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PVC : the long term building material

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The level of gelation was between 38% and 80% (the pipes from the 1970's showed ... Gelation : seems to be correlated with craze initiation ... – PowerPoint PPT presentation

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Title: PVC : the long term building material


1
PVC the long term building material
  • Joël Fumire
  • Research Technology SBU Vinyls

São Paulo, 2005
2
PVC in building
  • PVC is one of the most used plastics in building
  • Why ?

3
PVC in building
  • Building means
  • Strength , see the rigidity modulus !
  • weather resistance in all climates
  • well adapted to specific use (e.g. pipes)
  • Durability from 30 to gt 100 years
  • competitive cost !
  • recyclable

4
Comparison E Modulus
5
Rigidity in Sewage
  • Key property annular stiffness.
  • Directly related to the E-modulus of the material
    Stiffness SN K. E. I / D3

6
Good Weathering resistance
  • UV-resistance
  • PVC can be formulated easily to be used on a long
    term basis in very sunny climates

7
PVC adapted for use drinking water pipes
  • Key properties
  • Pressure resistance
  • No modification of the water quality
  • Long term durability

8
PVC adapted for drinking water pipes
Key property long term pressure resistance
PVC-U
PE100
50 y.
9
PVC adapted for drinking water pipes
  • No modification of water quality
  • No significant leaching of substances to the
    water
  • No taste or smell transferred to water
  • PVC pipes comply with the requests of drinking
    water contact in the most severe regulations
    (CEE, NSF, BGVV, etc)
  • Excellent resistance to bacteria growth
  • PVC is approved for drinking water transportation
    in the majority of countries

10
Other key properties for PVC pipes
  • Chemical inertia towards many chemicals
  • Cleaning liquids, acids,
  • No sensitivity towards oxidising substances
  • Good Fire resistance
  • Among plastics, PVC is one of the most difficult
    to ignite.
  • It is self-extinguishing

11
Durability
  • PVC pressure pipes are in use since more than 60
    years
  • PVC pressure pipes are designed theoretically for
    50 years but can last more than 100 years
  • PVC Window profiles are used since more than 40
    years and are still performing well

12
Pressure pipes 60 years old Dr Nowack study
  • Study realised in Germany published in KRV
    (1995) by Dr. Nowack
  • PVC pipes were produced and installed in
    Bitterfeld in 1935-1940 with the technology
    available at that moment (physical, chemical)
  • Pipes from 1938 extracted from Bitterfeld

13
Pressure pipes 60 years old Dr Nowack study
  • Tests on these pipes show that
  • Burst-pressure curve is still linear with no
    "knee"
  • Burst-pressure at 60C is found still gt 5 N/mm²
    after 600 h
  • Some of the pipes are still operating today at
    20C under 5.0 bar with satisfactory performance

14
TNO study on residual lifetime of PVC pipes
  • Are 50 years old pipes to be replaced ?
  • Study was realised between 2002 and 2005 by the
    Dutch institute TNO Science and Industry (A.
    Boersma J. Breen)
  • Water pipes from the 1950's until today were
    excavated and extensively tested

15
TNO study on residual lifetime of PVC pipes
  • Physico-chemical analysis
  • The K values were close to 66 (1 exception at
    72)
  • The level of gelation was between 38 and 80
    (the pipes from the 1970's showed the lowest
    gelation)
  • Analysis of the transformation of the stabiliser
    system indicates negligible consumption (at room
    temperature)

16
TNO study on residual lifetime of PVC pipes
  • Mechanical testing
  • Craze initiation is affected by the physical
    ageing and by fatigue phenomenon
  • Burst pressures are still at a good level (and
    still compliant to ISO standard)

17
TNO study on residual lifetime of PVC pipes
  • Main conclusions of this study are
  • No chemical degradation appears
  • Gelation seems to be correlated with craze
    initiation
  • Fatigue could lead to an increased mechanical
    ageing
  • Production and laying conditions induce
    additional stresses in the material
  • The lifetime can be expected to be 100 years or
    more for high quality produced and installed
    pipes.

18
Window frames since the 1970's
  • Window frames are installed since the 1960's
  • This window was installed in Germany in1972
  • and is still in operation after more than 30
    years of good operation!
  • Usually PVC frames are not replaced because of
    damage

19
Competitive price costs of piping systems
(installation and assembling)
Steel
Cast Iron
Cast Iron
PE
Steel
Cast Iron
PVC-U
Steel
PE
PVC-U
PE
PVC-U
Source DVGW 1998
DN 100
DN 200
DN 150
20
Recycling
  • Today in Europe gt 7 000 t/y of PVC is recycled in
    pipes
  • For homogeneous rigid PVC, recycling is mainly a
    collecting process
  • For composite material (or heavily contaminated
    PVC) a special separation process has been
    developped

21
Recycling
  • PVC material can be extruded several times
  • The problem is the availability of recycled
    material since the articles installed in the
    1970's are not available for recycling !

22
Thank you for your attention !
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