Title: Soil and Forensic Geology
1Soil and Forensic Geology
2What Is Soil?
- Mixture of organic and inorganic material
- May range from 100 inorganic (sand) to nearly
100 organic (peat) - Inorganic part is minerals
- Organic part is decayed plant and animal material
and is sometimes called humus
3Forensic Significance of Soil
- Soil is class evidence - cannot be individualized
to a particular location - There is no classification system for soils
- Soils can be easily transported
- Soils within a few meters horizontally or
vertically differ
4Forensic Analysis of Soils
- Bulk analysis
- Density gradient
- Particle size distribution (sieving)
- Inorganic components
- Color (dissolve in water)
- Petrography - mineral analysis Requires a good
deal of skill and practice
5Forensic Analysis of Soils
- Organic components
- Liquid chromatography
- Oxygen availability
- Bacterial DNA? - Future possibility
6(No Transcript)
7Why is soil such a good source of evidence?
- Large Variations of soil characteristics
- Extreme Complexity of its composition
- Minerals
- Oxides
- Organic Matter
- Microorganisms
- Artificial additions (concrete, asphalt,
plastics) - Runoff additions (salt, fertilizers, pesticides)
- Manufactured products glass, paint, asphalt,
brick, industrial products, - Complex Physical Nature
- Varies due to above compositions
8Forensic Geologists
- The forensic Geologists examinations involve the
identification of - Earth materials
- Comparison of samples to determine common source
- Studies that aid a criminal investigations and
intelligence studies.
9Forensic Geology In Intelligence Work
- Remember the outcrop you saw behind Osama bin
Laden on TV after September 11. What was the
location? - A geologist who has done field work in the area
would be able to locate that outcrop, and that
actually happened Geologist John Shroder was
able to identify the region where bin Laden had
been sighted in Afghanistan in 2001 (see
Geotimes, February 2002).
10Forensic Geologists of the Past
- Starting in 1887 Sir Arthur Conan Doyle wrote The
Sherlock Holmes series used soil and residues
many times to link individuals to specific
locations. - In 1893, Hans Gross, authored Handbook for
Examining Magistrates. In it he suggested
that the dirt on someone's shoes could tell more
about where a person had last been than many
other techniques used in that time.
11The Eva Disch Case
- In October 1904 a dirty handkerchief containing
bits of coal, snuff, and grains of the mineral
hornblend was found at the murder scene of a
seamstress named, Eva Disch. - A suspect was found who used snuff, and worked
part-time at both a coal burning gas works and a
quarry that had an abundance of the mineral
hornblend. - The suspect also had two layers of dirt in his
pant cuffs. The lower layer matched the soil at
the crime scene and the upper layer,
characterized by a particular type of mica
particle, matched the soil found on the path to
the victim's home. - When confronted with the evidence the suspect
confessed. (Murray and Tedrow, 1991, p. 4)
12Forensic Geologists
- The microscope is and will remain an important
tool. - Qualifications and competence of examiners is a
major problem. - Should those qualifications be regionalized?
- The future will see
- Improved training of those who collect and
analyze samples - Increased automated methods of examination
- Improved research
- The diversity of soils
- What parts of soil are transferred during various
types of contacts and could their be a pattern
13Forensic Geologists Questions
- Interconnected by the following questions
- What is this material?
- Where did this material come from?
- Is this material unique to a crime scene or
unique to circumstances under which a criminal
act was committed? - What is the geologic context of a crime scene?
14My Husband Went hunting and never came home ?
- A pond with bentonite (clayish mud) in the
mountains of western Colorado proved to be a
really great place to camp for John Dodson.
15Physical Properties of Soil
- Soil Texture, Structure, Compaction
- is the percent of sand, silt and clay in a soil.
- sand is the coarsest (0.06 - 2 mm)
- silt is intermediate (0.002 - 0.06 mm)
- clay is the finest (lt0.002 mm)
16Soil Texture
- The texture of a soil is determined by the
percentages of particles like sand, silt, clay
that it contains.
17Physical Properties of Soil
18Soil Comparison
- Simple observations using local geologists
- Color of dry sample, (1,100 controls)
- Texture of dry sample
- Composition
- Mineralogy, mineral crystalline solid
- 2,200 minerals,
- 40 commonly seen
- ROCKS COMPOSION VARIES BASED ON MINERAL
COMPOSITION - Mineral content
- Grain size
- LP Microscopy, shows animal, plant and
artificial remains and their s - Side by side comparison
19Minerals
- Minerals are used by various commercial and
industrial companies. - Brick, shale, plaster, and concrete are all found
in many indoor products, drywall insulation. - Robbery suspects often have minerals within
clothing fibers. - Why????
