?????????? CnH2n 2 - PowerPoint PPT Presentation

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?????????? CnH2n 2

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???????????? Cyclic aliphatic hydrocarbon. ??????? Cyclic aliphatic hydrocarbon. ?????????? Cyclic aliphatic hydrocarbon. ?????????? Cyclohexane ... – PowerPoint PPT presentation

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Title: ?????????? CnH2n 2


1
???????????????????
  • ?????????? CnH2n2
  • ????????? Single bond
  • Straight Chain
  • Cyclic Compound
  • Straight Chain ?????????????? C ??????? 4
    ????????????? isomer

2
??????????????????
3
??????????????????
4
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5
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6
??????????????????
7
??????????????????
8
???????????????????
9
???????????
  • ???????????? C 1 ????? - C 4 ?????
  • ????????? (?????) C 5 ????? - C 10 ?????
  • ?????? ??? ??????? ??? Cyclo alkane
  • ??????? ????????????? ???????????????????
  • ???????? Isooctane n-heptane

10
???????????
  • Kerosene C 12 -C 18 ?????? ?????????? ???
  • Aromatic Compound
  • ?????????????? C 16 - C 20
  • ????????? C16 -C 24
  • ????? C 18 -C 22

11
???????????? (Conformation) ?????????
Sawhorse projection Newman projection
12
????????????? Alkane
  • ??????????????? ???????????? Hydrogenation
    of Alkene
  • ????????????????????? ????????????
    Hydrolysis of Grignard Reagent

13
????????????? Alkane
  • ??????????????? ???????????? Hydrogenation
    of Alkene
  • ??????????????????????????????????????????????????
    ???????????? ??????????? ?? ??????
    ???????????????????????????? 2 ?????
    (?????????????????????)

14
????????????? Alkane
  • ??????????????? ???????????? Hydrogenation
    of Alkene
  • ??????????????????????????????????????????????????
    2 ????????????????????????????????????????????
    ??????????????????? (cis addition)

15
????????????? Alkane
  • ??????????????? 2-methylbutane ?????? alkene
    ??????????????

16
????????????? Alkane
  • ????????????????????? ????????????
    Hydrolysis of Grignard Reagent
  • ??????????????? 2-methylbutane ?????? Grignard
    reagent

17
????????? ??? Alkane
  • Halogenation
  • X-X -----gt 2X. Initial Step
  • X . R-H -----gt R. HX Chain Propagation
  • R . X2 ------gt R-X X. Chain Propagation
  • X . X . , R . R . ------gt Chain
    Termination
  • UV

18
????????? ??? Alkane
  • Oxidation
  • CnH2n2 excessO2 --------gt nCO2 (n1)H2O
  • Pyrolysis

19
???????????? Cyclic aliphatic hydrocarbon
20
??????? Cyclic aliphatic hydrocarbon
21
?????????? Cyclic aliphatic hydrocarbon
22
?????????? Cyclohexane
  • cyclohexane ?? 2 ?????????? chair ??? boat

23
?????????? Cyclohexane
  • cyclohexane ?? 2 ?????????? chair ??? boat
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