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Hydrogen bonded supramolecular tubules

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One-dimensional supramolecular structures of DRC. height contrast. phase contrast ... DRC molecules (dendron's generation series) Analogous DRC compounds ... – PowerPoint PPT presentation

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Title: Hydrogen bonded supramolecular tubules


1
Hydrogen bonded supramolecular tubules
2
Molecular design of H-bonded rosette macrocycles
Unstable in water
Stable in water
3
(No Transcript)
4
TEM image of Rosette Nanotubes
50 nm
50 nm
5
Rosette Nanotubes with Crown Ether Binding Sites
Fenniri et al. JACS 2002, 124, 11064
6
Induction of supramolecular chirality in rosette
nanotubes
7
Dendron rodcoil functional triblock
self-assembler
  • Rod
  • ?-? stacking
  • rigid

HO
OH
O
O
O
O
O
O
O
O
O
O
O
O
OH
-
m
n
HO
nm9
  • Dendron
  • hydrogen bonding
  • ?-? stacking
  • bulky
  • Coil
  • structurally diverse
  • hydrophobic
  • flexibile

8
Synthesis of dendron rodcoil
Stupp et al. J. Am. Chem. Soc. 123, 4105 (2001)
9
Supramolecular gels formed by dendron rodcoil
molecules
10
NMR spectra before and after gelation
11
One-dimensional supramolecular structures of DRC
12
AFM tapping mode images of DRC nanoribbon
13
Analogous DRC molecules
14
SAXS of DRC analogues
15
Analogous DRC molecules (dendrons generation
series)
16
Analogous DRC compounds (coil series)
17
Rod-dendron model compounds
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