Thermal Analysis Solutions from PerkinElmer

1
Thermal Analysis Solutions from PerkinElmer

• Dr. Lin Li
• Thermal Scientist Director of Business
  Development, China
• Global HyperDSC Seminar Tour
• April 13, 2005
• Hong Kong

2
Thermal Analysis

• A group of analytical techniques
• Each technique defines a material property

TA Use
TA Techniques
DSC Differential Scanning Calorimetry Heat
Flow TGA Thermogravimetric Analysis Mass TG/DTA
Thermogravimetric Analysis/Differential Thermal
Analysis Mass Heat Flow TMA Thermomechanical
Analysis Dimension DMA Dynamic Mechanical
Analysis Modulus
Research / Analytical 70 Routine / QC
20
3
Thermal Analysis is widely used
4
For a wide variety of applications
5
Differential Scanning Calorimetry (DSC)

• A Differential Scanning Calorimeter (DSC)
  measures the amount of energy (heat) absorbed or
  released by a sample as it is heated, cooled or
  held at a constant (isothermal) temperature. The
  precise measure of sample temperature is also
  made with a DSC.

6
DSC Technology
Power Compensation DSC
Quantitative DTA Heat Flux DSC
Pyris 6 DSC Sapphire DSC Competitive DSCs
Diamond DSC

• Derives H
• Uses thermocouples

• Measures H directly
• Uses platinum resistance thermometers

7
The different DSC technologies
Power Compensation DSC

• High resolution / high sensitivity research
  studies
• Absolute specific heat measurement
• Fast Scan DSC applications (HyperDSCTM)
• High throughput laboratories

Heat Flux DSC

• Routine applications
• Near / at line testing in harsh environments
• Education
• Automated operation
• Cost-sensitive laboratories

. are tailored for specific applications
8
High Sensitivity Thermal Analysis DSC family ...

• Diamond DSC
• Unique Power Compensation
• HyperDSCTM for unmatched sensitivity
• Highest signal resolution
• StepScan SW for MTDSC

Research
. for fast, accurate, reproducible results
9
HyperDSCTM
Differential Scanning Calorimetry (DSC) is the
most widely thermal analysis technique for the
characterization of pharmaceuticals, chemicals
and polymers. HyperDSCTM is the premier fast
scan DSC method. It provides the ability to
perform valid heat flow measurements while
heating or cooling a sample with fast linear
controlled rates, up to 500C/min.
a breakthrough DSC method for materials
characterization
10
Thermogravimetric Analysis (TGA)

• A Thermogravimetric Analyzer (TGA) measures the
  change in mass of a sample as the sample is
  heated, cooled or held at a constant (isothermal)
  temperature.

11
TGA Technology

• Top loading Balance below sample area
• Horizontal balance behind sample area
• Bottom loading balance above sample area

12
PerkinElmer High Sensitivity TGA TG/DTA family
...

• Pyris 1 TGA
• Bottom loading
• Ultra-microgram sensitivity
• Highest scan rates and throughput
• AutoStepwise SW
• Autosampler with AccuPik

• Diamond TG/DTA
• Horizontal
• Simultaneous TGA DSC
• 30 position Autosampler
• User-friendly beam change
• Convenient connection to MS and FT-IR

Research
. for fast, accurate, reproducible results
13
Mechanical Analysis (TMA / DMA)

• A Thermomechanical Analyzer (TMA) measures
  dimension changes of a sample (such as expansion
  or contraction) as a function of temperature,
  time and force applied to the sample.

• A Dynamic Mechanical Analyzer (DMA) measures
  rheological behavior of a sample under dynamic
  conditions (such as modulus, compliance and
  damping) as a function of temperature, time,
  frequency, stress, atmosphere or a combination of
  these parameters.

14
PerkinElmer High Sensitivity Mechanical Analysis
family ...

• Diamond TMA DMA
• Broad force range
• Multiple deformation modes
• Many measuring systems
• Dynamic static operation
• Advanced cooling system

Research
. for fast, accurate, reproducible results
15
PyrisTM Software
. the benchmark application for thermal analysis
16
(No Transcript)