Title: Isotope Selection:
1Isotope Selection
Lunar Radioisotope Power System
Presented by Caleb Robison, Dan
Osterberg Contributions from Jeff Katalenich,
Joel Sasser, Palani Ramu
2Outline
1.1 Mission Requirements and Isotope
Consideration Factors 1.2 Isotope Selection
Process 1.3 Initial Candidates 1.4 Final
Candidates 1.4.1 Power Densities 1.4.2 Decay
Modes and Shielding 1.4.3 Production/Availability
1.5 Curium Considerations 1.5.1 Radiation
Concerns 1.6 Sr-90, Pu-238, Cm-244 Comparison 1.7
Conclusions
3Mission Requirements and Isotope Consideration
Factors
Minimum of 5 year mission Single RPS to
provide 2.5 kWe until EOM Realistic isotope
extraction/production costs Heat source
assembly must survive re-entry and impact
Minimal dose to workers during fabrication
Total mass (including shielding) reasonable for
launch into space
Isotope Properties Considered Half Life
Power Density (including compound form and
isotopic concentration) Dose rate / Shielding
requirement Production / Availability / Cost
41.2 Isotope Preliminary Selection
51.3 Initial Candidates
Power Density
Availability
Power Density
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
6Availability
Isotopic Separation
Availability
Availability
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
7Availability
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
81.4 Final Candidates
On the basis of power density at EOM, radiation
dose, and availability, the most suitable
isotopes for use in a Lunar RPS
91.4.1 Power Densities
In order to maintain 2.5 kWe in a single RTG unit
for a 5 year mission, a volumetric power density
of 8.66 W/cc at EOM is required.
Note Values based on assumption of 25 heat to
electricity conversion
104.1.2 Decay Modes and Shielding
114.1.3 Decay Modes and Shielding
124.1.4 Production and Availability
Pu-238
Purchase - most cost effective when
available in stockpile - must be produced if
widespread use continues into the future
Breed from Np-237 - approximately 400kg
available in storage at the INL - ATR could be
used for Pu-238 production - cost of 150-200 M
for infrastructure and 15-20 M/year
operational - rate of approximately 5kg/yr
Breed from Am-241 - Am-241 neutron capture ?
Am-242 ? Cm-242 decays by alpha ? Pu-238 -
Spent fuel has 60 - 1370g/MTIHM of Am-241
Source Stephen Johnson, INL
134.1.4 Production and Availability
Sr-90
Stockpile - widely available in United
States stockpiles - 2.3 million Ci as of 2007 -
exists in the form of SrF2 - separated from
other waste - Sr-90 composes 50-60 of Strontium
isotopically - stored at Hanford Site
144.1.4 Production and Availability
Cm-244
Recover from vitrified storage at Savannah
River Site - F Canyon Tank at SRS contained
15,000 L fission products in dilute nitric acid
was vitrified into a lanthanide borosilicate
glass - 99 recovery of Cm by means of 15.7M
nitric acid - approximately 2.56 kg of Cm-244
available from this source Extraction from
spent fuel - 27.2 - 85.6 g/MTIHM in UO2 fuels -
time dependent - Much higher amounts in MOX or
plutonium fuels - Urex4 process has the
ability to separate Cm - Depends on change in
U.S. fuel cycle strategy - 1500 ton/year
facility could yield 30 40 kg/year
154.1.4 Production and Availability
U-232
Neutron irradiation of U-233 - Yields gram
quantities per year too expensive Proton
beam Th-232 - Yields gram quantities per year
too expensive Extract from spent fuel -
Small amounts low isotopic percent Neutron
irradiation from Th-230 - Small yield
moderate quantities available
161.5 Curium Considerations
Neutron Flux - 4.3 x 107 neutrons/second/gram
Fuel Form - Foil - Cm2O3 - Cm Hydride
Helium Gas - 1 gm Cm-244 evolves 45.9cm3 He gas
in 1 half life (18.1 yr) Reprocessing
Concerns - Cm-244 generates much more heat in
concentrated solutions than has been dealt with
in wide scale production (up to 700Wt/L) -
Concentrated streams of curium in reprocessing
may approach critical mass of Cm-245
171.5.1 Radiation Concerns
Cm-244
Major Radiations 5.80 MeV a (76.4)
5.76 MeV a (23.6) 42.8 keV ? (2.6E-4)
4.3 x 107 n/sec/gm
Our shielding calculations indicate that 10cm of
borated polyethylene will supply sufficient
neutron shielding.
