Title: Polar Covalent Bonds; Acids and Bases
1Polar Covalent BondsAcids and Bases
- Bond Moments and Dipole Moments
- Formal Charge
- Resonance
- Bronsted-Lowry Acid/Base
- Lewis Acid/Base
2Pauling Electronegativity Scale
3Electronegativity Trends Ability to Attract the
Electrons in a Covalent Bond
4Electrostatic Potential Map Cholormethane
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6Opposite polarity in CH3Li
7Methanol
8Dipole Moment (m) is sum of the Bond Moments
9Nonpolar CompoundsBond Moments Cancel Out
10NCl3 and BCl3
11Nitromethane
12Nitromethane has 2 Formal Charges
13Bonding Pattens for C, N, and O
14Common Cationic, Neutral and Anionic Forms
15Both Resonance Structures Contribute to the
Actual Structure
16Dipole Moment reflects Both Resonance Structures
17Curved Arrow Formalism Shows flow of electrons
18Resonance Rules
- Cannot break single (sigma) bonds
- Only electrons move, not atoms
- 3 possibilities
- Lone pair of e- to adjacent bond position
- Forms p bond
- - p bond to adjacent atom
- - p bond to adjacent bond position
19Resonance Stabilization of IonsPos. charge is
delocalized
20Two Nonequivalent Resonance Structures in
Formaldehyde
21Resonance in Acetate Anion
22Resonance in CH2NH2
23Definitions of Acids/Bases
24Dissociation in H2OArrhenius Acid forms
H3OBronsted-Lowry Acid donates a H
25Resonance Stabilization
26Measuring Acid StrengthKa
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28Acid Strength defined by pKa
29Stronger Acid Controls Equilibrium
30Reaction Described with Arrows
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32Equilibrium Reactions
33Acids Can React with Water
34The Effect of Resonance on pKa
35Identify the Acid and Base
36Equilibrium Favors Reactants
37Draw the Conjugate Acid and Base
38Propanol is a Base
39Draw the Conjugate Acid and Base
40Propanol is an Acid
41Some Acid-Base Reactions
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43Carboxylic Acids can be Separated from non-acidic
Compounds
44Lewis Acids and Bases
45Lewis Acid and Base Reactions
46Lewis Base NucleophileLewis Acid Electrophile
47Draw the Acid-Base Complexes