Title: Ultra energy
1Seawater Desalination by Ultralow-Energy Reverse
Osmosis
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2Reverse Osmosis
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Reverse osmosis (RO) is a water purification
technology that uses a semipermeable membrane to
remove ions, molecules, and larger particles from
drinking water. In reverse osmosis, an applied
pressure is used to overcome osmotic pressure.
3Osmotic Pressure
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- the measure of the tendency of a solution to take
in water by osmosis
4Spiral-wound Element
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- Spiral-wound Element refers to a membrane
configuration which is comprised of - Flat sheet membrane permeate channel spacer
- Flat sheet membrane feed channel spacer
- combination rolled up around a product collection
tube.
5Early Research
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- 1950s and 1960s University of Florida
- semipermeable reverse osmosis (RO) membrane
- thick-film
- asymmetric
- cellulose acetate
- Pressure required up to 105 bars
6Limitations
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- selectivity of membranes
- osmotic pressure of the seawater
- Recovery 25
- Energy Required 10 kWh/m3.
- GOAL Cost Effective Technology to desalt sea
water for human consumption.
7Thin-Film Composite Membranes
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- 1970
- thin-film composite membranes using polymeric
materials - Polyetherurea
- Polyamide
- Reduced resistance
- Pressure less than 70 bars
- Recovery 35
- Energy 6.6 kWh/m3
8First Commercial SWRO
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- 1978 Jeddah, Saudi Arabia
- Design Parameters
- Capacity 12,000m3/day
- Operating Pressure 56 bars
- Recovery 30
- TDS 1000mg/L (Blending with 50mg/L condensate)
- Energy 6.1 kWh/m3
9SWRO Energy Reduction using Energy Recovery
Technology
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- Pelton Wheels - 100-year-old engineering concept
- SWRO high-pressure pump/motor assemblies 1982
- Pelton wheel RO flow scheme
10Pelton Wheel Characteristics
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- Low capital cost
- Directly connected to SWRO pump/motor
- Requires full-sized SWRO pump/motor
- Operates in a centrifugal mode follows flow
pressure curves - Overall net transfer efficiencies can reach 88
- Metallic construction
11Efficiency Curve
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- Current Pelton wheel devices overall Net
Transfer Efficiency 60-88 - Typical Pelton wheel efficiency
curve
12Turbochargers
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- Improvement in economy Energy Recovery
Technology - A stand-alone device
- Not connected to the high-pressure pump
- Employed in Variety of ways
13Typical turbocharger RO flow scheme
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14Turbocharger as a Booster Pump
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15Turbocharger Characteristics
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- Moderate capital cost compared to Pelton wheel
- Not connected to SWRO pump/motor assembly
- Operates in a centrifugal mode and follows flow
and pressure curves - Overall net transfer efficiency follows a curve
and can reach 83 - Metallic construction
- Can be used in a variety of flow schemes
16Efficiency Curve
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- Efficiency 60-70
- The highest overall net transfer efficiency
achieved by a turbocharger is 83
17SWRO Energy Optimization
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- The three areas of innovation are
- Membrane/element design
- 1978 15 m2 of membrane 7.5 m3 of permeate/day
98.6 salt rejection - Today 40 m2 of membrane 28-34 m3 of
permeate/day 99.75 salt rejection - Large-capacity high-pressure pump/motor
efficiency - Energy recovery technology improvements
18Historical Cost Comparison
- Reduction in Energy Consumption
- 10 kWh/m3 - late 1970s
- 3.5 kWh/m3 2000
19Achievements
- Affordable Desalination Collaboration (ADC) -
California report published in August 2006 - Recovery 42.5
- Energy 1.58 kWh/m3
- TDS 110mg/L
- Efficiency 95
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