181.5.1 Radiation Concerns
- Pu-238 (PuO2) modeled for baseline and accuracy
(compared to existing papers) - Neutron - 0.3610.002 mrem/hr
- Photon - .650.03 µrem/hr
- Total .36368 mrem/hr
- Cu-244 (Cu2O3)
- Neutron 2.010.03 rem/hr
- Photon - 56.50.2 mrem/hr
- Total 2.0967 rem/hr
Above GPHS Model (MCNP VisEd) Left Dose vs.
Mass of Pure LiH Shielding GPHS General
Purpose Heat Source
191.6 Sr-90, Pu-238, Cm-244 Comparison
201.7 Conclusions
Sr-90 and Pu-238 would work for this
application - Power density is low - Launch
masses will be high - Sr-90 is the cheapest
isotope to acquire Cm-244 is the best
choice - Power density is high - Launch
masses will be low - Can be recovered through
proven methods in large quantities - Sources
exist and will source concentration will increase
with time U-232 would be ideal for this
application - Long string of alpha decay
U-232 ? Th-228 ? Ra-224 ? Rn-220 ? Po-216 ?
Pb-212 - Low launch mass - Production
limited
21Questions?
22Evaluation of General Purpose Heat Source Powered
Stirling Technologies for a2.5 kWe Lunar Surface
Power SourcePresented By Chris Miller and Troy
ReissContributions by Chris Miller, Troy
Reiss, Jeff Katalenich, Logan Sailer, Caleb
Robison August 10, 2007
23Contents
- Overview of existing space power conversion
technology - Justification for selection of Stirling power
conversion system - Review of current Stirling systems for space
applications - Concepts offering potential improvement to
existing technology
24Radioisotope Thermoelectric Generator (RTG)
- Flown on Galileo, Ulysses, Cassini, and New
Horizons missions - Powered by Pu-238 General Purpose Heat Source
(GPHS) - Produced approximately 300 We using 572 silicon
germanium thermoelectric elements - Thermal power 4400-4500 W from 18 GPHS modules,
mass 55.9 kg, specific power 5.5 We/kg,
efficiency 6.7-6.8 - Reliable, but electrical power output well below
lunar surface mission requirement
25Stirling Power Conversion System
- Other power conversion systems explored to
provide greater power output than RTG - Stirling and Brayton systems found to be capable
of supplying desired power - Stirling determined to be best power conversion
system due to better scaling at desired power
level - Better scaling results in lower mass and higher
efficiency than Brayton cycle based power
conversion system
26Stirling vs Brayton1 kW to 10 MW
27Existing TechnologyDual-Opposed Technology
Demonstration Converters
- Hot end temp 923K
- Cold end temp 333K
- 2 55 We Stirling
- Led to development of the SRG110
- Achieved 26,000 hours of operation
- Specific power of 3.5 We/kg
28Sunpower Advanced Stirling Converter (ASC)
- Resulted from the SRG110
- Free piston design
- Weight and size reduction
- 88 We at 38 Efficiency
- Hot end 1123K
29Advanced Stirling Radioisotope Generator(ASRG)
- Lifetime of 14 years plus 3 years of storage
- BOM Power Output 140 We
- EOM 126 We (14 yrs)
- Projected Mass 20.24 kg
- Projected Specific Power 7.0 We/kg (Using Pu)
- 72.5 cm L x 41 cm H x 29.3 cm W
- Beryllium housing
- Future model projects 8.5 We/kg
30Stirling Lunar Power System (LPS)
- Stacking GPHS modules has limits as distance
increases from the Stirling converter - Radial configuration allows all GPHS modules to
be in contact with the hot shoe - Can accommodate many GPHS modules
- Ni-200 hot shoe for high thermal conductivity
31Potential Improvements
- Problems
- Current technology fails to meet the 2.5 kWe goal
- Multiple units of the ASRG to meet power
requirements would be too heavy - Current heat rejection systems subjected to lunar
day/night cycles - Changing environmental conditions changes cold
end temperature, affects Stirling performance - Solution
- Development of Stirling converters with a higher
