Title: ROHS????
1ROHS????
2Environmental Protective Requirements on waste
electronic electrical products ??????????????
3WEEE RoHS
- They are resourced main on political reason, then
are the environmental target - ???????????,?????????
- They are the new barrier,
- ???????
- WEEE more like the tariff wall, the invisible
wall to increase your cost. - WEEE???????,???????????????
- RoHS more like the TBT the environmental
related certification, similar as the safety
certification but misty. - RoHS??????????,????????????,?????
4WEEE Directive 2002/96/EEC
5Why WEEE Directive ? ?????WEEE
- About 90 of the EEE waste is land-filled
90?????????
Total Collected in W. Europe (1999)- - 764,000
tonnes ???????(1999?) 76.4??
Landfill ??96
Mechanical Recycling ??????? 3
Energy Recovery ????? 1
6Objective ??
- A producer responsibility directive. It aims to
- ???????????????????
- Reduce the waste from electrical and electronic
equipment - ????????????
- Increase recovery and recycling rates of WEEE
- ???????????????????
- Improve environmental performance of all
operators involved in the life cycle of WEEE - ??????????????????????????????????
7Objective ??
Today ??
Resource ??
Product ??
Landfill ?? Burning ?? Throw away freely ????
Future ??
Dispose, Burning, Landfill designedly and
collection organically ??????/?????, ????????
Resource ??
Product ??
Recovery ?? Reuse ??? Recycling ????
8Scope General ??- ??
- Covers discarded EEE ??
- Designed to operate at a maximum voltage of 1,000
V a.c. or 1,500 V d.c ????????? 1000 V a.c
? 1500 V d.c,???????????????????????????????? - Falling within 10 categories of WEEE (Annexes IA
IB) - ???10???
- Includes all components, sub-assemblies and
consumables forming part of the EEE when
discarded94 products. - ?????????????????94?????(????).
- Excludes EEE that is ???
- Part of equipment not covered by the WEEE
Directive - ??WEEE?????????
- Specifically intended for military use.
- ????
9Scope Categories ??-??
- Large household appliances
- ??????
- Small household appliances
- ??????
- 3. IT telecommunications equipment
- IT?????
- Consumer equipment
- ?????
- 5. Lighting equipment
- Except filament light bulbs household
luminaires. - ????( ?????????????)
- Electrical electronic tools
- Except large stationary
- industrial tools.
- ??????(????????????)
- Toys, leisure sports equipment??????????
- Medical devices
- Except implanted infected products.
- ????(??????????)
- Monitoring control instruments????
- Automatic dispensers.?????
10Producers responsibility ?????
- WEEE from private households ???????WEEE
- - Producers install systems for take back
free of cost for final user - ??????????????????
- - Individual or collective possible
- ??????,???????
- - Producers take over cost of reuse,
recycling, disposal - ?????????????????
- - Distributors voluntarily(but free of cost)
may take back WEEE - ???????WEEE(??????)
- WEEE from other than private users ????????WEEE
- - Producers responsible for collection,
reuse, recycling, disposal and costs - ??????????????????????
- - Producers responsible for management cost
of historical waste - ????????????????
- - Member states as well as users and
producers may agree on different financing - ???,?????????????????????????
-
11Product Design ????
- Product designs shall ???????
- Allow selective removal of certain
materials/components. - ???????????????????
- Permit repair and end-of-life dismantling for the
recovery (reuse recycling) of
materials/components. - ???????????????????????(?????????)
- Not include design features which hinder reuse,
unless required for overriding reasons such as
safety or environmental protection. - ?????????????,??????????????
12Rate for Collection, Recovery, Recycling
??,?????????
Separate collection ? 4 kg per inhabitant and
year from households
Automatic dispensers Large household appliances
- Recovery 80 - Recycling, reuse 75
IT telecommunications appliances Consumer
equipment - Recovery 75 - Recycling, reuse
65
Small household appliances Lighting
equipment Electrical and electronic tools Toys,
leisure sports equipment Monitoring and
control instruments - Recovery 70 - Recycling,
reuse 50
Medical device To be determined by 31 December
2006
13Recovery Recycling Targets ???????????
- Example ??
