New Alcohol C12-13

1
New Alcohol C12-13
DERIVATIVES
2
New Alcohol C12-13

• This alcohol is a C12 C13 oxo-alchol derived
  from Alpha-Olefins
• Composition of the New C12-13 is comparable to
  alcohols in the market
• It reacts or derivatizes similar highly linear
  alcohols

3
Alcohols composition
4
Linear alcohol (C12) isomer
Ca. 50
5
Percent Linear Isomers
6
Mono methyl alcohol isomers (C12)
Ca. 30
7
Steric Hindrance Trend for Hydroxyl Groups
TDA gt Conv. Oxo gt Mod. Oxo ? C12-13 Oxo ?
Ziegler Most sterically hindered Least
sterically hindered 67 54
20 5
1 Level of C2 Positional Isomer
Ca. 5
8
Percent C2 Substituted Isomers
9
SODIUM ALKYL ETHER(2EO) SULFATES

• Viscosity profile at 25C (7 a. m.)
• Labelling
• Biodegradability
• Examples of formulations
• Viscosity Response Curves
• Rotary Foam Testing (Hard Water)

10
High Active Ether Sulfates

• INCI NAME Sodium Laureth Sulfate
• Viscosity / Shear Rate lower viscosity, higher
  shear rate than std high active products in our
  range
• Pour point lower than the std high active
  products in our range
• Set point lower than the std products in our
  range
• Better solubility and, as a consequence, higher
  clearness

11
Viscosity profile at 25C (7 a. m.)
12
LABELLING
Irritant

• R36/38 Irritating to eyes and skin Low
  Active
• R38 Irritant to skin,
  High Active
• R41 Risk of serious damage to eyes.
• No differences if compared to the alkyl ether
  sulfates we still have in our range of products

13
BIODEGRADABILITY

• Readily biodegradable (OECD 301)
• No differences if compared to the alkyl ether
  sulfates we still have in our range of products

14
Viscosity in formulations
QCCP (oC) -2 -5 -5 lt -5 lt -5 lt -5
15
FORMULATIONS Viscosity Response Curves
16
FORMULATIONSRotary Foam Testing (Hard Water)
17
EMPILAN KP7

• Solubility data
• Wetting Test
• Washing comparison for laundry products
• Labelling
• Biodegradability

18
Solubility data
Cpt (0.5 in H2O) Cpt (5/45/25 BDG) HLB value
Empilan KP7 49C 78C 12.3
Empilan KBE 7 56C 79C 12.3
Empilan KCL 7 lt 30C 75C 12.0
Empilan KCB 8.5 69C 79C 13.7
Empilan NP 9 55C 78C 12.9
19
Wetting test
1g/l in demineralized water _at_ 25C
Cloudy solution
20
Washing performances

• Conditions
• Concentration 1 g/l - Water Hardness27f -
  Washing time 30 min
• Temperature 40C and 60C

21
LINITEST 40C EMPA 101
Cotton soiled with Carbon Black and Olive Oil
22
LINITEST 40C EMPA 104
Polyester/Cotton (65/35) soiled with Carbon Black
and Olive Oil
23

LINITEST 40C EMPA 112
Cotton soiled with Cocoa
24
LINITEST 40C EMPA 114
Cotton soiled with Red Wine
25
LINITEST 40C EMPA 116
Cotton soiled Blood/Milk/Ink
26
LINITEST 60C EMPA 101
Cotton soiled with Carbon Black and Olive Oil
27
LINITEST 60C EMPA 104
Polyester/Cotton (65/35) soiled with Carbon Black
and Olive Oil
28
LINITEST 60C EMPA 112
Cotton soiled with Cocoa
29
LINITEST 60C EMPA 114
Cotton soiled with Red Wine
30
LINITEST 60C EMPA 116
Cotton soiled Blood/Milk/Ink
31
LABELLING
Harmful
Dangerous for the Environment

• R22 Harmful if swallowed
• R41 Risk of serious damage to eyes
• R50 Very toxic to aquatic organisms
• No differences if compared to the ethoxylated
  alcohols we have in our range of products

32
BIODEGRADABILITY

• Readily biodegradable (OECD 301)
• No differences if compared to the ethoxylated
  alcohols we still have in our range of products