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History of the Atom

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Title: History of the Atom


1
History of the Atom
  • Scientists and Their Discoveries

2
Atoms
  • Atoms- smallest possible unit into which matter
    can be divided, while still maintaining its
    properties.
  • Made up of
  • protons
  • neutrons
  • electrons
  • Electrically they are NEUTRAL!!!!

-

For example, what is the smallest possible unit
into which a long essay can be divided and
still have some meaning?

-


-

-
-
3
Elements
  • Element- made up of one kind of atom that cant
    be broken down into simpler substances by
    physical or chemical means
  • 90 occur naturally on Earth
  • 29 were synthesized (made) by scientists

4
The Periodic Table of Elements-Reference
  • Periodic table tiles contain a lot of information
    and to understand it, its necessary to know the
    parts of the atom and some terminology concerning
    them

Atomic Number (number of protons)
8 O Oxygen 15.999
Element Symbol (a capital letter or a capital
followed by a lower case letter)
Element Name
Atomic Mass (weighted average of all isotopes
mass)
5
The Atoms Center
  • Nucleons- particles in the nucleus of atoms
  • Protons
  • Neutrons

Notice that the electrons are not a part of the
nucleus
-
-
-
6
Neutrons
  • Neutrons- neutral particles have no electric
    charge
  • Help make up the nucleus of the atom
  • Contribute to the atomic mass
  • 1.67 X 10-24 g

7
Protons ()
  • Protons- positively charged particles
  • In nucleus
  • They ID an atomatomic number
  • Contribute to the mass of the atom 1.67 X 10-24
    g
  • Charge 1.6 X 10-19 coulombs (same value as
    electron but positive)


8
Atomic Number
  • Atomic number - the number of protons in the
    nucleus of an atomits ID !!!!
  • Represented by Z

-
-
-
What would be the atomic number of the atom to
the left? What element is it?
9
Electrons (-)
  • Electrons- negatively charged particles
  • Outside the nucleus of the atom in electron
    orbits/levels
  • Move rapidly and create an electron cloud
  • Mass is insignificant
  • Valence electrons- the outermost electrons
    involved in the formation of chemical bonds

-
10
Neutral Atoms
  • Most atoms are neutral and the number of protons
    the number of electrons
  • 1 protons and 1 electrons0 (neutral)
  • Atomic number protons electrons

11
Electromagnetic Force
  • Electromagnetic force is the force that results
    from the repulsion of like charges and the
    attraction of opposites
  • AND NEUTRALIZE
  • ONE ANOTHER
  • This the force that holds the electrons around
    the nucleus
  • Bill Nye Atoms




-
-
-
Notice how the particles with the same charge
move apart and the particles with different
charges move together.
Why are neutrons not pictured above?
12
Atomic Models
  • Model a familiar idea used to explain
    unfamiliar facts observed in nature
  • Theory- an explanation of observable facts and
    phenomena
  • To remain valid, models and theories must
  • Explain all known facts
  • Enable scientists to make correct predictions

13
Democritus(460 BC 370 BC)
  • Proposed the existence of atoms from Greek word
    atomos which means not to cut or
    indivisible
  • Thought you could cut matter in half until you
    got an indivisible (not dividable) particle

Image taken from https//reich-chemistry.wikispac
es.com/T.GlennTimeLineProject
14
Aristotle(384 BC 322BC)
  • Rejected idea of the atom
  • Said matter could be cut continually
  • Aristotle was more influential than Democritus
    so atoms were forgotten about until late 1700s

15
Antoine Lavoisier (1743 1794)
  • Father of Modern Chemistry
  • Generated a list of 33 elements
  • Devised the metric system
  • Discovered/proposed the Law of Conservation of
    Mass
  • - matter cant be created or destroyed, it just
    changes form (beginning mass end mass)

Image taken from www.ldeo.columbia.edu/.../v1001/
geotime2.html
16
John Dalton (1766 1844)
  • In 1803 he proposed first experimentally based
    Atomic Theory that states atoms
  • are building blocks of matter
  • are indivisible
  • of the same element are identical
  • of different elements are different
  • Billiard Ball Model

17
John Dalton (1766 1844)
  • Daltons Atomic Theory also explained The Law of
    Multiple Proportions -ratio of the masses of
    combined elements are WHOLE numbers which become
    subscripts for chemical formulas
  • Nitrogen and Oxygen combine to form NO or NO2,
    but not NO1.5

18
Law of Definite Composition
  • Law of Definite Composition (Prousts Law)-
    elements combine in a definite (constant) ratio
    by atomic mass
  • Water (H2O) is always 2 hydrogens for each oxygen
  • 162 oxygenhydrogen mass ratio or 81 reduced
  • For Carbon dioxide (CO2) there is always a 3212
    oxygen to carbon mass ratio, or 83 reduced.

