Title: HAZMAT
1HAZMAT Review
Wes Adams
2Hazardous Materials Basics
DOT Regulations
Common Elements
Chemical Reactions
Chemistry
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3Flammable Solids
Gases and Liquids
Oxidizers
Corrosives
Toxic Substances
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4Organics
Polymers
Explosives
Miscellaneous Hazards
Radioactive Materials
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5Hazardous Materials Basics for 1
The most common element in the Earths crust.
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6Hazardous Materials Basics for 1
What is oxygen?
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7Hazardous Materials Basics for 2
In 1986 Congress, as a result of the Bhopal,
India incident, enacted this.
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8Hazardous Materials Basics for 2
What is EPCRA?
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9Hazardous Materials Basics for 3
The red section of an NFPA placard indicates this.
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10Hazardous Materials Basics for 3
What is a flammability hazard?
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11Hazardous Materials Basics for 4
This is performed prior to site entry in order to
aid in the selection of appropriate personal
protective equipment.
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12Hazardous Materials Basics for 4
What is a preliminary evaluation?
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13Hazardous Materials Basics for 5
This is the highest level of hazardous materials
responder and should be aware things like of
route of exposure to hazardous materials, acute
and delayed toxicity, local and systemic effects,
dose response, and synergistic effects in
addition to the requirements of the previous
levels.
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14Hazardous Materials Basics for 5
What is the incident commander?
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15Chemistry for 1
Brass is an alloy of copper and zinc is this.
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16Chemistry for 1
What is a mixture?
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17Chemistry for 2
This is the change between the solid and liquid
states.
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18Chemistry for 2
What is melting?
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19Chemistry for 3
This is the symbol for the element iron.
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20Chemistry for 3
What is Fe?
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21Chemistry for 4
The number of neutrons in an atom of
phosphorus-31.
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22Chemistry for 4
What is 16?
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23Chemistry for 5
The seventh column of the periodic chart
containing the elements fluorine, chlorine,
bromine, iodine, and astatine are referred to as
this.
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24Chemistry for 5
What are halogens?
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25DOT Regulations for 1
Class 4.3 hazardous materials refer to these
materials.
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26DOT Regulations for 1
What is dangerous when wet?
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27DOT Regulations for 2
A liquid or solid that even in small quantities
and without external ignition source can ignite
within five minutes after coming in contact with
air.
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28DOT Regulations for 2
What are pyrophoric materials?
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29DOT Regulations for 3
These pages in the ERG list the materials in
alphabetical order.
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30DOT Regulations for 3
What are the blue pages?
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31DOT Regulations for 4
The placard below indicates this kind of material.
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32DOT Regulations for 4
What are nonflammable gases (class 2.2)?
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33DOT Regulations for 5
The placard below indicates this kind of material.
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34DOT Regulations for 5
What are Miscellaneous Hazardous materials (class
9)?
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35Common Elements for 1
This gaseous element comprises about 21 of the
atmosphere.
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36Common Elements for 1
What is oxygen?
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37Common Elements for 2
This element is the most chemically active
nonmetal and forms compounds with all elements
except the lighter noble gases.
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38Common Elements for 2
What is fluorine?
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39Common Elements for 3
Products made from this element can be used to
sterilize water and as a bleaching agent of paper
pulp and certain textiles.
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40Common Elements for 3
What is chlorine?
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41Common Elements for 4
4/5 of this element used annually is used to make
sulfuric acid.
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42Common Elements for 4
What is sulfur?
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43Common Elements for 5
Coal, diamond, and graphite are allotropes of
this element.
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44Common Elements for 5
What is carbon?
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45Chemical Reactions for 1
This class of fire results when flammable gases
and flammable (organic) liquids burn.
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46Chemical Reactions for 1
What is class B?
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47Chemical Reactions for 2
The type of reaction indicated here 2 H2O2(aq) ?
2 H2O(l) O2(g)
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48Chemical Reactions for 2
What is a decomposition reaction?
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49Chemical Reactions for 3
This factor that affects reaction rates causes
combustion reactions to occur much more quickly
if the oxygen content of the air is elevated.
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50Chemical Reactions for 3
What is reactant concentration?
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51Chemical Reactions for 4
Applying water is the most common way of putting
out a fire. Water is useful mostly because it
takes away this away from the fire.
