Title: Fig' 6CO, p' 138
1Weathering and Soil Sediment and Sedimentary
Rocks
Fig. 6-CO, p. 138
2Weathering and Soil
- Weathering Processes
- Mechanical
- Chemical
- Weathering Products
- Soil
- Resources
- Sediment
3Weathering
- Weathering
- Disintegration (physical breakdown) and
decomposition (chemical alteration) of rock
(parent material) at or near the surface
(exposure to air and water). - Breakdown of parent rock into sediment and
dissolved ions.
4Weathering is an important process in the rock
cycle. A transition process between rocks
(igneous, metamorphic, pre-existing sedimentary
rocks) and sediment. Sediment is the source for
new sedimentary rocks.
5Weathering vs. Erosion
- Weathering is related to erosion, but they are
NOT the same. - Weathering occurs in place. No movement of
material. - Erosion implies the transport (movement) of the
material made during weathering.
6Fig. 6-1a, p. 140
7Fig. 6-1b, p. 140
8Fig. 6-2, p. 141
9Weathering
- Weathering produces the source material for
- Sedimentary rocks
- Soil
- Some natural resources
- Weathering is critical for the evolution of the
landscape all around us.
10Mechanical Weathering
- Physical breakdown of rock (disintegration).
- Processes involve breaking rocks and minerals
into smaller pieces. - Composition of the pieces is identical to the
source rock. - Just change in size and shape
11Mechanical Weathering
- Frost action repeated freezing and thawing of
water in cracks and crevices. - Frost wedging Water expands by 9 in volume when
it freezes ? substantial tensional forces
produced within the rock, sufficient to detach
pieces. - Frost heaving lifting lowering of layers due
to ice formation. - Most effective where have (a) water and (b)
sufficient seasonal/diurnal temperature
variations.
12Frost Action
Talus accumulations of rock fragments at the
base of a cliff or slope that is actively
weathering (by any process).
Fig. 6-3a, p. 142
13Fig. 6-3b, p. 142
14Mechanical Weathering
- Crystal growth growth of salt (and other
crystals) in cracks and voids. New minerals grow
(volume change) and induce stresses in the rock
leading to fracture. - Just like frost action
- Action of salt crystals is most common in arid
and coastal areas.
15Mechanical Weathering
- Pressure release Rocks formed at depth are
stable at elevated ambient pressures. - When rock is exhumed (uplifted exposed at the
surface somehow), the pressure is decreased. - Stresses in the rock increase the rock will
fracture. - Fractures (sheet joints) form parallel to the
surface of the rock. Material peels off ?
exfoliation. - Problematic in mines
16Fig. 6-4a, p. 143
17Fig. 6-4b, p. 143
18Fig. 6-4c, p. 143
19Mechanical Weathering
- Thermal effects
-
- Materials change volume as they heat up and cool
down. Rocks tend to expand when heated.
Contract when cool. - Volume change in a solid tends to cause stresses
sufficient to fracture, especially if
heating/cooling is uneven. - Day-night seasonal cycles not sufficient to
make this a large effect
20Mechanical Weathering
- Abrasion wearing away of rock surfaces by the
action of water-, wind-, and ice-bourne
particles. Even the action of water by itself - Critical factors
- Frictional forces electromagnetic interaction
of surfaces in contact. - Shear stresses the amount of force applied to a
surface due to changes in velocity.
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22Mechanical Weathering Processes
- Biological factors
- Plant roots forcing open cracks
- Animals burrowing
- These processes physically disrupt geologic
materials. Also enable and cause other,
non-mechanical weathering processes
23Fig. 6-5a, p. 144
24Fig. 6-5b, p. 144
25Chemical Weathering
- Minerals are decomposed by chemical alteration.
New minerals replace pre-existing ones according
to stability. - Variety of chemical reactions
- Dissolution (dissolving)
- Oxidation (rusting)
- Hydrolysis (just add water)
26Chemical Weathering
- Dissolution dissolving of minerals into a
solution (usually aqueous e.g. water). - Few minerals are very soluble in pure water.
Acidic water (carbonic, hydrochloric, sulfuric,
etc.) helps things along - Carbonates dissolve readily ? chemically
made/weathered rocks (chemical sediment)
27Chemical Weathering
- Polar nature of water makes it a good solvent.