electrical power output - Designs to incorporate multiple Stirling
converters were developed - Concept to reduce cold end variation during
changing environmental conditions proposed
32Development of New Stirling Converters
- Nasa has recently funded development of a 5 kWe
free-piston stirling converter for lunar
application - Sunpowers EG1000 is a 1.2 kWe free piston
stirling converter has been in use for DOD
applications for several years - Infinia Corp. is working to develop a 3 kW
free-piston stirling convertor for solar
applications
33Tri-core with Two Stirling Converters
- Based on LPS configuration
- Used to determine capability of other
configurations - Results would be baseline for other designs
34Quad-core and Octagon-core
- Based on LPS design
- Ability to attach multiple Stirling converters
- Stirling converters with higher power output
could be attached
35Heat Pipe Concept
- 4 converters .75 kWe each
- 5 GPHS blocks (Cm 244)
- Heat pipes couple GPHS modules to Stirling hot
ends - Working fluid transport via capillary forces in a
wicking structure - Heat rejected to surroundings via cold end
radiators - Possible power output of 2.5 to 3 kWe
- Designed to be easily assembled prior to or after
launch
36Stirling Cooling
- All designs discussed thus far cooled from a cold
flange attached to the cold end of the engines - The cold flanges are coupled to the outer shell
which acts as the radiator for the unit - Issues arise from changing lunar day/night
temperatures and lunar dust collection on
radiators - Method of heat rejection from cold end identified
as major potential area for improvement of
existing concepts
37Sub-lunar Surface Heat Sink Concept
- Current lunar Stirling concepts exposed to
changing environmental conditions during lunar
day/night cycle - Potential to eliminate this complication through
use of constant -30 C sub-lunar surface
temperature as heat sink - Liquid metal or sulfur injected into bedrock or
regolith during drilling operation - Liquid diffuses into lunar material, providing
higher thermal conductivity sink than lunar
material alone - Stirling cold end coupled to sink with high
thermal conductivity material prior to freezing - Heat rejected via conductive path to sink instead
of radiator
38Sub-lunar Surface Heat Sink Concept
- Advantages
- Elimination of fluctuating cold end temperature
and power output - No exposure of radiators to lunar dust
- Reduced shielding and insulation mass if entire
assembly placed below lunar surface - Potential mass savings from removal of radiators
- Remaining issues
- Thermal analysis must determine necessary size of
heat sink - Cold end temperature must be determined and
compared with cold end temperatures of current
concepts - Tradeoffs between sulfur and metal sink must be
determined and evaluated - Physical location of sink, converter, and GPHS
units must be determined
39Conclusions and Future Work
- Stirling converters best power conversion option
for 2.5 kWe lunar surface radioisotope power
system - Free piston Stirling should be basis for such
systems - Great potential for improvement of existing
Stirling systems through utilization of sub-lunar
surface heat sink - Extensive modeling and thermal analysis must be
performed on all proposed concepts to determine
if they offer improvements over existing Stirling
systems
40Questions?
41RPS Cooling Options on the Moon
- Holly Szumila,
- Mookesh Dhanasar
- Benjamin Schreib
- Center for Space Nuclear Research
- August 10, 2007
42Outline
- Assembly / In-transit cooling (active)
- Cooling options on the moon
- Surface
- Sub-surface
- Analysis
- Thermal models (1-D analytical, 2-D numerical)
- Compare different sources
- Conclusions
- Questions
43RPS Cooling (Assembly and In-Transit)
- Already have assembly active cooling.