19
J.J. Thomson (1856 1940)
  • Put electricity through a vacuum tube and
    produced a beam that was negatively charged
  • Cathode Ray Tube Experiment

20
J.J. Thomson (1856 1940)
  • Credited with discovery of electron a blow to
    Daltons indivisible atom idea
  • Plum Pudding Model
  • Also because atoms are neutral, the negative
    electrons must be embedded in a ball of positive
    charge

21
Millikan Oil Drop Experiment
  • Calculated the mass and quantified the charge of
    electrons!
  • Mass of electron 9.1 X 10-28 grams
  • (0.00000000000000000000000000091 g)
  • Charge on the electron -1.6 X 10-19 coulombs
    (unit of charge)
  • Millikan Animation and Interactive

22
Millikan Oil Drop Experiment-Reference
23

JJ Thomson and E. Goldstein
  • Realized if neutral atoms contain negative
    electrons, they must contain positive particles
  • Used vacuum tube similar to discovery of electron
    to discover protons
  • Mass 1.67 X 10-24 grams (much heavier than
    electron!)
  • Charge 1.6 X 10-19 coulombs (same value as
    electron but positive)

24
Ernest Rutherford (1871 1937)
  • Gold-foil experiment
  • Positively charged alpha particles aimed at thin
    gold foil, but most passed through
  • A few were deflected and some even bounced right
    back
  • Gold foil experiment

25
Rutherfords Gold Foil Experiment-Reference
(1871 1937)
26
Ernest Rutherford (1871 1937)
  • Conclusions
  • Disproved Thomson because showed most of atom is
    empty space
  • Discovered dense, positively charged core, or
    nucleus, repels the alpha particles
  • Protons are surrounded by negatively charged
    electrons
  • Planetary Model
  • Youll never see life the same way again

27
James Chadwick (1891 1974)
  • Discovered the atomic mass of most elements was
    double the number of protons ? discovery of the
    neutron in 1932
  • Worked on the Manhattan Project
  • Worked with Ernest Rutherford
  • Like many others before him, he won a Nobel Prize

28
ReviewEarly Atomic Theory video 5 min
  • Number your paper from 1-5 and answer the
    following questions. Two will be cumulative
    review!
  • 1. Which of these has 3 significant figures?
  • a. 3340
  • b. 3.340
  • c. 0.001334
  • d. 334.00

29
Review
  • A
  • 2. Which of these is a homogenous mixture?
  • a. salt
  • b. iced tea
  • c. pizza
  • d. your computer

30
Review
  • B
  • 3. Which of these is true about subatomic
    particles?
  • a. electrons are negatively charged and in the
    nucleus
  • b. protons are negatively charged and in the
    nucleus
  • c. protons are positively charged and fly around
    the outside of the nucleus
  • d. neutrons are neutral and are in the nucleus

31
Review
  • D
  • 4. Which of these is true about the discovery of
    Millikans oil drop experiment
  • a. He discovered the electron
  • b. He discovered the mass of the neutron
  • c. He discovered the mass and the charge of the
    electron
  • d. He discovered the proton

32
Review
  • C
  • 5. Which of these is false?
  • a. Neutrons are neutral
  • b. Protons are positive and two will repel
  • c. Electrons are negative and two will attract
  • d. Protons are positive and they will attract
    negative electrons

33
Review
  • C

34
Mass of Sub-Atomic Particles-Reference
(protons, neutrons, electrons)
Neutron 1.6749286 x10-24 gProton 1.6726231
x10-24 gElectron 9.1093897 x10-28 g
1836 electrons 1 proton
1839 electrons 1 neutron
How do you think the mass of a neutron compares
to that of a proton?
1 neutron 1 proton 1.67 x10-24 g
35
Mass Number
  • Mass number number of particles of significant
    mass in the atom
  • Represented by A
  • protons neutrons mass number
  • Electrons are NOT included, their mass is zero
  • NOT found directly on the periodic table!