- One half of water molecule is more positive
(hydrogen side) than the other (oxygen side).
28Fig. 6-6, p. 145
29Chemical Weathering
- Acids are good solvent due to amount of H
cations. More H, more acidic, better solvent. - Carbonic acid forms naturally due to equilibrium
between atmosphere and surface water. Biology
helps (decay). Climate (wet, hot) affects it too
30CaCO3 H20 CO2 -gt CaCO3 H HCO3- -gt Ca2
2HCO3-
31Chemical Weathering
- Oxidation minerals react with oxygen. Metal
cations form oxides/hydroxides that are more
stable at surface free-oxygen concentrations.
Rusting. - Important way of altering ferromagnesian
minerals. - Generally slow. Water helps the process.
324Fe 3O2 -gt 2Fe2O3
33Chemical Weathering
- Hydrolysis reaction of minerals and water ions
(H and OH-). - H can replace cations in minerals. OH- can
substitute for anions. - Mineral becomes hydrated with water in its
structure. - Ions are released
- Mineral structure/properties may change
- Mineral may become soluble
- Example hydrolysis of feldspar produces clay
minerals
342KAlSi3O8 2H 2HCO3- H2O -gt
Al2Si2O5(OH)4 2K 2HCO3- 4SiO2
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37Weathering Rates
- Rates of weathering vary over time and from place
to place and depending on the material being
weathered. - Mineral stability
- Climate
- Temperature
- Moisture
- pH
- Surface-area vs. volume
-
38Mineral Stability
- Rocks formed in the crust are made of minerals
chemically stable at elevated temperatures,
elevated pressures, and certain amounts of oxygen
and water. - Bring those rocks to the surface where those
conditions are different, and the minerals in the
rocks will weather in order to attain chemical
equilibrium with the new surroundings
39- The minerals most susceptible to weathering at
Earths surface are those that crystallize early
in Bowens reaction series. - Example Quartz is the most stable. Olivine is
the least stable.
40Environmental Factors
- Higher temperatures tend to accelerate chemical
reactions. - Wetter climates promote chemical weathering.
- Biology contributes to both mechanical and
chemical weathering. - ? Weathering is faster in the tropics than in
deserts
41Surface Area Volume
- Weathering is a process that acts on surfaces.
- The more surface area available, the more damage
weathering (especially chemical weathering) can
do.
42Surface Area Volume
- A cube 1 m on a side
- Volume 1 m3
- SA 6 m2
- Break it into 8 pieces, each 0.5 m on a side
- Total volume 1 m3
- Total SA 12 m2
- etc...
43Fig. 6-8, p. 146
44Surface Area Volume
- Small objects have a higher surface-area-to-volume
ratio than larger objects. - Mechanical weathering acts on surfaces, but tends
to reduce the size (volume) of particles. - It therefore gives chemical weathering more
surface area for it to act on
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46Corners are unstable mechanically and chemically
Fig. 6-9, p. 147
47Fig. 6-7, p. 146
48Soils
- Regolith unconsolidated rock and mineral
fragments - Soil regolith with weathered material, water,
air, organic matter that can support plant
growth - Humus organic material processed by bacterial
decay ? enriched in N, less C than original
organic matter - Sand, silt, clay make up 45 of fertile soil.
- Sand silt mostly quartz create pore spaces
- Clay mostly weathered feldspar important
nutrient supply
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50Soils
- Residual soil formed by in-place weathering of
parent material. - Transported soil weathered material is
transported to another place where it is
converted to soil.
51Soil Profile
- A soil profile is a horizontal stack of layers
(horizons). - A mature soil has well-developed horizons. An
immature soil does not have well-developed
horizons.
