HAZARDOUS WASTE MANAGEMENT

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HAZARDOUS WASTE MANAGEMENT

• Self-Study Guide for Laboratory Personnel
  

Annual Refresher Training for Departmental
Hazardous Waste Coordinators
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TABLE OF CONTENTS

• Introduction 3
• What is RCRA 4-6
• Identifying Hazardous 7-8 Chemical Waste
• Generator Responsibilities 9-14
• Disposal Procedures 15-23
• Spill Response 24
• Contacts 25
• Quiz Q-1 Q-2

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I. Introduction

• The Hazardous Waste Management Online Training
  is
• for lab personnel with departmental
• responsibility for coordinating hazardous
• waste procedures.
• to be used in lieu of classroom-based
• Hazardous Waste Management annual
• refresher training.
• a review of Hazardous Waste Management
• or RCRA compliance for lab personnel in
• teaching, research, and clinical services on
  
• all UMDNJ campuses, including the
• University Hospital.

NOTE This guide does not apply to non-laboratory
staff. Credit for this course is
received by passing the mandatory quiz.
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II. What is RCRA

• Resource Conservation and Recovery Act
• Regulated by the U.S. Environmental Protection
• Agency (EPA) since 1976.
• Authorized EPA to regulate the management of
• hazardous waste from Cradle-to-Grave.
• Regulates the generation, transportation,
• treatment, storage, and disposal of hazardous
  
• chemical waste.
• Sets forth a framework for the management of
• non-hazardous and Universal wastes.
• Requires generators to ensure that the hazardous
  
• waste they produce is properly identified and
  
• managed up to and including disposal.

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II. What is RCRA

• UMDNJ Generator Sites
• RCRA classifies waste generators by the amount of
  hazardous chemical waste generated monthly.
  UMDNJ holds nine EPA numbers as hazardous waste
  generators at the following campuses
• Two Large Quantity Generators Newark
  Piscataway Campuses
• Seven Small Quantity Generators Newark (ICPH),
  New Brunswick (MEB, CINJ, CAB, CHI), Camden, and
  Stratford campuses
• Conditionally Exempt Small Quantity
• Generators Scotch Plains campus and
• offsite medical and dental clinics.
• Note clinics do not need EPA ID Numbers,
• according to RCRA

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II. What is RCRA

• When Does a Chemical Product Become a Waste?
• As a byproduct of a chemical experiment or
  industrial process
• Upon reaching an expiration date
• When a decision is made to no longer use a
  chemical

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III. Identifying Hazardous Chemical Waste

• Individuals using chemicals must first determine
  if the resultant chemical waste is a hazardous
  waste. It is a hazardous waste if it is one of
  500 chemicals listed by the EPA (click here for
  list) or has one of four characteristics. Check
  the container label and/or review the Material
  Safety Data Safety (MSDS) to determine if the
  waste possesses one of the characteristics listed
  below.
• Corrosive
• pH less than or equal to 2.0
• pH greater than or equal to 12.5
• Toxic
• Chemical substance or mixture containing heavy
  metals
• Chemical substance or mixture made of toxic
  organic constituents

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III. Identifying Hazardous Chemical Waste

• Ignitable
• Liquid with flashpoint below 1400F (i.e.
  alcohol, acetonitrile, xylene)
• Solids burn vigorously when ignited (i.e.
  picric acid, sodium dithionite)
• Oxidizers (i.e. nitrates, nitrites,
  permaganates)
• Flammable compressed gases (i.e.
  propane, butane, methane)
• Reactive
• Substances that react violently with water (i.e.
  sodium)
• Chemicals containing Cyanide or Sulfide (i.e.
  potassium cyanide)
• Explosive or unstable (i.e. dioxane, di- and tri-
  nitro compounds)

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IV. Generator Responsibilities

• EOHSS established specific procedures based on
  the RCRA regulations. These procedures must be
  followed without exception to ensure compliance,
  and avoid costly penalties resulting from
  non-compliance. The procedures summarized in
  this section are presented in the Laboratory
  Safety Plan and can be found in more details in
  the University Hazardous Waste Management Program.