-
- Refrigerator Weight ???? 100 kg
(Category 1)Recovery Target ???? 80Reuse
/ Recycling Target ???/?????? 75Conclusion
?? Disposal as Landfill ????
max. 20 kgRecovery as
incineration ??
max. 5 kgBack into resource stream ????
minimum 75 kg
14Treatment - Selective Removal ??-?????
The following materials, substances, components
must be removed from the product by the treatment
facilities(the information should be provided by
manufactories) ???????????????????????????????????
(????????????????????)
- All liquids????
- Capacitors containing PCBs PCTs??PCBs
PCTs??? - Mercury-containing components ????
- Batteries ??
- Printed circuit boards from mobile phones ??????
- Printed circuit boards from other devices with a
surface area - ?????????10 ?????????
- Toner cartridges etc ????
- Plastics containing brominated flame
retardants????????? - Refractory ceramic fibre-containing components
- ????????
15Treatment - Selective Removal ??-?????
- Cathode ray tubes ?????
- External electric cables ????
- Radioactive substances
- ?????
- CFCs, HCFCs, HFCs HCs
- ???????
- Liquid crystal displays (LCDs) with a surface
area gt 100 cm² - ?????100 ??????????
- LCDs back-lit by gas discharge
- lamps
- ????-?????
- Electrolyte capacitors which contain relevant
substance and depth25mm/diameter25/as the
similar volumn proportion - ???????????(??25 ??,??25 ???????????)
- Gas discharge lamps
- ?????
- Asbestos waste.
- ????
16Treatment Process ??-??
- Only permitted at licensed or registered sites.
- ????????????????????
- Storage sites must prevent environmental
contamination. - ????????????
- Treatment sites shall ??????
- - Use the best available techniques.
- ?????????
- -Prevent environmental contamination.
- ???????
- -Include appropriate storage facilities.
- ????????
- -Treat water before discharge.
- ?????????
- -Have balances to monitor incoming WEEE, outgoing
recovered materials waste. - ??WEEE???????????????
- Minimum quality standards for treatment may be
set up. - ??????????????
17Recovery Recycling Targets ???????????
Word Definition ????
Word ?? Word ?? Word ?? Explain ??
Prevention ?? Prevention ?? Prevention ?? Reduced the hazardous substance content ??????????
Treatment ??,????? ??????????????? Recovery ?? Reuse ??? Fulfill the requirement of the desiring designing use ???????????
Treatment ??,????? ??????????????? Recovery ?? Recycle ???? Re-produce or re-process ????????????
Treatment ??,????? ??????????????? Recovery ?? Energy recovery ???? Recover the heat energy or the other energy ?????????
Treatment ??,????? ??????????????? Disposal ?? Disposal ?? Just cremate or bury only ???????
18 Recovery Recycling ???????? Waste Stream
during Recycling example ???????????
Component suppliers ?????
Component suppliers ?????
Manufactory ?????
Raw material producers ??????
Raw material producers ??????
Dismantler ????
Re-use ???
Components ??
Recycling ????
WEEE
Steel ?
Siderurgy ??
Shredder ???
SR ???
Non-ferr metal ????
Foundry ???
Energy recovery ????
Landfill ??
19Cost Estimations ????
- Collection costs 200-400 Euro per ton
- ???? ??200-400??
- - 4kg pp, 350M inhabitants 300-600M Euro
per year - 4??????,3.5?????3?-6???
- Treatment costs 300-800 Euro per ton
- ??????300-800??
- - 450-1200M Euro per year
- ??4.5?-12???
- Original average price increase of 0.5 to 2 per
electric/electronic device - ?????????????????0.5?2.
- To be detailed per product category
- ?????????
20Marking - All WEEE 1 ??- ??WEEE 1
- Information for Users ?????????
- The products placed on the market after 13
August 2005 must be labeled with
2005?8?13??????????????? - Marking the product according to prEN
50419, Marking must include ? prEN 50419
??,????????? - - A unique identification of producer (e.g
brand name, trade mark or others
means)?????????? (????,?????????) - - Date or year of manufacture/placed on the
market in coded or un-coded text???????/?????????
????
21Marking - All WEEE 1 ??- ??WEEE 1
- - Marking as above with the crossed-outwheeled
bin and additional bar Crossed wheelie bin
symbol. - ??????????????????????????????????
