(2)

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??? ???
?????
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1???????????????????????? ?,????????????????????


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(1)???(????)??? (2) 2???? (3)1???? (4)(5)(6)
??????
2????????
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3???NaI-???????????
(4 )gt (5) gt (1) gt (2) gt(3) gt(6)
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4???AgNO3-??(SN 1)????????
(2)gt(1)gt(4)gt(3)gt (6) gt(5)
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5.???????????
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6.??????
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a ?????,??????
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7??????????????????
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(No Transcript)
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8??1,3-????1,4-???,?????? ????,????????????
(1)??????????,?H2/Pt ?
??????????????
(2)????????????,?? ??????
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9????????????????????? ?????????,??????2,3-?
?????????
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10????(ClCH2CH2SCH2CH2Cl)??????
??????????????????? ???????????????????
???NaOH???????,?????OH- ????,???Cl-?????????
? ???????????
Cl-
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?????????????,???????????????????????Cl-????????Cl
-?????????????,????????
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11.???????????????SN 1 ??, ??I????II?,????
???????????????????,??C???????????,?????????C,
???SN1????????????????????
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12??( R )-CH3CH2CH2CHID????? NaI???,???
(1)????????? (2)?????????I-??,???????????
?I-??????????????,????
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???????,??????I-?(R)?????????(S)??,
????(S)?????????I-?????(R)??????????,??????????50
?????????
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????????????(I-)????,?????R????????S?????
??S????????????R???????????,??50?????????????????
???????,????????????????????
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13????????SN 1?????????? ?,?ClCH2-O-C2H5??????
???? ????SN 1??,???
??P-P???,O???????????C ??,???????C ?????? SN
1???
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14???????????2-??????? ?????????2-??????6?
1 ?
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15???????????
?????????SN1,??????SN2. ??H2OgtCH3OH.????????SN1
????? ??????,??????SN2???????, ?????????.
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16?2-??2-??2-?-2-?????????? ?????,??????2-???-2-
??? ?,2-??-1-???2-??-2-?????? ??????????
???????????????????,???????????
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17?3-?-1-??????????????? ?????RCl?-OC2H5???3
-?? ?-1-???3-?-1-??????? ?,????3-???-1-??,???
1-???-2-????????????
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18? ???????????KOH?????? ????,???????????,??
?????????????????
???????,???-OH???????,????????????????????????
???????????????,????????????,???????,???????????
??????????,?????,?????????????????
?????-OH? ???????.
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???????, ??????????????????????????,????????????
??.
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19??????????C8H10,???????1mol
???,????????A,A?????1mol ???,??????B?C,???A?B?C?
? ?
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20????M?????C6H11Cl,M????????
???????????M?NaOH?????? ?????????N,M?KI(??)????
?????????M,N??????
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21????????????,???????, ????????????????,??
??
???????????????????????,????????????????????????
????
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????(NO2-)?????????????(???)????
(1)????????????,????????????? ??
(2)a????? ???????,b????
???????