Waste Minimization
Hazardous Waste Label
Container Management
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IV. Generator Responsibilities

• Waste Minimization
• UMDNJ certifies that the University has tried, to
  the extent feasible, to minimize the amount of
  hazardous waste generated at our institution.
  Waste minimization means any process modification
  resulting in the prevention or reduction of
  hazardous chemical waste. Meeting the objectives
  of waste minimization at UMDNJ requires
• the cooperation of everyone producing
• hazardous waste.
• an obligation to implement practices and
• procedures

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IV. Generator Responsibilities

• General principles of waste minimization, in
• order of priority, are
• Elimination ending a procedure or
• stopping the use of a hazardous
• substance that would result in the
• generation of hazardous waste.
• Substitution replacing a hazardous substance
  with a less hazardous material
• (i.e. substitution ethanol (non-toxic) for
  methanol (toxic).
• Scale Reduction reducing the amount of a
  hazardous materials used in a procedure.
• Recycling the reuse of spent materials either
  back into the same process or into a different
  process (e.g., purification, such as solvent
  distillation).
• Reclamation any process that removes and reuses
  a hazardous material (e.g., silver recovery).

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IV. Generator Responsibilities

• Hazardous Waste Labels
• Every container of hazardous chemical waste must
  have a UMDNJ Hazardous Waste label when first put
  into use.
• The label must include
• Name, location, and phone number of generator
• Contents with ingredients and including water
  (no abbreviations!)
• Hazard Class Ignitable, Corrosive, Toxic,
  Oxidizer, Reactive (circle one or more)
• Date the label only when the container is full
• Click here for hazardous waste labels

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IV. Generator Responsibilities

• Container Management
• Hazardous waste containers must be
• In good condition and free of precipitate
• and drips
• Compatible with the waste being collected
• Closed at all times except when adding or
• removing waste
• Inspected on a regular basis for leaks, etc.
• by the person generating the waste
• Stored at or near point of generation
• Controlled by trained personnel responsible
• for waste

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IV. Generator Responsibilities
Example of the Satellite Accumulation Area (SAA)
Container Inspection Sign
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V. Disposal Procedures

• Hazardous Chemical Waste Disposal
• Schedule a Waste Pick-up
• Fill out all requested information on the
  Chemical Waste Disposal Request Form or on line
• List all chemical waste to be disposed
• Fax, email, inter-office mail or submit on line
  the Disposal Request to EOHSS within three days
  of the container becoming full
• EOHSS will contact you to confirm a pick-up date
  and approximate time

Fax 2-3694 Email sangiokd_at_umdnj.edu Inter-Off
ice EOHSS, SSB-443, Newark Campus On Line
Chemical Waste Disposal Request
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V. Disposal Procedures
Example of Chemical Waste Disposal Request Form
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V. Disposal Procedures

• Hazardous Chemical Waste Disposal
• Preparing for a Chemical Waste Pick-up
• Ensure containers are clean, sealed, in good
  condition, and have proper hazardous waste labels
• Ensure that all full containers are dated before
  EOHSS arrives
• Leave labeled waste containers in a conspicuous
  location, if you will not be available when EOHSS
  picks up waste
• Maintain an appropriate spill kit and ER flip
  chart in the lab or work area
• Do not handle shock sensitive or potential
  explosive wastes. Contact EOHSS for assistance

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V. Disposal Procedures

• Special Types of Hazardous Waste
• Mixed Waste Streams
• Certain types of hazardous waste pose particular
  problems for disposal. They may be difficult to
  dispose of or may require handling and storage by
  a specialized hazardous waste vendor. They are
  almost always more costly to dispose, therefore,
  consult EOHSS and the Radiation Safety Officer
  before generating the following wastes to ensure
  that a disposal option exists
• Mixed radioactive/hazardous chemical waste
• Mixed radioactive/biological waste
• Mixed biological/hazardous chemical waste

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V. Disposal Procedures

• Special Types of Hazardous Waste
• NOTE The generation of wastes containing human
  body fluids treat Petri dishes, syringes,
  hypodermic needles, and test tubes as Regulated
  Medical Waste. Do not dispose of biological
  wastes in the chemical waste stream. Do not
  dispose of chemical waste in biological
  (regulated red bags) waste stream.
• Radiographic Waste Photographic
• Film Lead Foil
• Two Options for Managing Liquid Radiography Waste
• Run used fixer solutions through a silver
  recovery unit. Ensure vendor changes the silver
  recovery unit often enough to ensure the
  discharge meets the EPA limit.

