Title: Clickers
1Clickers!
We will work out a synthetic route to achieve the
following overall transformation in four steps.
2Clickers!
A 1) B2H6, THF 2) NaOH, H2O2 aq. B 1) O3,
CH2Cl2 2) Zn/HOAc C mCPBA, CH2Cl2 D KMnO4,
H3O E Hg(OAc)2, H2SO4 (aq.)
3Clickers!
KMnO4, H3O
4Clickers!
KMnO4, H3O
5Clickers!
KMnO4, H3O
A pTsOH, toluene, D B CrO3, H2SO4
(aq.) C mCPBA, CH2Cl2 D Sn, HOAc
6Clickers!
KMnO4, H3O
pTsOH, toluene, D
7Clickers Spectroscopy.
Data on an unknown organic compound whose formula
is C6H8O2 will be presented. The questions will
follow.
8IR Spectrum
9Clicker question
The degree of unsaturation in this compound is
A 1 B 2 C 3 D 4
10Clicker question
The degree of unsaturation in this compound is
A 1 B 2 C 3 D 4
11Clicker question
From the IR spectrum, what functional group is
likely to be present?
A Ester B Ketone C Carboxylic acid D Nitrile
12Clicker question
From the IR spectrum, what functional group is
likely to be present?
A Ester B Ketone C Carboxylic acid D Nitrile
13NMR Spectra.
14Clicker question
We know the compound contains a COOH group, and
has 3 degrees of unsaturation. Based on this and
the NMR spectra, what other functionality is
present?
A Aromatic ring B Alkyne C Two Alkenes
15Clicker question
We know the compound contains a COOH group, and
has 3 degrees of unsaturation. Based on this and
the NMR spectra, what other functionality is
present?
A Aromatic ring B Alkyne C Two Alkenes
16Clicker question
What is the structure of the unknown compound?
17Clicker question
What is the structure of the unknown compound?