- In exceptional cases, where the products
size and function prevent this, the symbol shall
be placed on - ????????????????????,???
- Packaging ??
- Instructions for use ???
- Warranty.???
22Information Supplied - All WEEE ????- ??WEEE
- Information for Treatment Facilities ????????
- - Information about reuse and treatment of EEE,
of components and hazardous substances used
inside the product and their location inside the
product and disassembly information. - ????????????????????????????,?????????????????
????????? - - Plastic parts, which is gt25g or gt200mm2 must
be marked according ISO 1043 - ???????25??????200???????????? ISO 1043
??????? -
-
23Information Supplied - All WEEE ????- ??WEEE
- This information must be made available to all
interested parties especially to reuse centers,
treatment and recycling facilities in the form
of manuals, by electronic means or on-line on
Internet. The information must be available
within one year after placing the product on the
market. ?????????,?????????????????,?????????
??????????????????????????????????????????????????
????????????????
24Information Supplied - Household WEEE????- ??WEEE
- Details to be supplied to consumers??????????
- Not to dispose of WEEE as unsorted municipal
waste, but collect it separately
???WEEE???????????,??????? - Available return and collection systems???????
- The role of consumers in the reuse, recycling and
other forms of recovery?????????????????????????
- The potential effects on the environment human
health of hazardous substances in the
WEEE.WEEE?????????????????? - Meaning of the crossed wheelie bin symbol.
- ?????????????
- May be required in the instructions and/or at
point of sale. - ???????/???????
25RoHS Directive 2002/95/EEC
26Reason and Objective ?????
- WHY? ????
- Increased risk that lead disposed at landfills
contaminates drinking water supplies?????????????
????????? - 22 of the annual world consumption of mercury is
used in electronic and electrical equipment
?????????,? 22??????????? - Brominated flame retardants emit furan and dioxin
during heating - ????????????????????????
- Objective ??
- Restriction of of the use of hazardous substances
in electrical and electronic equipment????????????
???? - and contribute to the protection of human health
and recovery and disposal of waste of electrical
and electronic equipment - ??????????,?????????????????
27Scope ?? 1
- Similar to the WEEE Directive, except
- ?WEEE????,??
- Applies to new EEE placed on the market after 1
July 2006. - ???2006?7?1???????????
- Includes household filament light bulbs
luminaries. - ?????????????
- Should not disobey the special regulation or
directive to safety and healthy - ????????????????????????
- - Vehicle ELV (2000/53/EEC)
- ????
- - Battery directive, 91/157/EEC, 93/86/EEC
98/101/EC - ????
28Scope ?? 2
- Large Household Appliances ??????
- Small Household Appliances ??????
- IT and Telecommunications Equipment
- ???????
- 4. Consumer Equipment ???
- 5. Lighting Equipment ????
- Electrical and Electronic Tools
- ???????
- 7. Toys, Leisure and Sports Equipment
- ??, ???????????
- 8 Medical Devices (not implanted and infected
devices) (after 2008) - ???? (????????????) (2008??)
- 9 Monitoring and Control Instruments (after
2008) - ??????? (2008??)
- 10.Automatic Dispenser?????
- Excludes ???
- - Medical devices or monitoring control
equipment (WEEE categories 8 9) - ?????????-WEEE???8,9?
- - Spare parts for the repair of EEE placed on
the market before 1 July 2006 - ?2006?7?1????????????
- - Re-used EEE originally placed on the market
before 1 July 2006. - 2006?7?1??????????????
29Requirements Outline ??- ??
- Restricted hazardous substances
- ???????
- Heavy metals ???
- Lead ?
- Mercury ?
- Cadmium ?
- Chromium (VI) ???.
- Certain brominated flame retardants
- ???????
- Polybrominated biphenyls (PBBs)
- ????
- Polybrominated diphenyl ethers (PBDEs).
- ?????
30Requirements Outline ??- ??
Proposal by TAC (Technical Adaptation Committee)
TAC ???(???????) A maximum concentration value
up to 0.1 by weight in specific materials of
electrical and electronic equipment for lead 1)
, mercury, hexavalent chromium, polybrominated
biphenyls (PBB) and polybrominated diphenyl
ethers (PBDE), and up to 0.01 by weight in
specific materials for cadmium, shall be
tolerated. ???????????????,????1),?,???,????
