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Catalysis

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accelerate reactions by facilitating the formation of transition state ... axis osa. curve krivka. despatch urychlen . decelerating - zpomalen ... – PowerPoint PPT presentation

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Title: Catalysis


1
Catalysis
  • Veronika Bacová
  • Lenka Rábová

2
Catalysis
  • process, which runs in a present of calalysts or
    inhibitors
  • 3 main types
  • homogeneous
  • heterogeneous
  • microheterogeneous (enzyme)
  • autocatalysis

3
Catalysts
  • chemical substances
  • accelerate reactions by facilitating the
    formation of transition state
  • alter only the reaction rate and not the reaction
    equilibrium

4
(No Transcript)
5
How catalysts work?
  • active site
  • binding substrate
  • forming complex
  • releasing product
  • allowing to bind additional substrate

6
How can we influence rate of catalysis?
7
Autocatalysis
  • special type of homogeneous catalysis
  • catalyst is the product of reaction

8
Inhibition, inhibitors
  • negative catalysis
  • chemical substances
  • activity of catalyst is inhibited by the binding
    of specific small molecules and ions on the
    substrate
  • types reversible
  • irreversible

9
Reversible inhibition
  • competitive bind substrate (CS) or inhibitor
    (CI), not both
  • noncompetitive bind inhibitor and substrate at
    different binding sites (CSI)

10
Vocabulary
  • accelerate urychlovat
  • facilitating usnadnení
  • transition state transitní stav
  • alter menit, upravovat
  • rate rychlost
  • equilibrium rovnováha
  • axis osa
  • curve krivka
  • despatch urychlení
  • decelerating - zpomalení
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