52Fig. 6-10, p. 148
53Soil Profile
- O horizon organic zone
- contains humus
- only a few cm thick
- A horizon leaching zone
- water percolating down - removes soluble material
- high biological activity
- B horizon accumulation zone
- clay and oxides precipitated from A horizon
leachate - fragipan either claypan (dense clay) or hardpan
(carbonate) - C horizon transition zone
- actively weathering rock
- saprolite (rotten rock)
54Soil Formation
- Climate is the most important factor
- moisture temperature controls on weathering
- climate determines extent of soil transport
- Parent material helps determine soil type and
depth and fertility - Organisms are active soil formers
- Topography (relief and slope and elevation)
affects (micro) climate and has mechanical
controls (slope stability, etc.) - Time weathering processes/soil forming
processes act at different rates and compete with
soil degradational processes/erosion
55Fig. 6-11, p. 149
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58Soil Types
- Soil classifications in use are very complicated,
but can be simplified to three types, based on
climate - pedalfer Al and Fe soil humid temperate
climates dark A clay- oxide-rich B acidic
fertile - pedocal Ca soil arid/semi-arid climates
light, less leached A hardpan B (caliche)
alkaline difficult - laterite tropical soils extreme leaching
removes all but clay and Fe oxides ? not fertile
valuable Al and Fe resources in some places
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62Soil Degradation
- Decrease in soil fertility/volume by
- Removal of soil by erosion
- Physical or chemical deterioration
63Soil Degradation
- Erosion transport of sediment/soil by the
action of water, wind, ice - Big problem in mismanaged farmlands
- Rain forest clearing removes vegetation that
stabilizes topsoil. - 25 of US cropland is eroding faster than being
renewed
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65Soil Degradation
- Water erosion by
- Sheet erosion overland flow of water as evenly
distributed sheet. Removes thin layers of soil - Rill erosion flow of water in channels (rills
or gullies). If severe, may make cropland
unusable.
66Fig. 6-13a, p. 152
67Fig. 6-13b, p. 152
68Fig. 6-14, p. 153
69Soil Degradation
- Chemical deterioration nutrients depleted and
not renewed ? productivity decreases - Overuse
- Misuse of fertilizers (too little or too much)
- Salinization (big issue in arid/semi-arid places)
- Pollution by industrial wastes, insecticides,
pesticides, etc.
70Soil Degradation
- Physical deterioration soil structure disrupted
? soil productivity decreases - Compaction
- elimination of pore spaces
- increase in hardness (hard to plow, erosion by
water) - Sun-baking (problem in tropics) ? clear-cut areas
of laterite (clay-rich soil) baked into brick in
short time!
71Soil Resources
- Laterites derived from Al-rich parent
- Al hydroxides accumulate in B horizon (residual
concentration) - These deposits are called bauxite (very important
Al ore) - US has little bauxite. Most imported from
Brazil, Australia, etc. - Fe, Mn, clays, Ni, P, Sn, diamond, gold also
found in residual deposits
72Fig. 6-12, p. 149
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75Sediment Sedimentary Rocks
- Sediment
- Types
- Transport
- Deposition
- Lithificaton
- Sedimentary Rocks
- Types
- Facies and Environment
- Resources
76Fig. 1-12, p. 20
77Sediment
- Raw materials for sedimentary rocks.
- Derived from weathering of parent rocks
- Detrital rock fragments mineral grains
liberated by mechanical weathering and
transported/deposited by mechanical processes.
Terrigenous or clastic (clasts) - Chemical formed of material dissolved during
chemical weathering and deposited by biological
or non-biological chemical reactions.
Precipitates (solutions)
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80Sediment
- What sorts of material?
- Clay minerals
- Quartz
- Calcite and dolomite ? chemical
- Feldspars
- Fe oxides and sulfides ? chemical
- Salts and gypsum ? chemical
- Volcanic debris (tephra)
- Organic matter
81Sediment Sizes
- Detrital sediment is classified according to
size. - Detrital sedimentary rocks can contain a wide
range of sizes, from mud to boulders
- boulder gt 256 mm
- cobble 64 to 56 mm
- pebble 2 to 64 mm
- sand 1/16 to 2 mm
- silt 1/256 to 1/16 mm
- clay lt 1/256 mm
82Table 6-1, p. 147
83Sedimentary Processes
- Weathering is the first step (form sediment).
- Unconsolidated detrital sediment is often eroded
and transported and deposited. - Products of chemical weathering are transported
in solution. - Sediment is then transformed into sedimentary
rock by lithification. Chemical sedimentary
rocks form directly from solution
(precipitatation).
