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Review Session today in Gildemeister 324 at 12:0012:50

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Strong bases have a net negative charge, but not all negatively charged species ... strain) 2.17. Eclipsed (0, 360 ) Gauche (60, 300 ) Eclipsed (120, 240 ) Anti ... – PowerPoint PPT presentation

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Title: Review Session today in Gildemeister 324 at 12:0012:50


1
Review Session today in Gildemeister 324 at
1200-1250 Chemistry Picnic today 400 PM,
Lions Pavilion on Lake Winona Free Food,
Games Exam Monday 10-15 multiple choice (lt
50) naming short answer/explanation Extra
Credit Home Page
2
Bases
  • Strong bases have a net negative charge, but not
    all negatively charged species are strong bases.
    For example, none of the halides F, Cl, Br,
    or I, is a strong base.
  • Strong bases have weak conjugate acids.
  • Carbanions, negatively charged carbon atoms, are
    especially strong bases. A common example is
    butyllithium.

3
Commonly Used Bases
4
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5
Lewis Acids/Bases
  • A Lewis acid is an electron pair acceptor.
  • A Lewis base is an electron pair donor.
  • Lewis bases are the same as BrØnsted-Lowry bases.
    Both have an available electron paira lone pair
    or a ? bond.
  • Any species that is electron deficient and
    capable of accepting an electron pair is a Lewis
    acid.

6
Lewis Acid/Base Reactions
  • In a Lewis acid-base reaction, a Lewis base
    donates an electron pair to a Lewis acid.

7
Torsional Strain
8
Butane Conformations
9
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