- In transit cooling systems already exist.
- Include fins.
44Cooling options on the moon
- Lunar Surface
- Lunar Sub-surface
- Regolith
- Bedrock
45Lunar Surface
- Lunar Surface
- Unstable temperatures
- Micrometeorites
- Radiation
- Lunar Dust
46- Radiation considerations
- Solar wind, peak solar flares, galactic cosmic
radiation. - Primary concern solar cosmic radiation, or solar
flares. - Heavy ion fluxes not accounted for using MCNPX,
but can travel through layers of shielding and
spallation effects (high energy neutron fluxes). - Proton and neutron fluxes can only cause heat
deposition to RTG on nano-Watt magnitude. - Lunar Dust
- Micrometeorites
- Caused thin films on Apollo structures, thought
to pile a great deal and cause wear to metal over
extended periods of time.
47Lunar Surface - Conditions
LUNAR AND MARTIAN ENVIRONMENTAL INTERACTIONS WITH
NUCLEAR POWER SYSTEM RADIATORS Maria E.
Perez-Davis and James R. Gaier NASA Lewis
Research Center, Cleveland, OH 44135 Cynthia M.
Katzan Sverdrup Technology, Inc., Lewis Research
Center Group
48Lunar Sub-Surface (Regolith)
- Lunar sub-surface (Regolith)
- Thermal shield.
- Constant temperature.
- Radiation shield.
- Shielding against micro-meteorites.
49- Lunar Bedrock
- Difficulty in drilling
- Less known on bedrock
- Constant temperature sink
50Lunar Sub-Surface Thermal analysis (Regolith)
51RPS Thermal Analysis-Model
52RPS Thermal Analysis-Assumptions
- The analysis is carried out in 1-D only.
- Steady-State conditions apply.
- Heat generation is constant and uniform.
- The thermal conductivity for the material is
constant. - The RTG is symmetric about its centerline.
- There is a conduction-convection interface with
the outer surface of the RTG and the medium.
53RPS Thermal Analysis Theory (Analytical)
54RPS 1-D Temperature Profile
55Surroundings Analysis - Model
56Surroundings Analysis - Assumptions
- 1-D heat transfer.
- Steady State conditions apply.
- There is no heat generation in the region of
interest. - There is no bulk fluid motion, so heat transfer
is a special case of conduction. - The temperature at the surface of the RTG is
known. - The ambient temperature is known.
57Surroundings Analysis Theory (Analytical)
58RPS Surrounding Area Temperature Profile
59Surroundings 2-D Analysis (Numerical)
60Surroundings 2-D Analysis (Point Source) Results
61Surroundings 2-D Analysis (Numerical) Results
62Compare Various RPS Sources
63Compare Various RPS Sources
64Compare Various RPS Sources
65Compare Various RPS Sources
66Conclusion
- From our research it is desirable to have the RPS
buried in the regolith. - From the thermal analysis, a simple heat transfer
tool was created. - It was used to determine the thermal profile for
a variety of sources. - From this analysis it is observed that for the
commonly used isotope source, approximately 0.8 m
of sulfur is required before phase change occurs.
67Future Work
- Refine model.
- Detail 3-D
- Investigate various convective mediums.