84Sedimentary Processes
- Detrital sediment eroded and carried by water,
ice, wind. - Key factor is energy. Detrital sediment of a
given size will be carried by an agent with
sufficient energy. - Example I can blow dust and sand by blowing on
it. I cant move gravel or a boulder by blowing
on it
85Sedimentary Processes
- Abrasion during transport reduces particle size
and changes particle shape. - Particles become rounder the longer they are in
the transport phase - Sorting of particles (distribution of sizes) is
also affected by transport. Largest and heaviest
particles settle out first (not transported as
far).
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88Fig. 6-15a, p. 154
89Fig. 6-15b, p. 154
90Fig. 6-15c, p. 154
91Sedimentary Processes
- Sediment eventually gets put somewhere. It
ceases to be transported and is deposited. - Deposition of detrital sediment occurs when
energy necessary for transport is no longer
available. Chemical deposition (precipitation)
occurs when environmental (chemical) conditions
change. - Depositional environment geographic area where
sediment is deposited. - Continental
- Transitional
- Marine
92Fig. 6-16, p. 155
93Sedimentary Processes
- Lithification is the process by which sediment
becomes sedimentary rock. - Relatively simple for chemical sediments as they
simply precipitate out of solution and directly
form a rock - Detrital sediments are compacted (dewatered),
cemented, recrystallized (diagenesis)
94Sedimentary Processes
- Deposited sediment has pore spaces between
particles. - Compaction due to pressure of overlying sediment,
etc. reduces the volume of the deposit - Reduces pore space (50 volume reduction)
- Forces fluid out (dewatering)
95Sedimentary Processes
- Cementation is the process by which clasts are
stuck together. - Compaction does some of the job (e.g. for mud),
but for larger grainsizes, a cement or matrix is
needed. - The cement is like glue. Usually it is a
chemical sediment (calcium carbonate or silica or
Fe oxides) that precipitates in pore spaces
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98Sedimentary Rocks
- Single most important characteristic of sediments
and sedimentary rocks they are layered ?
history. - Layering of sediment records history of
sedimentary process, climate, tectonics, life,
etc
99Original Horizontality
- Sedimentary rocks are formed in layers (strata)
which were originally horizontal. - Flat strata are probably undisturbed
- Tilted strata have been affected by tectonics.
100Superposition
- Oldest sedimentary rocks at the bottom C
deposited first - Younger sedimentary rocks on top B then A.
101Superposition
- Crosscutting igneous rocks are younger than what
they intrude. - Faults are younger than what they cut.
102Lateral Continuity
- When they form, horizontal strata continue in all
directions until they - Thin to nothing,
- Change into something else,
- Abut against a barrier.
103Principle of Inclusion
- Erosion surfaces exist in the rock record...
- Fragments within strata above are derived from
the older strata below ? they are older than the
strata containing them. - The strata containing the fragments are younger
than the strata the fragments came from.
104Conformable Contact
- Layers of rock that have been deposited without
any interruption. - No gaps in time.
- No missing record due to erosion, non-deposition,
etc.
105Unconformity
- 3 types of break in the rock record.
- Such surfaces represent
- A hiatus in deposition and/or
- A period of erosion.
- ?Missing time
- ?Significant events.
106Angular Unconformity
- A sharp discontinuity in the rock record
separating strata that are not parallel. - Indicates that during the break, a period of
deformation occurred.
107Disconformity
- A break in the rock record across which there is
little change in stratal orientation. - Often just a pause in deposition (subtle).
- May also be obvious erosion surface.
108Nonconformity
- Horizontal sedimentary rocks on top of eroded
crystalline rocks (metamorphic or igneous). - Requires erosion to bring crystalline rocks to
the surface. - Buried topography.
- Intrusive contact is different!
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111Sedimentary Rock Types
- Sedimentary rocks are classified by the particles
that make them up - Detrital (terrigenous or clastic) sedimentary
rocks - Chemical sedimentary rocks
112Clastic Sedimentary Rocks
- Generally consist of clasts (large pieces) within
a matrix (finer grained pieces, all held together
by a cement. - Classified according to the size of the clasts.
- Classified by the angularity of the clasts
(breccia vs. conglomerate). - Classified by other characteristics (fissility,
composition).
