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Uniaxial opics

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Title: Uniaxial opics


1
Uniaxial opics
  • Nesse, 1991
  • Chapter 6, page 53 to 76

2
REVIEW
  • An indicatrix is a geometric figure that shows
    the index of refraction and vibration direction
    for light passing in any direction through the
    material
  • IMPORTANT Indicatrix is constructed so R.I.s
    plotted as radii that are parallel to the
    vibration directions of the light
  • Simplest example Isotropic Indicatrix- the
    velocity of light is the same in all directions
    as it passes through a substance ie a sphere
  • This is exhibited by glasses
  • minerals of the cubic system eg Garnet

3
Optical properties of uniaxial minerals
  • UNIAXIAL Minerals eg calcite
  • Two images are produced by double refraction,
    each image composed of PPL vibrating at right
    angles to each
  • If the rhomb is rotated, one image is stationary
    thus behaves like isotropic material (known as
    ORDINARY RAY, ?)
  • one moves around, very different from what was
    expected in an isotropic material (known as
    EXTRAORDINARY RAY , e )

4
Optical properties of uniaxial minerals
  • The ordinary ray vibrates perpendicular to the
    c-axis
  • The extraordinary ray always vibrates
    perpendicular to the ordinary, so it vibrates in
    a plane that contains the c-axis

5
Optical properties of uniaxial minerals
  • In calcite the refractive index of the
    extraordinary ray, ne is smaller than that of the
    ordinary ray, nw.
  • Thus nw gt ne
  • This is called OPTICALLY NEGATIVE or the negative
    optic sign.
  • In the opposite case, when ne gt nw the mineral is
    called OPTICALLY POSITIVE or positive optic sign

6
Uniaxial indicatrix
  • It is important to know where are your indices of
    refraction within a crystal and what are their
    values
  • We already know that the nw vibrates
    perpendicular to the c-axis and the ne in the
    plane that includes the c-axis
  • The value of the refractive index varies between
    ne and nw and intermediate values are referred to
    by ne
  • IMPORTANT In anisotropic minerals, only
    specific crystallographic sections are isotropic,
    the general rule is double refraction. The
    direction perpendicular to an isotropic section
    is called an optic axis.

7
UNIAXIAL MINERALS
UNIAXIAL ve
  • Geometric figure is constructed called
  • UNIAXIAL INDICATRIX
  • All light traveling along the Z-axisoptic axis
    has nw, whether it vibrates parallel to X or the
    Y-axis
  • So X-Y plane of indicatrix must be a circle (and
    mineral is uniaxial positive)

UNIAXIAL -ve
8
Uniaxial indicatrix
?gt? Uniaxial ve
  • Other planes that contain the c-axis are called
    principal sections
  • Relationship between crystallography of mineral
    privileged directions (R.I.s) best viewed with
    uniaxial indicatrix

?lt? Uniaxial -ve
9
Uniaxial indicatrix
  • When nw gt ne optically negative
  • The indicatrix is oblate ellipsoid
  • Or when ne gt nw optically positive
  • The indicatrix is prolate ellipsoid

ne
ne
10
Uniaxial indicatrixBirefringence and
Interference Colors
  • Case 1 Normal incidence on a sample cut
    perpendicular to the c-axis
  • Circular section nw
  • When placed between crossed polars the light is
    entirely absorbed
  • Section stays dark on rotation of stage, acts as
    if isotropic

11
Uniaxial indicatrixBirefringence and
Interference Colors
  • Case 2 Mineral cut parallel to optic axis
  • Indicatrix section is a principal section with
    the axes equal to ne and nw
  • Section called optic plane
  • Incident ray split into two rays vibrating
    perpendicular to optic axis
  • So Birefringence is ne - nw which is maximum or
  • highest interference color

12
Uniaxial indicatrixBirefringence and
Interference Colors
  • Case 3 Mineral is cut in random direction
  • Ordinary ray has refractive index nw
  • Extraordinary ray has an index ne intermediate
    in value
  • This crystal will show a birefringence color
    lower than the maximum
  • ie partial birefringence

13
Uniaxial indicatrixBirefringence and
interference colors
  • We can use this technique the other way around.
  • We can use the interference colors to find the
    correct section of the indicatrix in a section
    with randomly oriented mineral grains.

14
Uniaxial indicatrixBirefringence and
Interference Colors
  • When observing randomly oriented grains in thin
    section
  • To find the grain with nw look for the isotropic
    section section perpendicular to c
  • To find the grain with ne and nw look for the
    section with the highest interference colors
    section parallel to c or // optic plane

15
  • Extinction in tetragonal minerals Optic axis is
    parallel to 4-fold symmetry axis

Isotropic section
Section with highest interference colors
6.10
16
  • Extinction in hexagonal minerals Optic axis is
    parallel to 6-fold symmetry axis

Isotropic section
Section with highest interference colors
6.12
17
Interference figures
An interference figure is optical phenomenon
observed through a polarizing microscope when it
is arranged conoscopically (ie strongly
converging light).
  • How to make an interference figure
  • 1/ Focus on mineral grain, first with low power
    and then with high power objective
  • 2/ Flip in the condenser
  • 3/ Cross the polars
  • 4/ Insert Bertrand lens

18
Interference figure
  • When the optic axis of the grain is perpendicular
    to the stage (or section perpendicular to c-axis)
  • 1/ Centered uniaxial interference figure

Melatope
Isochrome
Isogyre
19
2/ Off-Centered Uniaxial Interference Figure
  • Section not perpendicular to c-axis
  • Not parallel to optic plane
  • Somewhere in between ie partial birefringence
  • 3/ Flash Figure Broad fuzzy indistinct cross
  • Section of mineral contains c-axis and the Optic
    Axis is parallel to microscope stage
  • Such a grain exhibits maximum birefringence in
    thin-section

20
Interference figures
  • Interference figure in tetragonal minerals

Isotropic section Centered uniaxial
Section with highest interference colors - Flash
Figure
Section with intermediate interference
colors Off-centered uniaxial interference figure
6.10
21
Interference figures
  • Extinction in hexagonal minerals

Isotropic section Centered uniaxial
Section with intermediate interference
colors Off-centered uniaxial interference figure
Section with highest interference colors - Flash
Figure
6.12
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