dorbitals within octahedron

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d-orbitals within octahedron
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(No Transcript)
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Tetrahedral field
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Splitting in tetrahedral field
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Distortion to octahedral field
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Comparison of d-orbital energy levels for various
geometries
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MO levels for octahedral complex
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MO diagram NH3
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SALCs (LGOs) for octahedral
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SALCs of ligand s orbitals in Oh
0
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MO diagram CO
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p-bonding interactions
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p-donor ligand effect on DO
Ex Cl-, Br-
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p-acceptor ligand effect on DO
Ex CO, N2
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Absorption in the electronic spectrum
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Optical absorption spectrum of Ti(OH2)63
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Spectrum of a d3 complex Cr(NH3)63
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Microstate table for p2
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Microstate table for p2
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Microstate table for p2
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Microstate table for p2
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Reduction to free-ion terms
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1D
1S
3P
Term symbols
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Correlation of spectroscopic terms for d
electrons in Oh complexes
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Correlation diagram (d1)
Free ion Strong field d1
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Correlation diagram (d2)
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Tanabe-Sugano diagram (d2)
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Tanabe-Sugano diagram (d2)
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Tanabe-Sugano diagram (d2)
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Cr(NH3)63
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Charge transfer transitions
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Cr (NH3)63 and CrCl(NH3)52
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Ru(bipy)32
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Absorption and Phosphorescence of rubies and
Ru(bipy)32