Linear paired electrochemical valorization of glycerol

1
Linear paired electrochemical valorization of
glycerol
Literature Presentation Debabrata Bagchi Ph. D.
Student 24/09/2022
2
(No Transcript)
3
Glycerol
Green Chem., 2021, 23, 78657889
4
Glycerol Oxidation
ACS Catal. 2018, 8, 6301-6333
5
Reaction kinetics involving H2O-H2-O2
HOR
HER
OER
ORR
M.T.M. Koper, H.A. Heering, in Fuel Cell
Science, Eds. A. Wieckowski, J.K. Nørskov, Wiley
(2010), p. 71-110
5
6
Organic Molecule Oxidation
Nat. Catal, 2022, 5, 66-73
7
Linear paired electrochemical valorization of
glycerol
Glycerol oxidation reaction
Oxygen reduction reaction
EH2O21.76 V
Oxidation
E.OH2.8 V
Oxidation
Fenton's reagent
8
Overall Process
9
Catalyst for O2 to H2O2
10
Stability of NiSe2
11
Characterization NiSe2
12
Characterization CoSe2
13
RRDE Experiment ECSA
14
ORR Performance of metal-selenide
15
Stability during ORR
16
Post Electrochemical Characterizations
17
Bulk Electrolysis on carbon fibre paper
18
Bulk Electrochemical Cell
19
ORR Performance during Bulk Electrolysis
20
Stability of Bulk Electrolysis
21
Net H2O2 Production
22
Stability of H2O2 Production
23
Glycerol valorization via the electro-Fenton
process
24
Standard 1H and 13C NMR
25
Role of Fe2
26
Impact of Fe2 Concentration
(Fe2 OH H? Fe3 H2O)
27
Impact of Fe2 Concentration
28
Stability after Electro-Fenton Process
29
Anodic glycerol oxidation
30
Glycerol oxidation Reduction
31
Linear paired glycerol valorization
(condition I 0.1 M NaHSO4/Na2SO4 for catholyte
and 0.05 M H2SO4 for anolyte condition II 0.5 M
NaHSO4/Na2SO4 for catholyte and 0.5 M H2SO4 for
anolyte)
32
Summary
33
(No Transcript)