?????????(ATRP)

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?????????(ATRP)

• Atom Transfer Radical Polymerization

?? ??? ???
2
1.??
ATRP????

• 1995 ??????????????????(Carnegie2Mellon)
  ???????????????????????(A tom Transfer Radical
  Polymerization , ??ATRP) , ????????????????,
  ?????????????????????????????????????????

3
2.????
???ATRP???????????????????????????????????,?60130
oC???????????????????????????105????????????,????
??????????????????????
???????????,??ATRP???,ATRP??????????????
4
ATRP?????
????
,p??
???????????
?
?
5
ATRP????
(?)ATRP???
(1)??ATRP???????????????????,????,???????????????
????ATRP,????????????,?????????
6
ATRP????
(?)ATRP???
(2)???????????Greszta?????????????????,????????AT
RP,?????????????????,???????,???????????,?????????
????????,?????????????????????????????
7
ATRP????

• (?)ATRP???
• (1) ATRP?????????????????,??????????,?????????????
  ???
• (2)??????????(????????),????????
• (3)???????????,??????????????,??????????????????.
  

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?ATRP???
ATRP ??????????

• ??ATRP???????????, ??????????????,
  ????????????????, ?????????, ??????????????,
  ????????????????????. ?????, ????ATRP?????????????
  ??????????.

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?ATRP???
?????
????ATRP , ????? ??????????
?????????????????????????,??????????,???????????
??????????????????????????,???????????????????????
?????????????????????????????
10
ATRP???
???ATRP ??????
? ???????, ???? ? ??????????????????? ?????,
????????
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ATRP???
??ATRP
????????????, ???????????(CuX2) ?2, 2-???
(bpy)????????,???????(ABN)??????,??????ATRP
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ATRP???
??ATRP
??, I-I ???? Mn 1t??????????? Mnt ???????????
I-M,I-Mn????I-M-X,I-Mn-X ????.
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ATRP???
??ATRP
??A TRP ?????I?I-P?Mn 1tX??????. ?????,
?????I/I-M????, ???????????????Mn 1tX??????,
????????????Mnt?I-X/I-M-X,??????????Mnt??????????A
TRP ????.
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???
???
????
???
???
???????????
?????? ????????
???
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??????RATRP????????
????? ??? ??? ???
St AIBN CuCl2,FeCl3, Ni(mph)2 bpy, PPh3
AN AIBN,DCDPS FeCl3 IDA, IMA, IPA
MMA TPED,DCDPS,DCDTS,AIBN FeCl3,CuCl2 PPh3, bpy, IPA , PMA,TREN
BMA AIBN CuCl2 dNbpy
MA AIBN CuCl2 bpy
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