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52Chemical Reactions for 4
What is heat?
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53Chemical Reactions for 5
A KHCO3 extinguisher is sometimes called this.
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54Chemical Reactions for 5
What is purple K?
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55Gases and Liquids for 1
Since corn oil has a specific gravity of 0.91 it
do this on water.
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56Gases and Liquids for 1
What is float?
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57Gases and Liquids for 2
Since propane has a vapor density of 1.5 it do
this in air.
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58Gases and Liquids for 2
What is sink into low lying areas?
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59Gases and Liquids for 3
This is the minimum temperature at which a
flammable liquid first forms an ignitable mixture
with air.
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60Gases and Liquids for 3
What is the flash point?
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61Gases and Liquids for 4
This is the largest amount of a gas or vapor that
will burn when exposed to an ignition source.
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62Gases and Liquids for 4
What is the Upper Explosive Limit (UEL)?
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63Gases and Liquids for 5
A liquid that has a flash point below 73oF and a
boiling point below 100oF is referred to as a
this of class of flammable liquid.
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64Gases and Liquids for 5
What is class IA?
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65Flammable Solids for 1
This group of elements from the periodic chart
reacts violently with room temperature water.
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66Flammable Solids for 1
What are alkali metals?
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67Flammable Solids for 2
A W with a line drawn through it on the white
section of an NFPA placard cautions against
adding this.
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68Flammable Solids for 2
What is water?
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69Flammable Solids for 3
Sodium Burns with this color of flame.
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70Flammable Solids for 3
What is yellow/orange?
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71Flammable Solids for 4
Most combustible metal fires are this class of
fire.
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72Flammable Solids for 4
What is class D?
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73Flammable Solids for 5
When water is added to calcium carbide it
liberates this gas.
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74Flammable Solids for 5
What is acetylene?
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75Oxidizers for 1
Oxidizers are in this class of hazardous
materials.
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76Oxidizers for 1
What is class 5.1?
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77Oxidizers for 2
The following reaction illustrates this redox
pair partner Mg ? Mg2 2e-
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78Oxidizers for 2
What is an oxidation?
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79Oxidizers for 3
The fluorine in the following reaction is this
F2 2 I-1 ? I2 2 F-1
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80Oxidizers for 3
What is the oxidizing agent (oxidizer)?
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81Oxidizers for 4
The bombing of the Federal Building in Oklahoma
City on April 19, 1995 involved mixing this
oxidizer with diesel fuel.
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82Oxidizers for 4
What is ammonium nitrate?
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83Oxidizers for 5
This often explosively unstable oxidizing organic
material can form in old ether bottles.
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84Oxidizers for 5
What are organic peroxides?
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85Corrosives for 1
A solution with a ph 5.4 is considered this.
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86Corrosives for 1
What is acidic?
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87Corrosives for 2
One hazard of this acid is that it will extract
water from organic materials like sugar for one.
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88Corrosives for 2
What is sulfuric acid?
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89Corrosives for 3
This oxidizing acid causes yellow burns on
contact with exposed skin.
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90Corrosives for 3
What is nitric acid?
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91Corrosives for 4
Grades of this acid above 73 are not offered for
transportation because they are explosively
unstable.
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92Corrosives for 4
What is perchloric acid?
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93Corrosives for 5
The best way to deal with a large spill of a
corrosive material is to do this.
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94Corrosives for 5
What is to neutralize it with an appropriate
material?
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95Toxic Substances for 1
This route of exposure refers to a substance that
penetrates the epidermis into the dermis and the
blood stream.
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96Toxic Substances for 1
What is skin absorption?
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97Toxic Substances for 2
These are toxic substances that cause liver
damage, alcoholic beverages for one.
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98Toxic Substances for 2
What are hepatoxins?
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99Toxic Substances for 3
This is an injury, disease or death caused by
continued or repeated short-term exposures over a
period of a few days, weeks, or longer periods.
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100Toxic Substances for 3
What is chronic effect?
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101Toxic Substances for 4
The dosage of a toxic substance when administered
to laboratory animals kills half of them is
referred to as this.
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102Toxic Substances for 4
What is Lethal Dose 50 kill (LD50)?