68Questions
69Acknowledgments
- Dr. Steve Howe
- John Bess, Jon Webb
- Ms. Kristi Bailey
- INL
- 2007 CSNR Summer Fellows
70Isotope Selection
Radioisotope Powered Vehicle
Presented by Jeff Katalenich Contributions
from Joel Sasser, Caleb Robison, Dan
Osterberg, Troy Reiss, Jeff Perkins
71Outline
1.1 Mission Requirements and Isotope
Consideration Factors 1.2 Isotope Selection
Process 1.3 Initial Candidates 1.4 Final
Candidates 1.4.1 Power Densities 1.4.2 Decay
Modes and Shielding 1.4.3 Production/Availability
1.5 Isotopic Mass Requirements 1.6 Ru-106,
Ce-144, Po-210, Cm-242 Considerations 1.6.1 Reali
stic Power Densities 1.6.2 Power Density
Decay 1.7 Curium Considerations 1.7.1 Radiation
Concerns 1.7.2 Reprocessing Options 1.8
Conclusions
721.1 Mission Requirements
Minimum flight time of 7-12 months Isotope
shall provide 20-40 kWt Realistic isotope
extraction/production costs Heat source
assembly must survive re-entry and impact
Minimal dose to workers during fabrication
Total mass (including shielding) reasonable for
our flight unit and for launch into space
Isotope Properties Considered Half Life
Power Density (including compound form and
isotopic concentration) Dose rate / Shielding
requirement Production / Availability / Cost
731.2 Isotope Preliminary Selection
741.3 Initial Candidates
Availability
Gamma Dose
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
75Gamma Dose
Isotopic Separation
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
76Isotopic Separation
Availability
Availability
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
77Availability
Availability
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
78Availability
Notes 1) Power Density of Compound at 5 years
(isotopic considered for Sr-90, Ru-106, Ce-144,
Pu-238, Cm-244) 2) Spent fuel concentrations at
5 years out of reactor
791.4 Final Candidates
On the basis of power density at EOM, radiation
dose, and availability, the most suitable
isotopes for use in the RPV are
801.4.1 Power Densities
Analysis showed that a minimum power density of
0.40 W/g is necessary based on mass requirements.
Note Compound Power Density Values Account for
Isotopic Concentration and are taken at 1.5 years
811.4.2 Decay Modes and Shielding
821.4.3 Production and Availability
Sr-90
Stockpile - Widely available in United
States stockpiles - 2.3 million Ci as of 2007 -
Exists in the form of SrF2 - Separated from
other waste - Sr-90 composes 50-60 of Strontium
isotopically - Stored at Hanford Site
831.4.3 Production and Availability
Ru-106
Extraction for Spent Fuel - 2.086kg/MTU
Ruthenium in UO2 spent fuel - Ru-106 has 7
isotopic concentration - Possibility of minor
isotopic separation?
841.4.3 Production and Availability
Ce-144
Stockpile - 2.28kg/MTU Cerium in spent UO2
fuel - Ce-144 has isotopic concentration of
9-13 - Possibility of minor isotopic
separation?
851.4.3 Production and Availability
Po-210
Neutron Irradiation of Bi-209 - Bi-209 gtgt
Bi210 gtgt 5 day half life gtgt Po-210 - Bi-209
composes 100 of natural Bismuth - Bi-209 has
capture cross section of 0.3 microbarn - Ni-210
and Po-210 have capture cross sections in the
millibarns - Large batch production - High
neutron flux required
861.4.3 Production and Availability
Pu-238
Purchase - Most cost effective when
available in stockpile - Must be produced if
widespread use continues into the future
Breed from Np-237 - Approximately 400kg
available in storage at the INL - ATR could be
used for Pu-238 production - Cost of 150-200 M
for infrastructure and 15-20 M/year
operational - Rate of approximately 5kg/yr
Breed from Am-241 - Am-241 neutron captures ?
Am-242 which decays ? Cm-242 which decays ?
