Title: MAGMA MIXING AT KARYMSKY: PETROLOGIC CONSTRAINTS AND MODEL
 1MAGMA MIXING AT KARYMSKY PETROLOGIC CONSTRAINTS 
AND MODEL
Pavel Izbekov1, John Eichelberger1 and Boris 
Ivanov2 
1 Alaska Volcano Observatory, Geophysical 
Institute, UAF, Fairbanks 2 Institute of Volcanic 
Geology and Geochemistry, Petropavlovsk-Kamchatsky
, Russia 
 2Introduction
- Mixing of compositionally distinct magmas is well 
documented by the presence of enclaves and zoning 
of phenocrysts in igneous rocks  - The question is how fast can the compositionally 
distinct magmas mix?  - We present results of a detailed petrologic study 
of andesite and basalt that erupted 
simultaneously at Karymsky volcanic center 
beginning in January 1996.  - Continuous eruption of Karymsky offered an unique 
opportunity to determine compositional variations 
of its magma caused by basaltic recharge. These 
variations indicate that mixing can be 
surprisingly fast and thorough. 
  3Location 
 4Geological background 
- Karymsky volcano and Academy Nauk caldera belong 
to a chain of volcanoes, calderas, and maars, the 
location of which is controlled by a local 
north-trending fault.  - Karymsky is a 5300-yr-old andesitic 
stratovolcano located in the center of a 
7900-yr-old caldera. During the past 500 yr, the 
volcano has been in a state of frequent, but 
intermittent eruptive activity.  - Academy Nauk caldera is centered 9 km south of 
Karymsky on the same fault system. Since its 
caldera-forming event (ca. 40,000 yr B.P.), the 
volcanic activity within the caldera was confined 
to phreatomagmatic eruptions of basalt, which 
have occurred at least twice since 5000 yr B.P. 
  51996 eruption of Karymsky and Academy Nauk 
The most recent episode of volcanic activity at 
Karymsky started on January 2, 1996, after 13 yr 
of dormancy. It began with simultaneous eruption 
of andesite from the central vent of Karymsky 
volcano and basalt from a new vent, which formed 
in the northern part of Academy Nauk caldera.
- The magmas erupted simultaneously. 
 - The erupted magmas had strongly contrasting bulk 
compositions. Academy Nauk vent produced basalt 
(52.2 wt SiO2), while Karymsky summit vent 
erupted andesite (62.4 wt SiO2).  - The eruptive vents are located along the same 
active fault.  - Significant ground deformation occurred between 
eruptive vents. Extension between eruptive vents 
occurred gradually, rather than catastrophically. 
The eruption of basalt coincident with the start 
of the most recent cycle of activity at Karymsky 
is suggestive of eruptive triggering. 
The eruption of basalt coincident with the start 
of the most recent cycle of activity at Karymsky 
is suggestive of eruptive triggering.  
 6Questions to answer
- Was there a mixing of andesite and basalt? 
 - If yes, how can we explain the homogeneity of 
andesite? Was the mixing that fast? 
  7Samples and analytical techniques
- Electron microprobe (major elements) 
 - Cameca SX-50 at University of Alaska Fairbanks 
 - 15 kV acceleration voltage 
 - 10 nA beam current 
 - 5 micron beam (10 microns for glass)
 
- LA-ICP-MS (Ba and Sr) 
 - Micromass Platform ICP- HEX-MS at Michigan State 
University  - Cetac LSX 200 laser ablation system equipped with 
UV laser  - 30 micron beam.
 
Samples of pyroclastics of Karymsky vs. time of 
their eruption. Length of hori-zontal bars 
corresponds to approximate time of lava flows 
effusion. 
 8Petrography
Modal Abundances, vol.  
 9Karymsky Glass composition vs. time 
Compositions of volcanic ash glass plotted 
against the date of eruption. Melt of Karymsky 
andesite, which erupted in February 1996, was the 
most mafic. Error bars correspond to 2s in 
electron microprobe analyses of ash samples. 
 10Karymsky and Academy Nauk plagioclases 
BSE images of Academy Nauk (a) and Karymsky (b) 
plagioclases and their corresponding 
compositional profiles. Note contrasting textures 
and compositions. 
 11Karymsky Calcic cores in plagioclases
- Approximately 25 vol. of plagioclase phenocrysts 
in Karymsky andesite contain calcic cores.  - Composition and texture of cores match those of 
plagioclases in Academy Nauk basalts.  - Widths of sodic rims are consistent with 
introduction of calcic cores at the onset of 
eruption (2.5  109 mm/s plagioclase growth rate) 
  12Karymsky Xenocrysts of olivine 
Photomicrograph (a) and a simplified sketch (b) 
of Karymsky andesite from the lava flow, which 
effusively erupted during April-August 1996. Note 
olivine xenocryst attached to the calcic core of 
plagioclase  both likely introduced to andesite 
by basaltic replenishment in January, 1996. 
Composition of olivines is shown in figure C. 
 13Summary 
- By late February 1996 Karymsky erupted texturally 
homogeneous andesites, no mafic enclaves were 
found.  - Within two months of the onset of eruption, the 
composition of melt of Karymsky andesite, as 
recorded by glass in tephra, shifted toward a 
more mafic composition and then gradually 
returned to its original state and remained 
constant for the following 4 years.  - Andesite contains xenocrysts of basaltic origin, 
i.e calcic plagioclase and olivine, at least part 
of which was most likely introduced by basaltic 
replenishment in January 1996, at the onset of 
the eruptive cycle. 
  14Viscosity constraints on mixing 
The plausibility of mixing can be roughly tested 
using estimates of viscosities for Academy Nauk 
basalt and Karymsky andesite. 
- Isobaric crystallization of basalt was modeled 
using COMAGMAT algorithm (Ariskin)  - Viscosity was calculated using Shaw (1972) model 
 - Volume of injected basalt was assumed negligible 
comparative to the volume of the stored andesite 
and did not affect the temperature of the 
produced hybrid significantly. 
Variations of viscosity vs. temperature for 
Academy Nauk basalt (2 wt.  H2O) and Karymsky 
andesite (1.5 wt. H2O) at 200 MPa total pressure.
Variations of viscosity vs. temperature for 
Academy Nauk basalt (2 wt.  H2O) and Karymsky 
andesite (1.5 wt. H2O) at 200 MPa total pressure. 
 15Comparative model 
 16Conclusion
- Homogeneity of andesite erupted by late February 
1996 suggests to us that thorough mixing of 
injected basalt and andesite occurred in a period 
of time as short as two months.  - Perhaps the rapid and effective blending was 
facilitated by an only modest contrast in 
viscosities and temperatures between the magmas 
and by a vigorous fluid dynamic regime in 
Karymsky reservoir.  - Karymsky is a well-mixed end member case that 
reflects the short recurrence interval of 
recharges to the system. In contrast, Trident 
volcano in Alaska may represent an intermediate 
case, where both clotting and direct mixing 
occurs, and Kizimen volcano in Kamchatka  a 
poorly-mixed end member case, where clotting 
along is dominant.