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High Volume Manufacturing of MEAs

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Title: High Volume Manufacturing of MEAs


1
High Volume Manufacturing of MEAs other bad
things
  • 3rd Annual MEA Manufacturing Symposium Aug 22,
    2007

2
Mind of Mencia .Willis
I was a simply Mechanical Engineer before I met
Fuel Cells
3
Mind of Mencia .Willis-then Fuel Cells
became my life
Thermal Engineer
Materials Engineer
Mechanical Engineer
Electro-Chemist
Hydraulic Engineer
Thermal Engineer
Electrical Engineer
4
Mind of Mencia .Willis-then Fuel Cells
became my life now scrambled eggs!
5
A little about PET Manufacturing of MEAs
National Composite Center Dayton, Ohio
6
PET Equipment
Wet Processing Machines
Lab Laminator
Catalyst Electro-deposition Machine
Laminator flow Assembly bench
50 Ton TMP Vacuum Oven Press
24 Laminator Anti-Static roller
7
High Volume Manufacturing???
  • Batch laminating of MEAs versus Continuous Roll
    Bonding
  • Batch bonding
  • Los Alamos National Laboratory
  • 210 C and compressed to 110 lbs per square
    centimeters for 5 minutes.
  • DYMOS
  • Anode pressed at 100Kg/cm2 and 125 C for 5
    minutes
  • Cathode pressed at 50 kg/cm2 and 125 C for 5
    minutes
  • Fraunhofer
  • 126 KN at 128 C for 10 minutes.
  • NOTE
  • If we were to match the Prius production
    (500k units annually) with a 200 volt 50Kw
    electric motor that would require 143MM MEAs
    at 5 minutes each. At 40 hours/week and 80
    efficiency, one operator can produce 19,200 units
    per year! That would require nearly 7500 operator
    for the Prius alone!

8
High Volume Manufacturing
  • Batch laminating of MEAs versus Continuous Roll
    Bonding
  • Roll bonding
  • Actual compression area is small 5mm x width
  • Temperature can be considerably above transition
    temperatures based on rate and heat transfer
  • Pressure (and hence mechanical damage to
    electrode fibers) can be lowered
  • NOTE
  • Again, if we were to match the Prius demand
    and 60 MEAs per minute are possible. With roll
    laminating as a continuous process , with 3
    shifts -7 days per week-52 weeks per year, each
    roll laminating machine would generate over 31MM
    MEAs.
  • THIS WOULD STILL REQUIRE AT LEAST 5 ROLLING
    MACHINES RUNNING CONTINUOUSLY WITHOUT FAILURE!

9
High Volume Manufacturing of MEAs
Lets take a quick view on a topic, some of us
may be familiar .
Anheuser Busch can produce approximately 28
bottles of beer per second !!! If 10 U.S. auto
sales were Fuel Cells32 MEAs per second
10
Electrode Materials
11
Backing Paper-GDL
12
Inconsistent Materials Inconsistent
OperationSame material
13
Know your materials and their limitations
This material had splintering coming through to
the surface and pierced the thin Membrane It
also had different electrical characteristics
depending on orientation
14
And the Fuel Cell leaders are not without fault
  • A 50 m2 roll of a well-know membrane manufacturer
    continues to split at the end seem where it was
    slit!

15
High Volume MEAs
  • Please note that high volume processing does not
    include
  • CVD Processes
  • Spraying
  • Ink printing
  • Or any other processes measured in seconds,
    minutes, or hours !!!

16
Electrode Process
Tape Cast
Spraying
Electro-Deposition
Extruding Rolling
17
Laminating Issues

18
High Production means Rolled materials
19
Lamination takes time to match Rate
Pressure-Temperature to all the materials

20
Precision Energy and Technology (PET)
The Heart of PETs High Volume MEA Fuel Cell
Capability
  • Results
  • MEA Bonder
  • Two Patents (applied)
  • Flexible anode cathode
  • Flexible Membrane
  • Flexible Pressure Temperature-Rate

21
THANK YOU
  • Special Thanks to my Team-mates in the MEA
    Bonder
  • EMTEC
  • Faraday Technologies
  • Case Western
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