- Locards Exchange Principle
20Locards Exchange Principle
- The exchange of materials between two objects
that occurs whenever tow objects come into
contact.
21Physical Properties of Soil Organics
- Humus a mixture of organic material that binds
nutrient mineral ions and holds water. - Detritivores like Earthworms, termites, and ants
help to breakdown humus. - Humus persists in agricultural soil for about 20
years. - Humus ? CO2 H2O nutrient minerals
22 Physical Properties of Soil(Organisms)
- Bacterial and Protozoan colonies
- Plant litter
- Fungi
- Animal
- Most common insects, arachnids, and annelids
- Materials in varying states of decomposition
23Physical Properties of Soil Soil Pore Spaces
- Pore spaces Occupy about 50 of a soils volume
and can be filled with H2O (soil H2O) or air
(soil air). - Soil air is found in larger pores.
- Soil H2O is found in smaller pores (0.05mm).
24Physical Properties of Soil Soil Horizons
- Horizontal layers of organized soil.
- A soil profile is a vertical section from surface
to parent material.
Differentiated Instruction Alert
25Soil Horizon Basic
26Soil Horizon Basic
27Soil Horizons
28Soil Horizons for Honors??
29Soil Collection
- Various interval 100 yard radius of the CS.
- Sampling Surface and Subsurface layers
- Approximately 1 tablespoon per sample
- Individual plastic vials
- On Suspect
- Both soil and object are wrapped in paper
- Layering effect on vehicles occurs over time due
to sedimentation - Collected separately only if jarred loose
30Laboratory Possibilities
- Soil Comparisons
- Soil nutrients, Nitrate and Phosphorus
- Water holding capacity
- Texture
- pH
- Organic Content
- Sieve Percent Composition
- Undisturbed vs. newly disturbed soil
- Density
- Leads to other chapters
- Crime Scene
- Impression
- Foot and tire
- Anthropology
- Botanicals
- Inductively coupled plasma mass spectrometry
(ICPMS) - (Ask Mark He can get you one)
31Soil Comparison
- Differences in soils can identify location of
victims, suspects, or the crime scene. - Or Inconsistencies between them!!
- Remember the DEA SA Camarena?
32Disturbed Soil Comparison
Newly disturbed Soil showing O-Layer(Organic)
fresh, organic topsoillayer
OldUndisturbedSoil same consistent color
33Excavations
34Lab Investigating Soil Core Sampling
35Lab Finding Your Past
- Objective Locate evidence of a past structure
that is no longer in existence. - Hint Try to remember past homes, hangouts,
relatives homes . Can you think of a structure - Change the color of your house?
- Relocate a structure?
36Lab Finding Your Past
37Lab Finding Your Past
38Lab Finding Your Past
39Charcoal tells us what??
- Another Attempted Cremation Like Hitler, Joseph
and Magda Goebbels were cremated. The bodies of
their six children remained in the bunker. They
were found by Russian soldiers when Berlin fell
to the Allies.
40Density-Gradient Tube
- Glass tubes measuring 6 to 10 millimetres in
diameter and 25 to 40 centimetres in length are
filled with several layers of two liquids mixed
in varying proportions such that each layer has a
different density. - An example is the mixture of tetrabromoethane,
which has a density of 2.96 gmL-1 with ethane,
with a density of 0.789 gmL-1. - The soil components then sink to the layers
corresponding to their own density values and the
distribution of particles can be compared between
soil specimens.
Sample from Crime Scene
Sports Pitch
College Gardens
Courtyard
41Inductively coupled plasma mass spectrometry
(ICP-MS)
- The coupling of ICP-MS shows many advantages over
other analysis techniques. - Benefits of the ICP over other radiation sources
include improvement in excitation and ionization
efficiencies and the reduction or elimination of
many of the chemical interferences found in
flames or furnaces. - Mass spectrometry generates a large amount of
information, has high throughput capabilities,
high sensitivity and low limits of detection.
ICP-MS is capable of multi-elemental detection
which reduces analysis time and therefore
increases sample throughput. ICP-MS is one of the
few analytical techniques that permits the
quantifying of elemental isotopic concentrations
and ratios. - It can achieve very low limits of detection
42Inductively coupled plasma mass spectrometry
(ICP-MS)
- An analysis of the elemental composition of the
soil. - The plasma is formed by argon gas flowing through
a radiofrequency field where it is kept in a
state of partial ionization, i.e. the gas
consists partly of electrically charged
particles. This allows it to reach very high
temperatures of up to approx. 10,000ºC. - The sample being analyzed is introduced into the
plasma as a fine droplet aerosol. ICP-MS is the
combination of an ICP with a mass spectrometer
(MS). - The ions generated by the ICP are directed into
the MS, which separates the ions according to
their mass-to-charge ratio. Thus, ions of a
selected mass-to-charge ratio can be detected and
quantified.
