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Title:

CH3OCH3

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1,3-dioxane. 1,4-dioxane. ????. ???? ??????????. RO CH3Br R-O-CH3 Br. ???????? ?????? ... ??????: ????? ??'? ????????. R-O-R 2 HBr 2 RBr H2O. H Br ... – PowerPoint PPT presentation

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Title: CH3OCH3


1
????? ??????
?????
??????????
CH3OCH3
?????? ???
EtOEt
?????? ???
CH3OCH2CH3
???????? ???
????-???-????? ???
MTBE
2
tetrahydrofurane
oxane
1,3-dioxane
1,4-dioxane
THF
????
???? ??????????
RO CH3Br ? R-O-CH3 Br
???????? ??????
H2SO4
-H2O
3
???????? ??????
?????? ????? ??"? ????????
R-O-R 2 HBr ? 2 RBr H2O
H
RBr R-OH
Br
4
Crown ethers
12-crown-4
1.2-1.5 Å
2.6-3.2 Å
18-crown-6
1.7-2.2 Å
15-crown-5
2.66Å
1.80Å
1.35Å
5
(No Transcript)
6
????
????
KOH

18-C-6
Template
7
???????
Phase transfer catalyst
????? ???????? ?? ?????
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