Particle Charge Mass number Location in atom
Proton 1
Neutron 1
Electron 0
36
Lets Do It!!!
What would be the mass number of this atom?
-

? 3
? 4
-
3 protons 4 neutrons a mass number of 7
Why did we not account for the electrons when
calculating the mass number?
-
37
Calculating the Actual Mass of 1 Atom
  • Actual mass of an atom is determined by the
    protons and neutrons (electrons have virtually no
    mass)
  • Each proton and neutron mass 1.67 x 10-24 g
  • Ex a hydrogen atom has 1 electron and 1 proton
  • Proton 1.67 x10-24 g
  • No neutrons 0g
  • Electron 0 g
  • Mass of the entire hydrogen atom 1.67 x10-24 g

38
Calculating the Actual Mass of 1 Atom-Reference
  • The actual mass of an atom
  • (protons neutrons)(mass of ps and
    ns)(protons neutrons) (1.67 x 10-24 g)
  • dont count sds
  • Ex Whats the actual mass of a Lithium atom with
    3 protons and 4 neutrons?
  • (protons neutrons)(mass of ps and ns)
  • (7)(1.67 x
    10-24g)

  • 1.17 x 10-23 g

39
Relate Actual Mass to Mass Number
  • We can say the actual mass of an atom
  • (protons neutrons)(mass of ps and ns)
  • OR
  • (mass number) (1.67 x 10-24 g)
  • dont count sds

40
Lets Do It!!!
  • Whats the actual mass of a Carbon atom with 6
    protons and 8 neutrons?

41
Lets Do It!!!
  • (14)(1.67 x 10-24g) 2.34 x 10-23 g

42
Calculating the Actual Mass of 1 Atom
  • Actual mass of an atom based on the idea that the
    whole atom is equal to the sum of the parts
  • Not exactly correct because binding energy is
    needed to hold the parts of an atom together
  • Some mass converted to this binding energy in a
    nuclear reaction so the calculation gives a value
    that is a little larger than reality
  • (E mc2)

43
Isotopes
  • What mass numbers do these atoms have?
  • What elements are these?
  • How do you know?


44
Isotopes
  • There mass numbers are 1, 2, and 3 but they all
    have one proton and therefore are all hydrogen!
  • So what is going on? They are isotopes.

45
Isotopes
  • Isotopes different versions of atoms of an
    element that have same of protons but different
    of neutrons
  • This discovery disproved one of Daltons idea
    that atoms of the same element are exactly alike!

46
Isotopes
  • Hydrogen-1 (Protium) 1 proton, no neutrons and
    is most common
  • Hydrogen-2 (Deuterium) 1 proton and 1 neutron
  • Hydrogen-3 (Tritium) 1 proton and 2 neutrons
  • All versions of hydrogen!

47
Hyphen Notation-Reference
  • We use mass numbers to distinguish between
    isotopes because they differ in their number of
    neutrons
  • Hydrogen-1 1 proton 0 neutronmass 1
  • Hydrogen-2 1 proton 1 neutron mass 2
  • Hydrogen-3 1 proton 2 neutronsmass 3
  • This is written in hyphen notation

48
Nuclear Symbols-Reference
  • Nuclear symbols are a way to write atoms using
    the mass number and atomic number
  • Format
  • Hydrogen-1 Hydrogen-2 Hydrogen-3
  • 1 2
    3
  • H H
    H
  • 1 1
    1
  •  

49
Lets Do It!!!
  • Naturally occurring carbon consists of three
    isotopes, Carbon-12, Carbon-13, and Carbon-14.
    State the number of protons, neutrons, and
    electrons in each of these carbon atoms
  • Think-Pair-Share
  • 12C 13C 14C
  • 6 6
    6
  • p _______ _______
    _______
  • n _______ _______
    _______
  • e _______ _______
    _______

50
ReviewAtomic Number video 9 min
  • Number your paper from 1-5 and answer the
    following questions. Two will be cumulative
    review!
  • 1. Which of these is proper scientific notation?
  • a. 4.56 X 106
  • b. 4.5 X 32
  • c. 45.6 X 1010
  • d. 456 X 106

51
Review
  • A
  • 2. Which of these would be the correct answer
    with the proper number of significant digits if
    you multiplied 0.05 X 3.01
  • a. 0.1505
  • b. 0.150
  • c. 0.15
  • d. 0.2