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114Fig. 6-17, p. 156
115Massive claystone (not fissile)
Shale (fissile claystone)
Siltstone
116Fig. 6-18d, p. 157
117Fig. 6-18c, p. 157
118Quartz sandstone
Greywacke (rock fragment) sandstone
Arkose (gt 25 feldspar) sandstone
119Breccia
120Fig. 6-18b, p. 157
121Conglomerate
122Fig. 6-18a, p. 157
123Chemical Sedimentary Rocks
- Result from the precipitation of minerals from a
solution. Material in solution originated in the
weathering environment. - Precipitation processes either biological or
non-biological. Biochemical sedimentary rocks
result from chemical processes of organisms. - Chemical sedimentary rocks classified based on
composition/chemical process
124Chemical Sedimentary Rocks
- Carbonates (limestone)
- biochemical
- fossiliferous limestone
- coquina
- chalk
- oolitic limestone
- non-biochemical
- Evaporites (evaporation)
- rock salt
- gypsum
125Table 6-2, p. 156
126Carbonate Sedimentary Rocks
- Carbonates are composed of calcite (CaCO3) and/or
dolomite (CaMg(CO3)2). Dolomite is probably
altered calcite - Most are biochemical (but not all).
- Chemical process is the dissolution and
precipitation of carbonate from water/carbonic
acid solutions.
127Biochemical Carbonate Sedimentary Rocks
- Fossiliferous limestone deposition of carbonate
matrix with organically-produced shells and other
fossils included - Coquina broken shells held together by
carbonate cement (dense fossiliferous limestone). - Chalk microscopic shells held together by
carbonate cement (microscopic fossiliferous
limestone). - Oolitic limestone sandstone formed of
cemented together spheres of carbonate (ooids).
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129Fig. 6-19a, p. 158
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131Fig. 6-19b, p. 158
132Fig. 6-19c, p. 158
133Fig. 6-19d, p. 158
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135Carbonate Sedimentary Rocks
- A couple of examples of non-biological
carbonates - Caliche B soil horizion deposit of carbonate
formed when alkaliine groundwater rises to the
surface and evaporates into a crumbly powder. - Travertine calcareous deposits from groundwater
(freshwater) - cave deposits (speleothems)
- surface mound deposits around hot springs, desert
lakes (tufa)
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138Evaporites
- Form by inorganic chemical precipitation of
minerals (usually salts) from solution. - Include halite (rock salt) and gypsum
- Why precipitate? Solution becomes saturated
(solvent cant hold any more dissolved ions).
139Fig. 6-20a, p. 159
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141Fig. 6-20b, p. 159
142Siliceous Chemical Sediments
- Dominated by silica (SiO2). Formed by
- Accumulation of silica-secreting organisms such
as diatoms, radiolarians, or some types of
sponges ? diatomaceous earth, layered chert
(ooze). - Chemical reactions of dissolved silica replacing
carbonate in limestones ? chert interbeds
143Fig. 6-20c, p. 159
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145Organic Chemical Sediments
- Coal compressed, altered remains of ancient
organisms. -
- Forms in oxygen-deficient (reducing)
environments. Bacterial decay is impeded. - Dead plant junk ? peat ? lignite ? bitumen ?
anthracite. - Each step in this diagenetic process involves
- Compression and dewatering
- Removal of more volatile elements (O, N, H)
- Concentration of C
146Fig. 6-20d, p. 159
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148Other
- Phospates. Nodules on the searfloor (ooze).
Fossilized guano (bird crap). - Iron formations. Sulfides. Bog iron.
Laterites. Placer deposits. Oolites! Banded
iron formation. - Mn nodules on ocean floor.
149 Sedimentary Facies
- Sedimentary rocks reflect the environment of
deposition. - The distribution and depositional patterns of
sedimentary rocks (facies changes) tell us about
environment. - Sedimentary structures also tell us about
environment and process.
150Fig. 6-16, p. 155
151 Sedimentary Facies
- A given horizon of sediment deposited at a single
time (a geologic timeline) will extend in all
directions. - But, as you trace a sediment stratum laterally
(over large enough distances), it will change in
composition and/or texture. Why? - Moving towards/away from different sources.