(PBB) ?????? (PBDE) ??????????0.1,??????????????0
.01? 1) For solder alloys used to attach
electrical components to printed circuit boards,
a maximum concentration of lead of 0.1 by weight
of solder alloy shall be tolerated. For
electrical components attached to the printed
circuit board, a maximum concentration of lead of
0.1 by weight of the component shall be
tolerated. ??????????????????,????????????,????
??????????????????,??????????,???????? 0.1?
31Requirements Outline ??- ??
- Definition of Material (under discussion)
- ????? (???)
- Metals, (e.g. solder alloys, electroplated
coatings, copper alloys, steel alloys, aluminum
alloys), plastics and plastic blends (e.g. ABS,
polyamide, PBT), ceramics, glass etc. in this
case the limits apply to mass of the single
material - ??, (??????, ???, ???, ???, ???), ???????
(?? ABS, ???, PBT), ??, ??????????,????????????? - Components (e.g. capacitors, switch,
semiconductors, PCB, relays etc.) in this case
the limits would apply to the mass of the whole
component - ??? (?????, ??, ???, PCB,
????)???????,???????????? - Assemblies
- ???
32Lead - Current Use ?- ????
- Solder ??
- Glass ??
- Lead halides and lead phosphors in certain gas
discharge lamps. - ???????? ???????????
- Electronic ceramic parts.
- ??????
- Amiable-Cutting metal and alloy.
- ????????????
- Metallic coatings brightener stabiliser.
- ?????- ???????
- Thermal stabiliser for plastics/rubber
- ??/???????
- Ink/pigment/paint for printing/painting
- ??/??/??
- Batteries ??
- Resin additives ?????
- Optical components ????
- Contacts ??
- Power cords and wires ?????
33Lead - Permitted Uses (RoHS Exemptions)?-
????(??)
- Glass in ??
- Cathode ray tubes ?????
- Electronic components ????
- Fluorescent tubes ???.
- Alloying elements in ??
- Steel (maximum 0.35 lead) ? (??0.35??)
- Aluminium (maximum 0.4 lead) ? (?? 0.4 ??)
- Copper (maximum 4 lead) ? (??4??).
- Solders ??
- Lead in high melting temperature type solders
(i.e. tin-lead solder alloys containing more
than 85 lead lead based alloys containing 85
by weight or more lead.) - ????????(?????????????85, ????????85???)
- Servers, storage storage arrays (until 2010)
- ???,??? ,?????(?2010)
- Network infrastructure telecom management.
- ???????????
- Electronic ceramic parts,e.g. piezoelectronic
devices.
Lead in solders for servers.storage and storage
array systems, Network infrastructure equipment
for switching, signaling, transmission as well
as net work management for telecommunications
34Lead - Permitted Uses (RoHS Exemptions)?-
????(??)
- Summary ??
- Clarification ???
- lead used in compliant pin connector systems
- ???????????????
- lead as a coating material for the thermal
conduction module o-ring - ???????C??????????
- lead and cadmium in optical and filter glass
- ???????????????
- lead in solders consisting of more than two
elements for the connection between the pins and
the package of microprocessors with a lead
content of more than 80 and less than 85 by
weight - ???????????????????????????????,??????80,??85
? ??? - lead in solders to complete a viable electrical
connection between semiconductor die and carrier
within integrated circuit Flip Chip packages - ????????????????????die???????????????
35RoHS DirectiveMercury - Current Use ?- ????
- Fluorescent lamps, High intensity discharge (HID)
lamps, - ????, ?????(HID) ??,
- Painting or pigment or ink ?????
- LCD back light ????
- Tilt switches/adjuster ?????/???
- Reed-relays ??????
- Contact point materials(e.g relays)
????(????) - Anti-corrosion treatment ?????
- Thermostats ???
- Batteries ??
- etc ?.
36RoHS DirectiveMercury - Permitted Uses (RoHS
Exemptions)?- ???? (??)
