?????????(ATRP)

1
?????????(ATRP)

• Atom Transfer Radical Polymerization

??? ??
2
?ATRP????
1995 ??????????????????(Carnegie2Mellon)
???????????????????????(A tom Transfer Radical
Polymerization , ??ATRP) , ????????????????,
?????????????????????????????????????????
3
??????12??????????, ????????(bpy) ?????????,
?130???????(St) ????????3h ????95????????????????
???????????, ???????????????????????????,
?????????
??RX ?????? BPY ?2 , 2 '2 ????? CuX ?????
4
?ATRP?????
Mn?n????????? M ??? R-X????(?????)Mn t
??????????? Mn 1t ??????????? R-M