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103Toxic Substances for 5
This is the time weighted average TLV of a toxic
substance that workers can be continuously
exposed for eight hours in conformance with OSHA
regulations.
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104Toxic Substances for 5
What is the Permissible Exposure Limit (PEL)?
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105Organics for 1
This type of hydrocarbon has at least one
carbon-carbon triple bond .
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106Organics for 1
What is alkyne?
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107Organics for 2
These three aromatic compounds make up the BTX
family.
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108Organics for 2
What are benzene, toluene, and xylene?
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109Organics for 3
The functional group in this molecule for example.
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110Organics for 3
What is an aldehyde?
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111Organics for 4
This type of organic solvent is typically not
flammable.
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112Organics for 4
What are halogenated hydrocarbons?
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113Organics for 5
Drinking as little as 0.6 pints of this alcohol
can cause death while lesser amounts cause
irreversible blindness.
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114Organics for 5
What is methanol?
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115Polymers for 1
These polymers are materials that if a moderate
amount of deforming force is added will return to
its original shape.
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116Polymers for 1
What are elastomers?
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117Polymers for 2
This type of polymerization has alternating types
of units (A-B-A-B).
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118Polymers for 2
What is a co-polymer?
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119Polymers for 3
This is written next to the guide book number in
the ERG to indicated a material will hazardously
polymerize.
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120Polymers for 3
What is a P?
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121Polymers for 4
This decomposition and formation of flammable
vapor away from the heat source can cause this in
which the fire spreads to another room with out
direct contact from the fire.
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122Polymers for 4
What is flashover?
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123Polymers for 5
This is the most common polymer made in the US.
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124Polymers for 5
What is polyethylene? Used to make milk jugs,
trash bags, plastic wrap etc.
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125Explosives for 1
These shock waves are associated with the
explosives shattering power called this.
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126Explosives for 1
What is the brisance?
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127Explosives for 2
The type of explosion that can occur in a grain
elevator is called this.
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128Explosives for 2
What is a dust explosion?
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129Explosives for 3
All explosive materials are stored in these
buildings by Federal, state, and local
regulations.
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130Explosives for 3
What are magazines?
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131Explosives for 4
According to DOT regulations, the hazard class
that houses explosives there are this many
divisions.
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132Explosives for 4
What is 6?
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133Explosives for 5
The bombers of the USS Cole used this as an
explosive.
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134Explosives for 5
What is C-4?
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135Miscellaneous Hazards for 1
OSHA specifies this Level of PPE as the minimum
protection for workers in danger of exposure to
unknown chemical hazards.
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136Miscellaneous Hazards for 1
What is Level B?
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137Miscellaneous Hazards for 2
The area immediately around the spill is called
this.
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138Miscellaneous Hazards for 2
What is the hot zone (exclusion zone)?
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139Miscellaneous Hazards for 3
The mail attacks that followed the September 11
terrorist attacks involved this biological agent.
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140Miscellaneous Hazards for 3
What is anthrax?
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141Miscellaneous Hazards for 4
This hazardous material is a waste, or reusable
material, that contains an infectious substance
and is generated in the diagnosis, treatment, or
research of humans or animals.
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142Miscellaneous Hazards for 4
What is an regulated medical waste?
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143Miscellaneous Hazards for 5
A Japanese doomsday cult, used this chemical
agent in a terrorist attack on the Tokyo subway
system that killed 12 and sent more than 5,000
people to hospitals.
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144Miscellaneous Hazards for 5
What is Sarin? (used by Aum Shinrikyo)
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145Radioactive Materials for 1
The number of protons does Uranium-238 has.
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146Radioactive Materials for 1
What is 92?
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147Radioactive Materials for 2
This is the time it takes for ½ of a radioactive
material to decay.
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148Radioactive Materials for 2
What is the half life?
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149Radioactive Materials for 3
This type of radiation types causes the most
damage from an external source .
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150Radioactive Materials for 3
What is gamma radiation?
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151Radioactive Materials for 4
Exposure to this radioactive material accounts
for on average 50 the 360 mrem annual exposure
to ionizing radiation.
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152Radioactive Materials for 4
What is radon?
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153Radioactive Materials for 5
This nuclear power plant disaster that occurred
in 1986 which is still known as the worst
peace-time nuclear disaster on record.
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154Radioactive Materials for 5
What is Chernobyl?
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