- Compact fluorescent lamps (maximum 5 mg per
lamp)?????(????????5??) - Straight fluorescent lamps for general purposes
??????? - Halophosphate (maximum 10 mg per
lamp)????????10?? - Triphosphate with normal life (maximum 5 mg per
lamp)????????(????????5??) - Triphosphate with long life (maximum 8
mg)????????(?????8??) - Straight fluorescent lamps for special
purposes???????? - Other lamps not specifically mentioned.????
37RoHS DirectiveCadmium - Current Use ?- ????
- Cadmium plating. ???
- Solar cells other light-sensitive devices, e.g
CdTe - ???????????
- Electrical contact alloys, e.g relay, switch,
thermostat - ?????, ????,??,???
- Pigments, yellow red - orange pigments ??
- Connection point ??
- Solder ?????
- Thermal stabiliser for plastics
- ???????
- Optical parts ????
- Batteries, e.g Cd-Ni battery
- ??,?????
- Springs ??
- Power cords ???
- Wires ??
38RoHS DirectiveCadmium - Permitted Uses (RoHS
Exemptions)?- ???? (??)
- Cadmium plating, except for applications banned
under the Cadmium Directive 91/338/EEC. e.g.
production equipment or machinery and the
associated products in certain industries. - ???,??91/338/EEC???????????????????????????????
- Cadmium and its compounds in electrical contacts
and cadmium plating except for applications
banned under Directive 91/338/EEC amending
directive 76/769/EEC relating to restrictions on
the marketing and use of certain dangerous
substances and preparations. Clarification of the - cadmium plating exemption.
- ?????????????????????????????
- lead and cadmium in optical and filter glass
- ??????????
-
39RoHS DirectiveChromium (VI) - Current Use
???-????
- Metallic coatings,eg. Zinc electrical plating
surface Anti-Corrosion layer - ????????,????????????(??? )?
- Metal plated plastics.
- ???????
- Coatings, paints, inks for printer
- ????????????
Dichromate anti-corrosion surface ????????????? (0
.2-2µm)
Zinc electrical plating surface ???(0.5-10µm)
Metal base ????
40RoHS DirectiveChromium (VI) - Current Use
???-????
Anti-corrosion agent for the carbon steel
system cooling system in absorption
refrigerators. And phase out with exemption.
???????,?????????????????????
41RoHS DirectivePBBs PBDEs - Current
Use??????????- ????
There are series of compounds concerned.
???????????? They are used as Flame retardants
used for Housings Printed circuit boards
Cables, rated V-0/V-1 according to
UL94. ??????????????????,?????,??????,??UL94,
V-0/V-1???
42RoHS DirectivePBBs PBDEs - Current
Use??????????- ????
- PBBs mainly used for ABS plastic(arylonitrile-b
utadiene-styrene) - ????ABS??
- US stop used in 1976, EU stop
used in 2001 - ???1976???,??2001???
- PBDEs used in plastics, PCB boards and cables.
- ????,????????
- And Penta/Octa/Deca-BDEs always
are available. - ?/?/??????????
- - Penta-BDEs mainly used for phenolic
resins/PVC/rubber/PU, - ?????????????/PVC??/??/???
- - Octa-BDEs mainly used for ABS/PA/PBT,
- ?????????ABS/???/???
- - Deca-BDEs mainly used for PA, PBT, PET,
PVC, PU, rubber, - ????????????/???/??/PVC/???/??
43RoHS DirectivePBBs PBDEs - Permitted Uses
(RoHS Exemptions)??????????- ????(??)
There are currently no exemptions for these
brominates flame retardants except Deca-BDE. And
Deca-BDE is under consideration by European
Commission. ????????????,?????????????? Penta-/Oc
ta-BDEs have already banned by EU
directive-2003/11/EEC. ??????????????????-2003/11/
EEC????
44RoHS Directive Exemption Ongoing evaluation
?????????
- With reference to Article 7(2), the Commission
shall evaluate the applications for - ????? 7(2)???????,???????????????
- - deca-BDE
- The lead in lead-bronze bearing shells and
bushes - The lead crystal in the glass of chandeliers
- The use of non-RoHS compliant parts from old
electrical and electronic equipment in the
manufacture of new equipment.
45RoHS Directive Exemption amendment for RoHS
Directive (VII) ?????
- Lead used in compliant-pin VHDM (Very High
Density Medium) connector system - ???(??????)???????