43Inductively coupled plasma mass spectrometry
(ICP-MS)
44Inductively coupled plasma mass spectrometry
(ICP-MS)
45Inductively coupled plasma mass spectrometry
(ICP-MS)
46Inductively coupled plasma mass spectrometry
(ICP-MS)
47Finito
48Links
Website link Analytical Techniques for the
Comparison of Soil Samples
- www.channel4.co.uk/.../S/science/
images/fracture.gif - http//www.file///C/InetTemp/Content.IE5/QFML278
9/256,1,All About Glass - http//www.adtdl.army.mil/cgi-bin/atdl.dll/fm/19-2
0/Ch10.htm
49Sewage leak do to inadequate Support
50Sherlock Holmes
- observation shows me that you have been to the
Post Office this morning, but deduction lets me
know that you dispatched a telegram.
51Sherlock Holmes
- It is simplicity itself. Observation tells me
that you have a little reddish (soil) mould
adhering to your instep. Just opposite the post
office they have taken up the pavement and thrown
up some earth. (It is) impossible to go to the
post office without treading that dirt. The
earth is a particular reddish color not found
anywhere else in town observation the rest is
deduction.
52Some Interesting? Cases Where Geological Evidence
Has Been Important
- Florida v. William Kennedy Smith
- South Dakota v. Donald Eugene Moeller
- Colorado v. Walter Osborne
- The Death of a DEA agent Enrico Camarena
53Florida v. William Kennedy Smith
- WKS accused of rape of Patricia Bowman
- Alleged attack on grass lawn behind Kennedy
estate in W. Palm Beach, Fl - WKS alleged consensual sex on the beach near
estate - Jay Siegel used PLM to compare samples from
clothing of victim to lawn and beach areas - Samples consistent with beach, not lawn
- WKS acquitted of rape
54South Dakota v. Donald Eugene Moeller
- Capital murder case of 9-year old Becky OConnell
on May 8, 1990. - Testimony by soil expert refutes defendant alibi
- Victim snatched off street, raped, killed, body
dumped in woods. - Suspicion fell on Defendant because of prior sex
crime involvement. - Found guilty and sentenced to death. Appeal
resulted in reversal owing to admission of
evidence of prior bad acts.
55South Dakota v. Donald Eugene Moeller (cont.)
- SD Supreme Court reversed and reinstated
conviction - State geologist analyzed soil found in wheel
wells of defendant pickup truck. Issue was
whether soil came from crime scene South of Sioux
Falls or from a road North of Sioux Falls where
defendant claimed he was at time of crime - Geologist testified that soil could have come
from crime scene. - Opinion based on
- Colors and general characteristics
- Soil was much lighter or could not have come from
other roads in area - Sharp, clean hornblende crystals much more
likely to have come from crime scene area
56South Dakota v. Donald Eugene Moeller (cont)
- Part of appeal called for striking geologists
testimony as being too speculative as to
conclusions - At 2nd trial, geologist came into more evidence
from scene and wheel well dark green to black
gahnite found at scene and in evidence from
truck. This mineral extremely rare.
57South Dakota v. Donald Eugene Moeller (cont)
- Defense argued that geologist erred in
identifying gahnite only by visual inspection.
Claimed that PLM should have been used (to
confirm that gahnite is isotropic) and that x-ray
diffraction should have been used to confirm.
Appeals court rejected appeal - There was no discussion at trial whether the
finding of both hornblende and gahnite near Sioux
Falls was a rarity or could be due to processing
after mining elsewhere. Bedrock of Sioux Falls
contains neither hornblende nor gahnite.
58Colorado v. Walter Osborne
- Osborne botches kidnapping of Adolph Coors from
his ranch near Morrison and kills Coors - Ranch is near Dakota Hogback which is made of
Dakota sandstone underlain by gray, green and
maroon clay stones, shales, more sandstone and
limestone. Dirt road near ranch was essentially
eroded, pulverized components of hogback.
59Colorado v. Walter Osborne (cont)
- During kidnapping, a fight broke out and Osborne
shot Coors. Fled in Osbornes yellow Mercury
with body. Fled south onto an unpaved road in
next county. Then went west and climbed. Road
made of muddled dust pink-feldspar. Dust was
granite, but compared to bedrock was deficient in
iron and magnesium. - As he climbed further, came into Pikes Peak
granite very distinctive.