52
Review
  • D Remember beginning zeros are never significant,
    so 0.05 has only 1!
  • 3. What does this mean? 14C
    6
  • a. this atom has 6 neutrons and 20 electrons
  • b. this atom has 6 protons and 8 neutrons for a
    combined mass number of 14
  • c. this atom has 6 protons and 14 electons
  • d. this atoms has 6 electrons and 14 neutrons

53
Review
  • B
  • 4. Which of these is a correct definition of an
    isotope?
  • a. different versions of an element that have a
    different number of neutrons
  • b. atoms of the same element with the same atomic
    number but different mass number
  • c. different version of an element that have the
    different number of electrons
  • d. A and B
  • e. B and C

54
Review
  • D
  • 5. How do you calculate the actual mass of an
    atom
  • a. add up all the protons, electrons, and
    neutrons
  • b. add up all the protons and neutrons and divide
    by two
  • c. add up all the protons and neutrons and
    multiply by 1.67 x 10-24 g
  • d. add up all the protons and neutrons

55
Review
  • C

56
Actual Mass of 1 Atom-Reference
  • The actual mass of an atom is a super small
    number and is cumbersome in calculations, so
    scientists assigned a relative scale to the mass
    of these particles and created a new unit called
    atomic mass unit, or amu (?)
  • amu (?) atomic mass unit

57
Finding Atomic Mass of a Single Atom
  • To convert from actual mass to this new amu,
    scientists set Carbon as the standard and the
    value of the amu unit is defined by the actual
    mass of Carbon-12
  • Actual mass of C-12 (12)(1.67x10-24g)
    2.00x10-23g
  • and we use this as a standard to create a
    conversion factor
  • 2.00x10-23g 12? (amu)

58
Reference-Atomic Mass of a Single Atom
  • Find the atomic mass of an Oxygen-18 atom
  • Step 1 calculate the actual mass of an
    Oxygen-18 atom
  • 18 x 1.67x10-24 g 3.01 x10-23 g
  • Step 2 use dimensional analysis to convert to
    amu with our Carbon standard conversion factor
  • 3.01 x10-23 g x 12 ? 18.1 amu
  • 2.00 x10-23 g
  • Dont use 12 when figuring SDs because it is a
    standard, not a measurement

59
Lets Do It!!!
  • Whats the atomic mass of a 7 Li atom?

60
Lets Do It!!!
  • Whats the atomic mass of a 7 Li atom?
  • Step 1 calculate the actual mass of this lithium
    atom
  • 7 x 1.67x10-24 g 1.17 x10-23 g
  • Step 2 use dimensional analysis to convert to
    amu with our Carbon standard conversion
  • 1.17 x10-23 g x 12 ? 7.02 amu
  • 2.00 x10-23 g

61
Isotopes
  • What elements are these?
  • What are their mass numbers?






62
Isotopes
  • How would we write the hyphen notation of these
    isotopes? Nuclear notation?
  • Students on board






63
Isotopes
  • If we pick up one of the trillions of boron atoms
    in the world, it could be either of these 2 types
    because they are both present





  • Boron-10
    Boron-11

64
Isotopes
  • As it turns out, any mass of Boron, and all Boron
    in the world, is 20 Boron-10, and 80
    Boron-11their relative abundances





  • Boron-10
    Boron-11
  • 20
    80

65
Isotopes
  • Many elements are like this
  • All chlorine in the world is 75 Chlorine-35 and
    25 Chlorine-37
  • The majority are Chlorine-35

66
Isotopes-Reference
  • In nature there are always mixtures of isotopes
    and this can pose difficulties when we do
    calculations. Why?
  • Pencil lead (carbon) has some carbon-12,
    carbon-13 and carbon-14 mixed
  • The mass of one Carbon-12 atom with 12 protons
    and neutrons would be this
  • (12)(mass of protons and neutrons)
  • (12)(1.67 x10-24 g) 12 amus (?)
  • but that is just for Carbon-12!!

67
Isotopes and Atomic Mass of an Element
  • STOP! Mass confusion and Reference Chart
  • In calculations we need a mass value that
    represents the whole element mixture (carbon-12,
    carbon-13 and carbon-14 mixed), not just one
    isotope, like Carbon-12 How?