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V. Disposal Procedures

• Special Types of Hazardous Waste
• Collect and dispose of used fixer solutions
  though EOHSS. Departments not employing silver
  recovery must collect the used fixer solutions
  for disposal through EOHSS. Follow applicable
  hazardous waste procedures outlined in the
  University Hazardous Waste Management Program.
• Photographic Films Lead Foil
• Used photographic films and lead foils must be
  collected as hazardous waste due to the residual
  silver and lead content, respectively. Bag or
  box the film/foil, and write used
  silver-containing films or lead foil on the
  hazardous waste label.

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V. Disposal Procedures

• Non-Hazardous Chemical Waste Disposal
• Although the majority of chemicals used in a
  research lab will be treated as hazardous waste,
  the following materials are non-hazardous waste
  and may be disposed as described below.
• Drain Disposal
• You may dispose of the following liquid
• wastes down a sink drain
• Weak acids and buffers with pH of 5.5 9.0 if no
  other hazardous components are present
• Ethanol/water mixtures of less than 10 ethanol
  if no other hazardous components are present. Do
  not dilute solutions of greater than 10 ethanol
  in order to dispose of them via the drain.

Contact EOHSS to determine if a waste stream is
non-hazardous.
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V. Disposal Procedures

• Non-Hazardous Chemical Waste Disposal
• Ethidium Bromide aqueous solution after filtering
  through an extractor. The extractor is disposed
  of as hazardous waste. These extractors are
  available through lab supply companies.
• Trash Disposal
• You may dispose of the following solid wastes in
  the trash
• Alkaline batteries
• Small quantities of solid non-hazardous wastes
  may be disposed of in the trash. (Examples of
  non-hazardous wastes sugars, salts, minerals,
  starches, amino acids, and enzymes)
• Ethidium bromide-stained agarose gels (with trace
  amounts of Ethidium Bromide (lt0.5 mcg/ml) and no
  other hazardous components present)

Contact EOHSS to determine if a waste stream is
non-hazardous.
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V. Disposal Procedures

• Empty Container Disposal
• Empty compressed gas cylinders should be
• returned to the vendor.
• Other empty containers
• Ensure that the container is completely empty and
  no liquid remains in the container
• If the chemical constituents are not acute
  hazardous waste
• Rinse the container, dry in hood
• Deface the label or write EMPTY on the label
• Dispose in regular trash
• If the chemical constituents are P-listed (e.g.,
  sodium azide or osmium tetroxide) as acute
  hazardous waste, only dispose of the container
  through EOHSS.

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VI. Spill Response

• Notify Public Safety of any chemical spill.
  Public Safety will contact EOHSS for spill
  response.
• If youve had training and the proper
  supplies/equipment, contain the spill with the
  appropriate spill kit.
• Exit the area and wait in a safe location, away
  from the spill area for EOHSS to respond.
• If exposed to the spilled material, employ the
  appropriate first aid procedures.
• DO NOT attempt to clean up a hazardous waste
  spill yourself.
• DO NOT ask Environmental Services (Housekeeping
  Staff) to clean up the spill.

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VII. Contacts
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Hazardous Waste Management Self-Study Guide for
Laboratory Personnel Complete the quiz fax it
to EOHSS at [phone]

• Who should you contact if you have a question
  about whether a chemical waste is a RCRA
  regulated hazardous waste?
• Manufacturer of the chemical
• EOHSS campus representative
• Public Safety Dispatch
• Your supervisor or RI/PI
• RCRA classifies generators by what criteria
• the number of large quantity generators a company
  has
• the different characteristic waste types a
  facility generates
• the amount of hazardous chemical waste generated
  monthly
• whether or not a company adheres to the cradle to
  grave philosophy
• Which statements is false regarding when a
  chemical product becomes a waste?
• as a byproduct of a chemical experiment or
  industrial process
• upon reaching an expiration date
• when a decision is made to no longer use a
  chemical
• when an experiment ends
• When does a generator date a hazardous waste
  label?

Q-1
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• Methanol/water mixtureslt10 can be drain disposed
• True False
• Proper hazardous waste container management
  includes
• stored at or near the point of generation
• closed at all times except when adding or
  removing waste
• in good condition and free of precipitate and
  drips
• all of the above
• None of the above
• A properly completed hazardous waste label
  includes
• generator name
• hazard class
• contents, including water
• all of the above
• none of the above
• According to UMD policy and RCRA regulations, how
  should a generator handle an empty container of a
  p-listed waste?
• Rinse it and dispose of it as regulated medical
  waste

Q-2