- Moving across different environments with
different processes (agent energy). - At any one time, different environments are
operating in different places, and each will have
characteristic deposits ? facies.
152Fig. 6-27b, p. 165
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154Fig. 6-21a, p. 160
155Fig. 6-21b, p. 160
156Fig. 6-21c, p. 160
157Fig. 6-21d, p. 160
158Fig. 6-21e, p. 160
159Fig. 6-21f, p. 160
160Fig. 6-21g, p. 160
161Fig. 6-21h, p. 160
162 Transgressions Regressions
- The seas came inthe seas went out again
- Sea level fluctuations can cause changes in
facies over large areas as time passes ? sediment
changes vertically in a column. - Transgression coarse to fine. Ocean comes in.
- Regression fine to coarse. Ocean goes out
again.
163Fig. 6-21, p. 160
164Fig. 6-27b, p. 165
165 Sedimentary Structures
- Keys to the past. Allow us to determine facies,
environment, and process. - Shapes and morphology (tool marks, etc.)
- Textures (coarse or fine well sorted or not).
- Bedforms (ripples, dunes, etc.)
- Three-dimensional geometry of deposits (sheets or
channels) - Fossils
- Interpreted based on comparison with present-day
processes.
166Sedimentary Structures
- Strata (bedding) horizontal layers (mm to m
scale). Represent timelines. Separated by
bedding planes transitions in sediment size,
composition, etc. - Graded bedding upward decrease in sediment size
within a single bed. Indicative of order of
settling of particles from suspension as in a
turbidity current. Lateral grading in bedding,
too (facies changes) - Cross bedding bedding at angles to the
horizontal at time of deposition. Indicative of
dunes, river deltas, submarine environments where
flow direction changes ? clues to paleocurrents.
167Fig. 6-22b, p. 161
168Fig. 6-22a, p. 161
169Varves climatically driven laminations
(seasonal) light (coarse grained) is summer,
dark (fine grained) is winter
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171Fig. 6-23a, p. 162
172Fig. 6-23b, p. 162
173Sedimentary Structures
- Bedforms regularly repeating features on a
bedding plane of sediment (sand) that is (was)
being moved. - Ripples
- Dunes
- Indicate environment (water or wind river or
shore) - Indicate flow direction and energy
- Indicate paleo-water temperature??
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175Fig. 6-24a, p. 163
176Fig. 6-24b, p. 163
177Fig. 6-27a, p. 165
178Fig. 6-24c, p. 163
179Fig. 6-24d, p. 163
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181Sedimentary Structures
- Mud cracks polygonal cracks formed as mud
dried indicates shallow water used to show
which way up. - Raindrops impressions of falling rain in
mudstone. Used to tell environment which way
is up. - Flute marks depressions scoured out by the flow.
- Tool marks tracks left by objects dragged along
bedding surface by flow. - Sole marks casts (fillings) of primary
structures (like flute and tool marks). Used to
tell which way is up.
182Fig. 6-25a, p. 163
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184Fig. 6-25b, p. 163
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187Sedimentary Structures
- Soft sediment deformation
- Flame structures
- Slump
- Disrupted/folded/convoluted bedding
- Indicate something happened to sediment after
deposited but before it was lithified
(dewatering, storms, earthquakes, dropped
boulders)
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189 Fossils Trace Fossils
- Body fossils
- Footprints
- Trails
- Burrows
- Stromatolites
190Fig. 6-26a, p. 165
191Fig. 6-26b, p. 165
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195Sedimentary Resources
- Gravel and sand ? construction, placer deposits
- Clay ? ceramics
- Limestone ? cement
- Evaporites ? chemicals
- Phosphates ? fertilizers
- Iron formations ? metal ores
196Sedimentary Resources
- Coal, petroleum natural gas for fuel
chemicals. - Deep sedimentary source rocks (contain dead plant
and animal matter) ? heat pressure ?
hydrocarbons. - Hydrocarbons accumulate in reservoir rocks with
high porosity permeability. - Cap rocks with low permeability trap
hydrocarbons. - Facies changes and structural features (faults)
important for geometries of reservoirs, caps, and
traps.
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198Fig. 6-28a, p. 167
199Fig. 6-28b, p. 167