68
Atomic Mass of an Element-Reference
  • Atomic mass- WEIGHTED average of the atomic
    masses of all the elements isotopes as they are
    found in nature (dont confuse it with mass
    number which is just p n)
  • (abundance isotope 1) (atomic mass isotope 1 ?)
  • (abundance isotope 2) (atomic mass isotope 2 ?)
  • continue for all isotopes

69
Isotopes and Atomic Mass of an Element
  • The atomic masses of each element (the weighted
    average of all its isotopes) is found in the
    periodic table





  • Boron-10
    Boron-11
  • 20
    80

70
  • Atomic Mass of an Element Reference
  • Use the following data to calculate the atomic
    mass for the element Magnesium
  • Isotope Atomic Mass of Isotope Abundance
  • Mg - 24 23.982628 ? 78.600
  • Mg - 25 24.963745 ? 10.11
  • Mg - 26 25.960802 ? 11.29
    (.78600) (23.982628 ? )
  • (.1011) (24.963745 ? )
  • (.1129) (25.960802 ? ) 18.850 ? 2.52
    ? 2.931 ? 24.305 ?
  • You do SDs for every individual calculation

71
Lets Do It!!!!
  • The element copper has naturally occurring
    isotopes with mass numbers of 63 and 65
  • The relative abundance and atomic masses are
    69.2 for a mass of 62.93amu and 30.8 for a mass
    of 64.93amu. Calculate the atomic mass of the
    element copper

72
Lets Do It!!!!
  • Divide the percentages by 100 to convert to
    decimals
  • (.692) (62.93amu) (.308)(64.93amu)
  • 43.5 amu 20.0 amu
  • 63.5 amu
  • This shows that the majority of the isotopes
    found in nature are 62.93 amu (closer to 63 than
    65)

73
Lets Do It!!!
  • There are two isotopes of silicon. The atomic
    mass of the element silicon found on the periodic
    table is 28.086amu.
  • Which of these is not possible to be one of the
    atomic masses of the individual isotopes?
  • A. 26.065
  • B. 29.543
  • C. 28.086
  • D. 27.439
  •  

74
  • Atomic Mass of an Element
  • If an element has only 1 isotope, then the atomic
    mass of that isotope IS the atomic mass of the
    element

75
Review
  • Number your paper from 1-5 and answer the
    following questions. Two will be cumulative
    review!
  • 1. Which of these is the symbol for the metric
    unit micro (and also for amu)?
  • A. M
  • B. m
  • C. ?
  • D. µ

76
Review
  • D
  • 2. Which of these is the amount of protons in an
    atom and therefore, the ID.
  • a. atomic mass
  • b. atomic number
  • c. mass number
  • d. isotope number

77
Review
  • B
  • 3. What is the bottom number on this periodic
    table tile?
  • a. atomic mass of the element
  • Boron
  • b. atomic number
  • c. mass number
  • d. atomic mass of a Boron atom

78
Review
  • A
  • 4. The atomic mass of the element sulfur is 32.1
    g. There are four common isotopes of sulfur, S-32
    (32.2344 µ), S-33 (33.45676 µ), S-34 (34.15643
    µ), S-36 (36.44321 µ) Which of these isotopes
    is the most abundant?
  • a. S-32
  • b. S-33
  • c. S-34
  • d. S-35

79
Review
  • A
  • 5. How do you calculate the atomic mass of an
    element?
  • a. l x w x h
  • b. D m/V
  • c. (abundance isotope 1)(atomic mass 1)
    (abundance isotope 2) (atomic mass 2) etc.
  • d. mass number atomic number

80
Review
  • C

81
The Mole
  • The word mole in Chemistry is a term used to
    describe a certain amount of something
  • For example
  • 1 dozen 12
  • 1 bakers dozen 13
  • 1 gross 144
  • 1 mole 6.02 X 10 23 which is
  • 602,000,000,000,000,000,000,000 or 602
    hextrillion of whatever

82
The Mole-Reference
  • A mole is the amount of a substance that contains
    6.02 x 1023 of something
  • 1 mole of pencils 6.02 x 1023 pencils
  • 1 mole of eggs 6.02 x 1023 eggs
  • 1 mole of carbon 6.02 x 1023 carbon atoms
  • 6.02 x 1023 is called Avogadros number
  • It helps us count atoms, which we cant see,
    using the measurement of mass

83
Lets Do It!!!
  • How many atoms of oxygen are in a mole of oxygen?
  • How many atoms of magnesium are in a mole of
    magnesium?
  • Would they have the same mass?

