Title: Acid Base Titrations
1Acid Base Titrations
2In a titration the molarity of one chemical is
determined by reacting it with another and
knowing the molarity of the other chemical.
3Special Equipment is used for a titration
Burette
Erlenmeyer Flask
Magnetic Stirrer
Pipette
4Digital Balance
Solid acid to make a standard solution
Volumetric Flask
5Titration Calculation 1. 6.50 mL of 0.100 M
H2C2O4 is required to neutralize 10.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2C2O4 2KOH ? K2C2O4
2H2O 0.00650 L 0.0100 L 0.100 M ? M this
is a molarity question molarity draw a
line KOH
KOH square brackets means the molarity
or concentration of what is inside.
6Titration Calculation 1. 6.50 mL of 0.100 M
H2C2O4 is required to neutralize 10.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2C2O4 2KOH ? K2C2O4
2H2O 0.00650 L 0.0100 L 0.100 M ? M You
need to get moles KOH over litres KOH You need to
start with H2C2O4 and then use stoichoimetry KOH
0.00650 L H2C2O4
7Titration Calculation 1. 6.50 mL of 0.100 M
H2C2O4 is required to neutralize 10.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2C2O4 2KOH ? K2C2O4
2H2O 0.00650 L 0.0100 L 0.100 M ? M KOH
0.00650 L H2C2O4 x 0.100 mole
1 L
8Titration Calculation 1. 6.50 mL of 0.100 M
H2C2O4 is required to neutralize 10.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2C2O4 2KOH ? K2C2O4
2H2O 0.00650 L 0.0100 L 0.100 M ? M KOH
0.00650 L H2C2O4 x 0.100 mole x 2 mole
KOH 1 L 1 mole H2C2O4
9Titration Calculation 1. 6.50 mL of 0.100 M
H2C2O4 is required to neutralize 10.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2C2O4 2KOH ? K2C2O4
2H2O 0.00650 L 0.0100 L 0.100 M ? M KOH
0.00650 L H2C2O4 x 0.100 mole x 2 mole
KOH 1 L 1 mole H2C2O4 0.0100
L
10Titration Calculation 1. 6.50 mL of 0.100 M
H2C2O4 is required to neutralize 10.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2C2O4 2KOH ? K2C2O4
2H2O 0.00650 L 0.0100 L 0.100 M ? M KOH
0.00650 L H2C2O4 x 0.100 mole x 2 mole
KOH 1 L 1 mole H2C2O4 0.0100
L 0.130 M
11If you get data in a table, you need to subtract
the final burette reading from the initial to get
the volume of acid or base added. A burette is a
device used to deliver a volume of solution and
determine the amount that was added. If you get
more than one run or trials, average them but
reject any volumes that are way off. Use some
common sense. Burette Volume in
mL Initial 0.00 8.95 17.41 Final 8.95
17.41 25.85 Volume Added 8.95 mL 8.46 mL 8.44
mL reject average 8.46 8.44 8.45
mL 2
12Now it's your turn to try one!
13Titration Calculation 2. 8.45 mL of 0.200 M
H2SO4 is required to neutralize 25.0 mL of KOH
solution in a titration. Calculate the base
concentration. H2SO4 2KOH ? K2SO4
2H2O 0.00845 L 0.0250 L 0.200 M ? M KOH
0.00845 L H2SO4 x 0.200 mole x 2 mole
KOH 1 L 1 mole H2SO4 0.0250
L 0.135 M
14Calculate the mass of H2C2O4.2H2O required to
make 100.0 mL of a 0.1000 M standard solution to
use in your titration lab tomorrow.
15Calculate the mass of H2C2O4.2H2O required to
make 100.0 mL of a 0.1000 M standard solution to
use in your titration lab tomorrow. 0.100 L
16Calculate the mass of H2C2O4.2H2O required to
make 100.0 mL of a 0.1000 M standard solution to
use in your titration lab tomorrow. 0.100 L
x 0.1000 mol 1 L
17Calculate the mass of H2C2O4.2H2O required to
make 100.0 mL of a 0.1000 M standard solution to
use in your titration lab tomorrow. 0.100 L
x 0.1000 mol x 126.06 g 1 L 1 mole
18Calculate the mass of H2C2O4.2H2O required to
make 100.0 mL of a 0.1000 M standard solution to
use in your titration lab tomorrow. 0.100 L
x 0.1000 mol x 126.06 g 1.261 g 1
L 1 mole