Pu-238
Source Stephen Johnson, INL
871.4.3 Production and Availability
Cm-242
Neutron irradiation from Am-241 - Am-241
gtgt Am-242 gtgt 16 hour half life gtgt Cm-242 -
Am-241 available in 78-87 pure isotopic form out
of spent fuel aged 10-30 years in quantity of
929-1560 g/MTIHM - Best yield at neutron flux of
7 x 1014 n/sec/cm2 similar to ATR - Period of
4-6 months gives best yield - Cm-242 is
available in spent fuel, but in small isotopic
percentages - Neutron irradiation yields purest
form of Cm-242
881.4.3 Production and Availability
Cm-244
Recover from vitrified storage at Savannah
River Site - F Canyon Tank at SRS contained
15,000 L fission products in dilute nitric acid
was vitrified into a lanthanide borosilicate
glass - 99 recovery of Cm by means of 15.7M
nitric acid - approximately 2.56 kg of Cm-244
available from this source Extraction from
spent fuel - 20-30 g/MTU in UO2 fuels -
400-1000 g/MTU in Pu recycled fuels -
reprocessing only UO2 fuels would allow for
production of 15kg/yr - reprocessing 25 MOX and
75 UO2 allows production of 200kg/yr - Urex
process separates Am/Cm from waste stream -
primary concerns include thermal loading and
neutron dose
891.5 Isotopic Mass Requirements
Note Assumes a necessary thermal output of 20 kW
at EOM
901.6 Ru, Ce, Po, Cm-242 Considerations
Ru-106, Ce-144, Po-210, and Cm-242 appear to be
excellent isotopes for space missions, but the
following variables need to be taken into
consideration Mission Timeline
Achievable Power Densities Power Densities
Changes with Time
911.6.1 Realistic Power Densities
When calculating power densities it is necessary
to take isotopic concentration and compound form
into account in addition to energy per decay.
Note Power densities taken at 1 month after
fabrication
921.6.2 Power Density Decay
The short half lives of Ru-106, Ce-144, Po-210,
and Cm-242 make them preferable for short term
missions
931.7 Curium Considerations
Neutron Flux - 4.3 x 107 neutrons/second/gram
- Effectively shielded by Cd Availability -
Cost for recovery facility - Access to fuels
with high Cm content - Reprocessing prospects in
the US Fuel Form - Foil - Cm2O3 - Cm
Hydride Helium Gas - 1 gm Cm-244 evolves
45.9cm3 He gas in 1 half life (18.1 yr)
Critical Mass - Concentrated streams of curium
in reprocessing may approach critical mass of
Cm-245
941.7.1 Radiation Concerns
Cm-244
Major Radiations 5.80 MeV a (76.4)
5.76 MeV a (23.6) 42.8 keV ? (2.6E-4)
4.3 x 107 n/sec/gm
Cm-244 generates much more heat in concentrated
solutions than has been dealt with in wide scale
production (up to 700Wt/L)
Our shielding calculations indicate that 10cm of
borated polyethylene will supply sufficient
neutron shielding.
951.7.1 Radiation Concerns MCNPX
- 16.5 kg Cm2O3 required for 40 kW (thermal)
- Unshielded dose 8.6 rem/hr
- 300 kg LiH 50 mrem/hr
- 90 kg LiH and 190 kg of a Gd/U mixture 60
mrem/hr - Pure LiH may be more attractive than including
Gd/U if volume is not important 300 kg of LiH
should fit inside the launch vehicle
Above RPV source model (MCNP VisEd)
dose cylinder and isotope shielding Left Dose
vs. Mass of pure LiH shielding
961.7.2 Reprocessing Options
Production Facilities - Studies in 1970s
suggested Barnwell Nuclear Fuel Plant as Cm
reprocessing site - Separate study suggested
modifications to Hanford, Savannah River, Idaho
Chemical Processing Plant, and Oak Ridge -
These studies were performed before 1979 and made
the assumption that Pu recycled fuel would
become widespread in the US Recovery -
Recover 90 of Cm in waste - Concentration in
spent fuel most dependent on Pu-242
concentration - Best to process fuel 6-18 months
out of the reactor, but up to 4 years
971.8 Conclusions
Sr-90 and Pu-238 could work for this
application - power density is low - launch
masses will be high - Sr-90 is the cheapest
isotope to acquire Cm-244 is the best
choice - power density is high - launch
masses will be low - can be recovered through
proven methods in large quantities - sources
exist and will source concentration will increase
with time Several issues arise with using
Ru-106, Ce-144, Po-210, or Cm-242 -
Fabrication of an isotope that is very hot in
concentrated form - Mission timeline
critical - Higher shielding requirements for
Ru-106 and Ce-144
98Questions