- Lead as a coating material for a thermal
conduction module c-ring - ?????o?????????
- Lead and cadmium in optical and filter glass
- ????????????
- Lead in optical transceivers for industrial
applications - ?????????????
- Lead in solders consisting of more than two
elements for the connection between the - pins and the package of microprocessors with
a lead content of more than 85 in - proportion to the tin-lead content (exemption
until 2010) - ????????????????????????????,??????85??
- ?????.
- Lead in high melting temperature type solders
(i.e. tin-lead solder alloys containing - more than 85 lead) and any lower melting
temperature solder required to be used - with high melting temperature solder to
complete a viable electrical connection - ????????(????????????85),????????????????
?????????????.
46RoHS Directive Exemption amendment for RoHS
Directive (VIII) ?????
- Lead in solders to complete a viable
electrical connection internal to certain - Integrated Circuit Packages (Flip Chips)
(exemption until 2010) - ???????????????(????????)?????????.
- Article 4(1) substances in safety equipment
for fire and rescue services. - ?4(1)??????????(???????)?.
- Lead in lead-bronze bearing-shells and bushes
- ??-????????????
47Implementation Timetable on WEEE RoHS WEEE/RoHS
?????
WEEE and RoHS publish in official EU-Journal
National implementation
Collection quote 4kg/inhabitant from household,
recycling and recovery quotes
Feb.13, 2003
Aug.13, 2004(?)
Dec.31, 2006
2003
2004
2005
2006
2007
2008
Aug.13, 2005
Jul.1, 2006
Dec.31, 2008
Take back system on the market
Material bans
Amendment of quota for recycling, recovery,
reuse
Deadlines Extended for new EU-Member
48Implementation present situation of EU countries
on WEEE RoHS ????WEEE/RoHS ?????
- There are 3 types
- ?????
- A type actively to push, sternly execute the
directive, and they always have the good
condition and basic on waste treatment system. - A?????,????, ???????????????
- -B type just follow, they have the waste
treatment system - B????,????????????
- -C type antipathy,
- C???
49Recommendation ??
50How to approach WEEE? ???????WEEE
Design ?? Bring the environmental concept into
the design scheme, actively and initiatively
research and develop the new material/new
technology/new ideas
??????????,?????????????????????? a)the dosage
of the raw material as less as better, the
number of assistant materials as less as
better, the output rate as higher as better. The
input material had better to be recovery and easy
to collect. ??????????????????????
??????????????????? b)performance/quality/securi
ty/reliability of the product should be design to
better or perfect, and prolong the durability.
????????????????????,???????? c)easy-disassemb
ly design try to design the product as blocking,
easy for dismantling/assemble/collection, in
order to reduce the dismantling fee, and can also
prolong the complete product lifeonly remove and
exchange one part. ????,?????????????????,?
?????????,???????????????????????-?????????.
51How to approach WEEE? ???????WEEE
d)the performance of the products can show more
benefit to environment, and energy exhaust should
be as lower as better. ????????????,
?????? e)reduce the manufacture cost include
cost used for environmental protection.
????????????????? f) Reuse and recycle design
concept, and lead to more parts with reused or
recycling function. ????,??????????????? Bu
t, Generally speaking it will not solve the WEEE
problem(some people think so, but it is not
true. ?????????????? Design for recycling is
useful when combined with other item
?????????????????? Lower disassembly
timelower assembly time Less materials
diversitygood for lower bill of material
52How to approach WEEE? ???????WEEE
- Join the Eropean Indstry Association EICTA
- ????????EICTA
- Join consortium of companies dealing with WEEE
implementation - ?????WEEE????????
- Collective implementation of individual producer
responsibility is allowed - ???????????????
- dont try to do by yourself ????????
- -No competitive advantage, but also no
competitive disadvantage - ???????,??????????
53How to approach WEEE? ???????WEEE
- Material declaration
- ????
- -Prepare the material list, and the materials
detail location - ??????,????????
- -Provide the each material weight, these
materials can be reused or recycled, - ???????????,???????????????
- Then, It can reduce the treatment cost, because
the waste treatment manufactories can sale the
useful materials, such as gold or copper to earn
the money by using the material declaration. - ??,??????????,???????????????????????,?????,???
