcoil
Stupp et al. J. Am. Chem. Soc. 123, 4105 (2001)
9Supramolecular gels formed by dendron rodcoil
molecules
10NMR spectra before and after gelation
11One-dimensional supramolecular structures of DRC
12AFM tapping mode images of DRC nanoribbon
13Analogous DRC molecules
14SAXS of DRC analogues
15Analogous DRC molecules (dendrons generation
series)
16Analogous DRC compounds (coil series)
17Rod-dendron model compounds