84
Atomic Mass of an Element Mole-Reference
  • Each element has a unique atomic mass and this is
    a standard for each element
  • Atomic mass mass of 1 mole of an element
  • The atomic masses are from the periodic table and
    we use grams
  • 1 mole O 6.02 x 1023 atoms O 15.999 g O
  • 1 mole Mg 6.02 x 1023 atoms Mg 24.305 g Mg

85
Molar Mass
  • Molar mass mass of 1 mole of a pure substance
  • Molar mass of element (g/mol) the atomic mass
    of an element
  • Molar mass of a compound (g/mol)- the sum of the
    molar masses of the elements making up the
    compound
  • Whats the molar mass of Cl? Dont forget units!
    We are going to round to 3 SDs for the atomic
    mass
  • Whats the molar mass of H2O?

86
Moles to Atoms-Reference
  • 1 mole 6.02x1023 atoms atomic mass (g)
  • These can be used as a conversion factors
    6.02 x 1023 atoms 1 mole atomic mass
  • atomic mass 6.02 x 1023 atoms 1
    mole
  • If you have 1.5 moles of potassium, how many
    atoms is this?
  • Question mark format for DA
  • ? atoms of K

6.02 x 1023 atoms K ---------------------
1 mole K
9.03 x 1023 atoms K
1.50 mole K
87
Moles to Grams-Reference
  • 1 mole 6.02x1023 atoms Atomic Mass (g)
  • If you have 1.25 moles of potassium, how many
    grams is this?
  • Question mark format for DA
  • ? grams of K

1.25 moles K
39.1 g K ----------- 1 mole K
48.9 g K
88
Grams to Atoms-Reference
  • 1 mole 6.02x1023 atoms Atomic Mass (g)
  • If you have 12.5 grams of phosphorus, how many
    atoms is this?
  • Question mark format for DA
  • ? atoms of P

6.02 x 1023 atoms P x ---------------------
31.0 g P
12.5 g P
2.43 x 1023 atoms P
89
Lets Do It!!
  • 1 mole 6.02x1023 atoms Atomic Mass (g)
  • If you have 2.93 x 1024 atoms of sodium, how many
    moles is this?
  • Question mark format for DA
  • ? moles of Na

2.93 x 1024 atoms Na
4.87 moles Na
90
Lets Do It!!!
  • 1 mole 6.02x1023 atoms Atomic Mass (g)
  • If you have 1.25 grams of sodium, how many moles
    is this?
  • Question mark format for DA
  • ? moles of Na

1 mole Na -------------- 23.0 g Na
1.25 g Na
0.0543 mole Na
91
Lets Do It!!!
  • 1 mole 6.02x1023 atoms Atomic Mass (g)
  • If you have 3.52 x 1022 atoms of carbon, how
    many grams is this?
  • ? grams of C

12.0 g C x
---------------- 6.02 x 1023 atoms C
3.52 x 1022 atoms C
.702 g C
92
Mole vs. Molecule
  • Dont confuse mole and molecule
  • A mole is an amount
  • A molecule is a thing
  • We can have a mole of molecules
  • A mole of water molecules
  • 6.02 x 1023 molecules of water
  • If I have an amino acid molecule tryptophan,
    C11H12N2O2, how many molecules of tryptophan are
    in a mole?

93
Review
  • Number your paper from 1-5 and answer the
    following questions. Two will be cumulative
    review!
  • 1. Which of these is proper scientific notation?
  • a. 5.56 X 106
  • b. 3.5 X 32
  • c. 95.6 X 1010
  • d. 256 X 106

94
Review
  • A
  • 2. Which of the numbers in the nitrogen periodic
    table tile is the atomic number?
  • a. N
  • b. 14
  • c. 14.007
  • d. 7

95
Review
  • D
  • 3. Which of these is NOT a correct conversion
    factor for Carbon?
  • a. 1 mole C
  • 6.02 x 1023 g C
  • b. 1 mole C
  • 6.02 x 1023 atoms C
  • c. 1 mole C
  • 12.011 g C
  • d. 12.011 g C
  • 6.02 x 1023 atoms C

96
Review
  • A
  • 4. If I have 14.007 grams of nitrogen, how many
    atoms do I have?
  • a. 1.67 x10-24
  • b. 1.17 x10-23
  • c. 2.24 x10-23
  • d. 6.02x1023