??????????????? - mark or provide the plastic information, then the
plastic can be reused or recycled again.
????????????????????
54How to approach WEEE? ???????WEEE
55How to approach WEEE? ???????WEEE
- Complies with EU Directive, 2002/96/EEC(WEEE)
for - ??WEEE?????
- Marking
- ??
- Product Design Article
- ??????
- ? Information for treatment Facilities Article
- ??????
- Additional Information for recycling facilities
about substances and materials impacting the
recycling process in particular the metal
smelting process included in parts and components
others than Printed Circuit Boards - ???????????????????????
- Report template ???? WEEE_Report_Version_1.doc
56How to approach RoHS? ???????RoHS
1. Build the environmental quality ensure
management system ????????????? 2.
Assuring the products not contain the banned
substances of the environmental QMs
????????????????
57How to approach RoHS? ???????RoHS
- know the hazardous substances content
information in raw materials and request
suppliers provide the relevant information.
Entirely survey to the composition of all the
materials. Set up the system and criterion on
factory auditing to all the suppliers.
Supervising the suppliers on real time. Provide
the necessary support and help to rectify and
improve the products for the suppliers. Provide
the essential information to suppliers. - ???????????????????????????,??????????????????
???????????????????,????????,??????????? - - Test report set up the documentation system
for the test reports of own products, the test
report from suppliers. - ????????????????????????????????
- - Confirm and establish the control point on
the producing process, real time inspection - ??,????????????,????
-
58How to approach RoHS? ???????RoHS
Manufacturer conduct Supplier Survey ?????????????
Suppliers ???
Manufacturer ???
Material Supplier ?????
Material, Component and Parts Declaration
???, ??? ?? ??
Establish Component and Material Database ??
??????? ???
Component Supplier ?????
Other parts Supplier ???????
59How to approach RoHS? ???????RoHS
- Supplier Survey ?????
- Survey for every supplier must cover
- ??????????????
- - Manufacturing process
- ????
- - Packaging material content (if any)
- ?????? (????)
- - Product / Component / Part content
- ?? / ?? / ????
- - Batteries content (if any)
- ???? (????)
60How to approach RoHS? ???????RoHS
Design and manufacture ????? - Design
a)control the hazardous substance, understand
the quality and possible harmful of every raw
material. Set up the documentation system, and
stop the use of the materials containing the
banned substances. And confirm the materials has
much less toxicity
???????,??????????????????,?????????,????????????
?????????? b)control the contamination
during manufacture design the manufacture
process and work flow in pertinence, in order to
prevent generating hazardous substances in every
working procedure or have the corrective action
plan. ???????????????????????,??????
??????????????,?????????????????
61How to approach RoHS? ???????RoHS
- Manufacture ?? a) Control the
contamination use testing for
supervision ????????,????,??????????,??????,?????
???,???????????????,???????? b)
Depollution ????Control beforehand, control the
design. ????,????????????,????????????????????????
?????????????????????????????????,???????????????,
?????,???????????,?????????????,?????
62How to approach RoHS? ???????RoHS
- If find banned substances ?????????
- dont fear ????
- find if it is exempted ??????????
- if it is no exempted, then find if other
companies also content all use, or if it is under
considering to be exempted by EU - ???????,???????????,???????????????
- if no way to change, and no exemption, no plan
to be exempted, no other companies use, then ask
help from the some EU association or European
famous experts, provide a letter to government of
related EU country, to explain and confirm the
improvement plan to ask the excuse. - ?????,???,?????,??????,??????????????????????,??
????????????????,??????????????
63Replacement-Example ????-??
- Lead free solder ????
- At present most of solders is the tin-lead alloy
as63 tin / 37lead (187 C) ???????????(63?,37
?)(187 C) - Main replacement SnAgCu (Ag 3.3-4.3, Cu
0.4-1.1) - ???????????? (?3.3-4.3, ? 0.4 1.1)
- LF218TM 96.5 Sn /3.0 Ag /0.5Cu (217-218)
recommended by JEIDA patented.(?JEIDA????) - 96 Sn / 3.5 Ag / 0.5 Cu (217-218) no
patented(????) - CASTIN 96.2 Sn / 2.5 Ag / 0.8 Cu / 0.5 Sb
(217) patented(????) - melting point in C
- ??? C
64Replacement-Example ????-??