60Colorado v. Walter Osborne (cont)
- At 7200 ft, Osborne dumped body in dump used by
an Ashram. Body would not be found for 7 months.
- Osborne went east and went on an unpaved road of
black slags and drifted sands on a New Jersey
barrier island. He hid car and torched it with
gasoline.
61Colorado v. Walter Osborne (cont)
- FBI investigation turned up Osborne in New Jersey
- Although Osborne (discovered to be Joseph
Corbett, Jr) covered his tracks well but was
writing his itinerary on the bottom of his car. - 4 depositional strata found
- 4th contained material from around New Jersey
dump where he burned car - 3rd contained pink feldspars of Pikes Peak
granite near where body was found - 2nd had materials from Morrison hogback formation
around Coors rangch - 1st had pink feldspars of other Front Range
granites generally related to Rocky Mountain
Front Range
62Death of a DEA Agent Enrico Camarena
- Story of how FBI geologist, Ron Rawalt was able
to determine, with certainty, where Camarena body
was buried, thus showing that Mexican govt. lied
about how he was killed. - He noticed a TV report of the killings. The body
was shown with soil clinging to it. The soil was
obviously of a different color than the soil from
the alleged burial site.
63Death of a DEA Agent Enrico Camarena (cont)
- He told the govt. that he could prove, with soil
analysis alone, that Mexican govt. was lying
about the murder. - He went to Mexico and collected a spoonful of
soil from Camarena body. He compared that to the
soil from the alleged burial site and found them
to be entirely different.
64Death of a DEA Agent Enrico Camarena (cont)
- Soil from body
- Spoke of mountains
- 98 rhyolite ash (clean, high in silica, angular,
vesicular) could be described as airfall
pumice - Bixbyite blacker than coal
- Pink glass of exceptional depth and richness of
color, he had never seen anything like it, except
in candy - 2 kinds of cristobalite opalized and clear,
elongate and faceted, clear polygonal columns
(octehedrons). Resembled branch coral. Very
rare to find both types together.
65Death of a DEA Agent Enrico Camarena (cont)
- Pinpointing location
- Research with Geological Survey and Smithsonian
minerologists located specific location A
Jalisco state park called Bosques de la Primvera.
Cristabolite was the result of a third-event
calderea formation. - Location is on upslope of mountain in park or
park itself - Rawalt flew to Mexico as DEA agent (FBI agents
were not allowed in to investigate
66Death of a DEA Agent Enrico Camarena (cont)
- While Rawalt was in Mexico searching for the area
of burial, FBI was approached about a French
consultant, Loic Le Ribault. He was the head
petrologist for the French national oil company
and was said to be able to do things geologically
speaking, that other people couldnt do. Show
him a few grains of sand and he could tell you
where they came from
67Death of a DEA Agent Enrico Camarena (cont)
- Le Ribault
- FBI tested him by giving him 3 samples
- Ash from Mt. St. Helens
- Alluvium from river delta in S. Carolina related
to recent murder - Dirt from girders taken from bomb site in Beirut,
Lebanon - Ribaults results
- Got location of ash from Mt. St. Helens within a
few miles of source - River basin in American Southest
- Bekaa valley in Lebanon soil had been subjected
to explosion
68Death of a DEA Agent Enrico Camarena (cont)
- Le Ribaults contribution to Camarena case
- Was showed samples from park and body. He said
you are there, but not there. Right elevation,
but these are samples (from park) from an area
washing north. The site is an area washing
south. - Sand deposited by water 4-5 ft. deep in a draw.
Slope of draw lt10 degrees. Shade predominates. - Rawalt found exact location from this data.
69Soil and Arsenic poisoning
- Â Â Washington State Patrol Forensic Geologist
Bill Schneck became involved in the investigation
into the serious illness of a small child caused
by arsenic poisoning. - The suspected person was absolved when an
examination of the child's house revealed a
number of mineral specimens left in the house and
the yard by a former occupant who was a mineral
collector. Many of those specimens were
arsenopyrite, an iron arsenic sulfide. - The child had been eating and chewing on the
material.
70An Early Case The Father Patrick Heslin Case
- In Colma, California on 2 August 1921 a priest,
Father Patrick Heslin, was kidnapped and a ransom
note was received, but there was no further
contact from the kidnapper. - The priest's body was found on a local beach by
William Hightower, a master baker. However, sand
grains found on Hightower's knife and in his room
matched the beach sand at the site where the body
was found. Hightower was convicted of the murder
and sentenced to life imprisonment in San Quentin.