97
Review
  • D
  • 5. How many atoms are in 10 moles of carbon?
  • a. 10 atoms
  • b. 6 atoms
  • c. 6.02x1023 atoms
  • d. 6.02x1024 atoms

98
Review
  • D
  • 1 mole of ANYTHING 6.02x1023 atoms
  • ? Atoms 10 moles C x 6.02x1023 atoms C
  • 1
    mole C
  • 10 x 6.02x1023 atoms C 6.02x1024 atoms

99
Radius of Nucleus of an Atom-Reference
  • Radius (1.4 x 10-13 cm)
  • Where A mass number of the atom
  • of protons neutrons
  • and the cube root of the mass
    number
  • and 1.4 x 10-13 cm a constant that

  • describes the
  • effective
    range of force

100
Radius of Nucleus of an Atom-Reference
  • Calculate the radius of the nucleus of a 56Fe
    atom
  • Radius (1.4 x 10-13 cm)
  • Radius (1.4 X 10-13 cm)
  • Radius 5.4 X 10-13 cm
  • only round ONCE ! ! !

101
Volume of a Nucleus-Reference
  • Calculate the volume of the nucleus of a 56Fe
    atom (we model as a sphere)
  • Volume of a sphere
  • Volume
  • Volume 6.6 10-37 cm3

102
Size of the Nucleus
Atom Nuclear Radius (1.4 x 10-13 cm) Nuclear Volume Nuclear Mass A(1.6710-24g ) Nuclear Density





103
Size of the Nucleus
Atom Nuclear Radius (1.4 x 10-13 cm) Nuclear Volume Nuclear Mass A(1.6710-24g ) Nuclear Density
4.0 x 10-13 cm
8.1 x 10-13 cm
2.2 x 10-13 cm
5.6 x 10-13 cm
6.0 x 10-13 cm
104
Size of the Nucleus
Atom Nuclear Radius (1.4 x 10-13 cm) Nuclear Volume Nuclear Mass A(1.6710-24g ) Nuclear Density
4.0 x 10-13 cm 2.7 x 10-37 cm3
8.1 x 10-13 cm 2.2 x 10-36 cm3
2.2 x 10-13 cm 4.5 x 10-38 cm3
5.6 x 10-13 cm 7.4 x 10-37 cm3
6.0 x 10-13 cm 9.0 x 10-37 cm3
105
Size of the Nucleus
Atom Nuclear Radius (1.4 x 10-13 cm) Nuclear Volume Nuclear Mass A(1.6710-24g ) Nuclear Density
4.0 x 10-13 cm 2.7 x 10-37 cm3 3.84 x 10-23g
8.1 x 10-13 cm 2.2 x 10-36 cm3 3.29 x 10-22g
2.2 x 10-13 cm 4.5 x 10-38 cm3 6.68 x 10-24g
5.6 x 10-13 cm 7.4 x 10-37 cm3 1.07 x 10-22g
6.0 x 10-13 cm 9.0 x 10-37 cm3 1.34 x 10-22g
106
Size of the Nucleus-Reference
Atom Nuclear Radius (1.4 x 10-13 cm) Nuclear Volume Nuclear Mass A(1.6710-24g ) Nuclear Density
4.0 x 10-13 cm 2.7 x 10-37 cm3 3.84 x 10-23g 1.4 x 1014 g/cm3
8.1 x 10-13 cm 2.2 x 10-36 cm3 3.29 x 10-22g 1.5 x 1014 g/cm3
2.2 x 10-13 cm 4.5 x 10-38 cm3 6.68 x 10-24g 1.5 x 1014 g/cm3
5.6 x 10-13 cm 7.4 x 10-37 cm3 1.07 x 10-22g 1.5 x 1014 g/cm3
6.0 x 10-13 cm 9.0 x 10-37 cm3 1.34 x 10-22g 1.5 x 1014 g/cm3
107
Densities of Atoms
  • Why are these density values nearly the same?
  • Because all nuclei are made up of the same
    material (protons neutrons). The SAME material
    always has the SAME density!

108
Densities of Atoms
  • If we look up the density of the element sodium
    (its on some periodic tables) we see that its
    density is .971 g/cm3.
  • Why is this different from the value we
    calculated?
  • We calculated values for the nucleus only and the
    periodic tables value is for the whole atom
    including the space that the electrons occupy
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