Lead free soldering cost comparison ??????????
Alloy Cost Per Kg (US Dollar)
63Sn / 37Pb 6.36
96.5 Sn /3.0 Ag /0.5Cu 9.33
96 Sn / 3.5 Ag / 0.5 Cu 10.44
96.2 Sn / 2.5 Ag / 0.8 Cu / 0.5 Sb 8.59
65Replacement-Example ????-??
- Japan companies leading in lead free soldering
???????????
66Replacement-Example ????-??
- Cadmium free Contact point ?????
- At present, the materials for contact point
are ?????? - AgCdO or AgCdSe or AgCdO Cu
- And the main replacement is ??????
- AgSnO or AgZnO
67Replacement-Example ????-??
- Alternative brominated flame retardants (BFR)
- ??????????
- - Oligomeric brominated flame retardants
- ???????- Tetrabromobisphenol A
(TBBPA) mainly used for PCB board - ????? A (TBBPA), ?????????-
Ethylene 1,2 bis(tetrabromophthalimide) (EBTBP) - ??1,2 ?(?????????) (EBTBP)- Ethane
1,2 bis(pentabromophenyl) (EBP) - ??1,2 ?(????) (EBP)
68Replacement-Example ????-??
4. Replacement of Mercury ????? tilt
switches, reed-relays, thermostats. contact point
material (e.g. relays) - replacement
available????,?????,??????? (????????) - ??????
69Replacement-Example ????-??
4. Replacement of Cr(6) ??????? DACROMET
technology ,invented by US, but Japanese buy the
patent. This material has a good anti-corrosion
performance, and no Cr(6) ?????,????,????????????
????,?????
70Test method ????
71Heavy metal test method ???????
Test method ???? Destroying method ????? Non-destroying method ??????
Test method ???? BS EN 1122,EPA 3050,EPA 3051,EPA 3052,EPA3060,etc. Non-destroying method ??????
Instrument ?? AAS- FAAS, GAAS, Hydride-AAS AFS ICP-AES ICP-MS UV-Vis XRF EDX
Excellence ?? Good recovery ???????? Exact quantitative method ???? Standard support method ?????? Can detect most of metal elements ??????????? Rapid and simple method ??????? Reserve sample integrality ??????? No sample preparation procedure, so no pollution ????????,??????????,????????????? Has the certain high detection sensitivity for Lead and Cadmium ?????????????
Disadvantage ?? Take long time and need more HR ?????,??? Bad pollution, and create waste water and gas ???,??????????? Dangerous method ????????? Investment more ????? High requirement to staff ?????? Cannot detect most of metal elements, just Lead/Cadmium at present ?????????????,??,???/?. It is not the quantitative method, just the semi-quantitative method ?????????,??????? Heavy interference ??????. It is not the international standard supported method ????????
72Heavy metal Detection instruments ???????
Graphite Furnace AAS ??????????
Flame Furnace AAS ?????????
EDX ?????X????????
ICP-MS ??????????
ICP-AES ????????????
UV-Vis spectrum meter ?????????
AFS(Hydride generator) ???????(????????????)
73EDX method ?????X?????????????
- Quantitative and qualitative applying ???????
- - strictly speaking, EDX is a
semi-quantitative method, or the qualitative
method, normally can tell the user contain or
not. - ????,EDX????????????,??????????????.
- - As the technical development, EDX use
standard reference calibration curve, and can
quantitatively and truly detect the some
elements(such as lead/cadmium, etc) in some base
material(PVC, the same material as the reference
std. sample). For Cr(6) and Bromine flame
retardant, should use other methods such as GC-MS
or HPLC or LC-MS for the confirmation, since the
EDX can only detect Total Cr and Total Bromine. - ???????,EDX???????????????(??/?)?????(PVC
, ?????????PVC?????????)??????????.
????????,????????????,??EDX???????????. - Actual usage ????
- - Filtering the raw materials ?????.
- - A lot of manufactories begin to use this
method. ?????????. - i.e. Cadmium ???? lt20ppm accepted(??)
- 20-50ppm Confirmed
by ICP(?ICP?????) - gt50ppm Unaccepted
(???)