Polar Covalent Bonds; Acids and Bases - PowerPoint PPT Presentation

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Polar Covalent Bonds; Acids and Bases

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Polar Covalent Bonds; Acids and Bases Bond Moments and Dipole Moments Formal Charge Resonance Bronsted-Lowry Acid/Base Lewis Acid/Base The Effect of Resonance on pKa ... – PowerPoint PPT presentation

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Tags: acids | bases | bond | bonds | covalent | polar

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Title: Polar Covalent Bonds; Acids and Bases


1
Polar Covalent BondsAcids and Bases
  • Bond Moments and Dipole Moments
  • Formal Charge
  • Resonance
  • Bronsted-Lowry Acid/Base
  • Lewis Acid/Base

2
Pauling Electronegativity Scale
3
Electronegativity Trends Ability to Attract the
Electrons in a Covalent Bond
4
Electrostatic Potential Map Cholormethane
5
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6
Opposite polarity in CH3Li
7
Methanol
8
Dipole Moment (m) is sum of the Bond Moments
9
Nonpolar CompoundsBond Moments Cancel Out
10
NCl3 and BCl3
11
Nitromethane
12
Nitromethane has 2 Formal Charges
13
Bonding Pattens for C, N, and O
14
Common Cationic, Neutral and Anionic Forms
15
Both Resonance Structures Contribute to the
Actual Structure
16
Dipole Moment reflects Both Resonance Structures
17
Curved Arrow Formalism Shows flow of electrons
18
Resonance Rules
  • Cannot break single (sigma) bonds
  • Only electrons move, not atoms
  • 3 possibilities
  • Lone pair of e- to adjacent bond position
  • Forms p bond
  • - p bond to adjacent atom
  • - p bond to adjacent bond position

19
Resonance Stabilization of IonsPos. charge is
delocalized
20
Two Nonequivalent Resonance Structures in
Formaldehyde
21
Resonance in Acetate Anion
22
Resonance in CH2NH2
23
Definitions of Acids/Bases
24
Dissociation in H2OArrhenius Acid forms
H3OBronsted-Lowry Acid donates a H
25
Resonance Stabilization
26
Measuring Acid StrengthKa
27
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28
Acid Strength defined by pKa
29
Stronger Acid Controls Equilibrium
30
Reaction Described with Arrows
31
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32
Equilibrium Reactions
33
Acids Can React with Water
34
The Effect of Resonance on pKa
35
Identify the Acid and Base
36
Equilibrium Favors Reactants
37
Draw the Conjugate Acid and Base
38
Propanol is a Base
39
Draw the Conjugate Acid and Base
40
Propanol is an Acid
41
Some Acid-Base Reactions
42
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43
Carboxylic Acids can be Separated from non-acidic
Compounds
44
Lewis Acids and Bases
45
Lewis Acid and Base Reactions
46
Lewis Base NucleophileLewis Acid Electrophile
47
Draw the Acid-Base Complexes
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